Method for preparing polyurethane prepolymers containing isocyanate groups
View Patent ↗The present invention relates to the technical field of isocyanates. The present invention provides a method for preparing NCO prepolymers by reacting a stoichiometric excess of an organic isocyanate with an isocyanate-reactive component, the reaction components being mixed together and the mixture being introduced directly into a storage or transport vessel, where it reacts to completion.
1. A method for preparing an isocyanate group-containing prepolymer from an isocyanate group-containing component and an isocyanate group-reactive component, which comprises
mixing continuously the components in a mixing device
and immediately after being mixed
introducing continuously the reaction mixture into a storage or transport vessel, where the reaction between the components is completed,
wherein in a first step of a batch production only a first reaction component is initially directed through the mixing device into the vessel, before in a second step the second reaction component is directed into the mixing device in addition to the first reaction component, where it is mixed with the first reaction component,
wherein to end the batch production the metering of the second reaction component is stopped and the mixing device is rinsed with the first reaction component, and
wherein the reaction component directed through the mixing device in the first step of the batch production is the isocyanate group-containing component and the reaction component directed into the mixing device in the second step is the isocyanate group-reactive component.
2. The method according to claim 1 , wherein the storage or transport vessel has no means of mixing and/or cooling.
3. The method according to claim 1 , wherein the transport vessel is the tank of a tanker vehicle.
4. The method according to claim 1 , wherein the temperature in the vessel rises less than 60° C.
5. The method according to claim 1 , wherein the proportion of isocyanate group-reactive component in the mixture is 0.1 to 10 weight %.
6. The method according to claim 1 , wherein the mixing device comprises one or more static mixers.
7. The method according to claim 1 , wherein after the end of the batch production the mixing device remains in the flooded state at ambient temperature until the start of the next batch production.
8. A method comprising introducing a reacting mixture into a storage or transport vessel, wherein the reacting mixture comprising an isocyanate group containing prepolymer from an isocyanate group-containing component and an isocyanate group-reactive component is prepared according to the method of claim 1 .