Metal complexes

1. A compound of the formula (1),

M(L) n (L′) m   formula (1)

where the compound contains a moiety M(L) n , of the formula (2):

where the following applies to the symbols and indices used:

M is a metal;

Y is on each occurrence, identically or differently, C or N, with the proviso that precisely one symbol Y in each ligand stands for N and the other two symbols Y stand for C;

X is on each occurrence, identically or differently, CR or N;

R is on each occurrence, identically or differently, H, D, F, Cl, Br, I, N(R 1 ) 2 , CN, NO 2 , OH, COOH, C(═O)N(R 1 ) 2 , Si(R 1 ) 3 , B(OR 1 ) 2 , C(═O)R 1 , P(═O)(R 1 ) 2 , S(═O)R 1 , S(═O) 2 R 1 , OSO 2 R 1 , a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more non-adjacent CH 2 groups is optionally replaced by R 1 C═CR 1 , C≡C, Si(R 1 ) 2 , C═O, NR 1 , O, S or CONR 1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 ; two adjacent radicals R here may also form a mono- or polycyclic, and/or aliphatic ring system with one another, with the proviso that the two adjacent radicals R do not form a benzo-fused ring system;

R 1 is on each occurrence, identically or differently, H, D, F, Cl, Br, I, N(R 2 ) 2 , CN, NO 2 , Si(R 2 ) 3 , B(OR 2 ) 2 , C(═O)R 2 , P(═O)(R 2 ) 2 , S(═O)R 2 , S(═O) 2 R 2 , OSO 2 R 2 , a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 2 , where one or more non-adjacent CH 2 groups is optionally replaced by R 2 C═CR 2 , C≡C, Si(R 2 ) 2 , C═O, NR 2 , O, S or CONR 2 and where one or more H atoms is optionally replaced by D, F, CI, Br, I, CN, or NO 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 2 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 ; two adjacent radicals R 1 here may also form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with one another;

R 2 is on each occurrence, identically or differently, H, D, F or an aliphatic, aromatic and/or heteroaromatic hydrocarbon radical having 1 to 20 C atoms, in which, in addition, one or more H atoms is optionally replaced by F; two or more substituents R 2 here may also form a mono- or polycyclic aliphatic ring system with one another;

L′ is, identically or differently on each occurrence, a co-ligand;

n is 1, 2 or 3;

m is 0, 1, 2, 3 or 4;

a plurality of ligands L here may also be linked to one another or L is optionally linked to L′ via any desired bridge V and thus form a tridentate, tetradentate, pentadentate or hexadentate ligand system and/or a substituent R may additionally be coordinated to the metal;

the following compounds are excluded from the invention:

2. The compound according to claim 1 , wherein M is selected from the group consisting of chromium, molybdenum, tungsten, rhenium, ruthenium, osmium, rhodium, iridium, nickel, palladium, platinum, copper, silver and gold.

3. The compound according to claim 1 , wherein all X in ligand L stand for CR or in that precisely one, two, three or four groups X stand for N and the remaining groups X stand for CR.

4. The compound according to claim 1 , wherein the moieties of the formula (2) are selected from the moieties of the formulae (4) to (33),

where the symbols and indices used have the meanings given in claim 1 .

5. The compound according to claim 1 , in which at least one group X═N, wherein at least one group X which is adjacent to this nitrogen atom stands for a CR 3 group, where R 3 is on each occurrence, identically or differently, a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more non-adjacent CH 2 groups is optionally replaced by R 1 C═CR 1 , Si(R 1 ) 2 , C═O, NR 1 , O, S or CONR 1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 ; R 3 here may also form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with an adjacent radical R.

6. The compound according to claim 1 , selected from the structures of the formulae (7a) to (33a) and (8b) to (32b),

where the symbols and indices used have the meanings given in claim 1 and R 3 is on each occurrence, identically or differently, a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more non-adjacent CH 2 groups is optionally replaced by R 1 C═CR 1 , C≡C, Si(R 1 ) 2 , C═O, NR 1 , O, S or CONR 1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 ; R 3 here may also form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with an adjacent radical R.

7. The compound according to claim 5 , wherein R 3 is selected from the structures of the following formulae (R 3 -1) to (R 3 -115), where in each case the linking of these groups to the ligand is also shown:

where Lig denotes the linking of the group to the ligand and the aromatic and heteroaromatic groups may each be substituted by one or more radicals R 1 .

8. The compound according to claim 1 , wherein the radicals R are selected on each occurrence, identically or differently, from the group consisting of H, D, F, Br, I, N(R 1 ) 2 , CN, Si(R 1 ) 3 , B(OR 1 ) 2 , C(═O)R 1 , a straight-chain alkyl group having 1 to 10 C atoms or an alkenyl group having 2 to 10 C atoms or a branched or cyclic alkyl group having 3 to 10 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more H atoms is optionally replaced by D or F, or an aromatic or heteroaromatic ring system having 5 to 30 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 ; two adjacent radicals R here may also form a mono- or polycyclic and/or aliphatic fused ring system with one another; the radicals R which are bonded to the central six-membered ring do not form an aromatic or benzo-fused ring system with one another.

9. The compound according to claim 1 , wherein the substituent R which is in the ortho-position to the metal coordination represents a group which is coordinated to the metal M and is selected from aryl or heteroaryl groups, aryl or alkyl cyanides, aryl or alkyl isocyanides, amines, amides, alcohols, alcoholates, thioalcohols, thioalcoholates, phosphines, phosphites, carbonyl functions, carboxylates, carbamides or aryl- or alkylacetylides.

10. The compound according to claim 1 , selected from metal complexes of the formulae (41) to (46),

where the symbols used have the meanings given above, where V represents a bridging unit containing 1 to 80 atoms from the third, fourth, fifth and/or sixth main group (IUPAC group 13, 14, 15 or 16), which may also be substituted by one or more radicals R 1 , or a 3- to 6-membered homo- or heterocycle which covalently connects the part-ligands L to one another or L to L′ to one another.

11. The compound according to claim 1 , wherein the ligand L′ is identically or differently on each occurrence, carbon monoxide, nitrogen monoxide, alkyl cyanides, aryl cyanides, alkyl isocyanides, aryl isocyanides, amines, phosphines, phosphites, arsines, stibines, nitrogen-containing heterocycles, carbenes, hydride, deuteride, the halides F − , Cl − , Br − and I − , alkylacetylides, arylacetylides, cyanide, cyanate, isocyanate, thiocyanate, isothiocyanate, aliphatic or aromatic alcoholates, aliphatic or aromatic thioalcoholates, amides, carboxylates, aryl groups, O 2− , S 2− , carbides, nitrenes, diamines, imines, diimines, diphosphines, 1,3-diketonates, 3-ketonates derived from 3-ketoesters, carboxylates derived from aminocarboxylic acids, salicyliminates derived from salicylimines, dialcoholates, dithiolates, borates of nitrogen-containing heterocycles and ligands which have a cyclometallated five-membered ring or six-membered ring with the metal.

12. A process for the preparation of the compound according to claim 1 which comprises reacting the ligand with metal alcoholates of the formula (93), with metal ketoketonates of the formula (94), with metal halides of the formula (95) or with dimeric metal complexes of the formula (96),

where the symbols M, L′, m, n and R have the meanings indicated in claim 1 and Hal=F, Cl, Br or I.

13. An electronic device which comprises the compound according to claim 1 .

14. The electronic device as claimed in claim 13 , wherein the device is an organic electroluminescent device, organic integrated circuit, organic field-effect transistor, organic thin-film transistor, organic light-emitting transistor, organic solar cell, organic optical detector, organic photoreceptor, organic field-quench device, light-emitting electrochemical cell or organic laser diode.

15. An organic electroluminescent device which comprises the compound according to claim 1 is employed as emitting compound in one or more emitting layers.

16. An organic electroluminescent device which comprises the compound according to claim 1 is employed as emitting compound in one or more emitting layers in combination with one or more matrix materials.

17. A compound of the formula (1)

M(L) n (L′) m   formula (1)

where the compound contains a moiety M(L) n , of the formula (2):

where the following applies to the symbols and indices used:

M is a metal;

Y is on each occurrence, identically or differently, C or N, with the proviso that precisely one symbol Y in each ligand stands for N and the other two symbols Y stand for C;

X is on each occurrence, identically or differently, CR or N; and in which at least one group X═N, wherein at least one group X which is adjacent to this nitrogen atom stands for a CR 3 group, where R 3 is on each occurrence, identically or differently, a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more non-adjacent CH 2 groups is optionally replaced by R 1 C═CR 1 , C≡C, Si(R 1 ) 2 , C═O, NR 1 , O, S or CONR 1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 ; R 3 here may also form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with an adjacent radical R;

R is on each occurrence, identically or differently, H, D, F, Cl, Br, I, N(R 1 ) 2 , CN, NO 2 , OH, COOH, C(═O)N(R 1 ) 2 , Si(R 1 ) 3 , B(OR 1 ) 2 , C(═O)R 1 , P(═O)(R 1 ) 2 , S(═O)R 1 , S(═O) 2 R 1 , OSO 2 R 1 , a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more non-adjacent CH 2 groups is optionally replaced by R 1 C═CR 1 , C≡C, Si(R 1 ) 2 , C═O, NR 1 , O, S or CONR 1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 ; two adjacent radicals R here may also form a mono- or polycyclic, and/or aliphatic ring system with one another, with the proviso that the two adjacent radicals R do not form a benzo-fused ring system;

R 1 is on each occurrence, identically or differently, H, D, F, Cl, Br, I, N(R 2 ) 2 , CN, NO 2 , Si(R 2 ) 3 , B(OR 2 ) 2 , C(═O)R 2 , P(═O)(R 2 ) 2 , S(═O)R 2 , S(═O) 2 R 2 , OSO 2 R 2 , a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 2 , where one or more non-adjacent CH 2 groups is optionally replaced by R 2 C═CR 2 , C≡C, Si(R 2 ) 2 , C═O, NR 2 , O, S or CONR 2 and where one or more H atoms is optionally replaced by D, F, CI, Br, I, CN, or NO 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 2 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 ; two adjacent radicals R 1 here may also form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with one another;

R 2 is on each occurrence, identically or differently, H, D, F or an aliphatic, aromatic and/or heteroaromatic hydrocarbon radical having 1 to 20 C atoms, in which, in addition, one or more H atoms is optionally replaced by F; two or more substituents R 2 here may also form a mono- or polycyclic aliphatic ring system with one another;

L′ is, identically or differently on each occurrence, a co-ligand;

n is 1, 2 or 3;

m is 0, 1, 2, 3 or 4;

a plurality of ligands L here may also be linked to one another or L is optionally linked to L′ via any desired bridge V and thus form a tridentate, tetradentate, pentadentate or hexadentate ligand system and/or a substituent R may additionally be coordinated to the metal;

the following compounds are excluded from the invention:

18. The compound according to claim 17 , selected from the structures of the formulae (7a) to (33a) and (8b) to (32b),

where the symbols and indices used have the meanings given in claim 17 and R 3 is on each occurrence, identically or differently, a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more non-adjacent CH 2 groups is optionally replaced by R 1 C≡CR 1 , C≡C, Si(R 1 ) 2 , C═O, NR 1 , O, S or CONR 1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 ; R 3 here may also form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with an adjacent radical R.

19. The compound according to claim 17 , wherein R 3 is selected from the structures of the following formulae (R 3 -1) to (R 3 -115), where in each case the linking of these groups to the ligand is also shown:

where Lig denotes the linking of the group to the ligand and the aromatic and heteroaromatic groups may each be substituted by one or more radicals R 1 .

20. The compound according to claim 17 , wherein the substituent R which is in the ortho-position to the metal coordination represents a group which is coordinated to the metal M and is selected from aryl or heteroaryl groups, aryl or alkyl cyanides, aryl or alkyl isocyanides, amines, amides, alcohols, alcoholates, thioalcohols, thioalcoholates, phosphines, phosphites, carbonyl functions, carboxylates, carbamides or aryl- or alkylacetylides.

21. The compound according to claim 17 , selected from metal complexes of the formulae (41) to (46),

where the symbols used have the meanings given above, where V represents a bridging unit containing 1 to 80 atoms from the third, fourth, fifth and/or sixth main group (IUPAC group 13, 14, 15 or 16), which may also be substituted by one or more radicals R 1 , or a 3- to 6-membered homo- or heterocycle which covalently connects the part-ligands L to one another or L to L′ to one another.

22. A compound of the formula (1),

M(L) n (L′) m   formula (1)

where the compound contains a moiety M(L) n of the formulae (5) to (33),

where the following applies to the symbols and indices used:

M is a metal;

Y is on each occurrence, identically or differently, C or N, with the proviso that precisely one symbol Y in each ligand stands for N and the other two symbols Y stand for C;

X is on each occurrence, identically or differently, CR or N;

R is on each occurrence, identically or differently, H, D, F, Cl, Br, I, N(R 1 ) 2 , CN, NO 2 , OH, COOH, C(═O)N(R 1 ) 2 , Si(R 1 ) 3 , B(OR 1 ) 2 , C(═O)R 1 , P(═O)(R 1 ) 2 , S(═O)R 1 , S(═O) 2 R 1 , OSO 2 R 1 , a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 1 , where one or more non-adjacent CH 2 groups is optionally replaced by R 1 C═CR 1 , C≡C, Si(R 1 ) 2 , C═O, NR 1 , O, S or CONR 1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 1 ; two adjacent radicals R here may also form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with one another;

R 1 is on each occurrence, identically or differently, H, D, F, Cl, Br, I, N(R 2 ) 2 , CN, NO 2 , Si(R 2 ) 3 , B(OR 2 ) 2 , C(═O)R 2 , P(═O)(R 2 ) 2 , S(═O)R 2 , S(═O) 2 R 2 , OSO 2 R 2 , a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 20 C atoms, each of which is optionally substituted by one or more radicals R 2 , where one or more non-adjacent CH 2 groups is optionally replaced by R 2 C═CR 2 , C≡C, Si(R 2 ) 2 , C═O, NR 2 , O, S or CONR 2 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I, CN or NO 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 2 , or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 , or an aralkyl or heteroaralkyl group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R 2 ; two or more adjacent radicals R 1 here may form a mono- or polycyclic, aliphatic, aromatic and/or benzo-fused ring system with one another;

R 2 is on each occurrence, identically or differently, H, D, F or an aliphatic, aromatic and/or heteroaromatic hydrocarbon radical having 1 to 20 C atoms, in which, in addition, one or more H atoms is optionally replaced by F; two or more substituents R 2 here may also form a mono- or polycyclic, aliphatic ring system with one another;

L′ is, identically or differently on each occurrence, a co-ligand;

n is 1, 2 or 3;

m is 0, 1, 2, 3 or 4;

a plurality of ligands L here may also be linked to one another or L is optionally linked to L′ via any desired bridge V and thus form a tridentate, tetradentate, pentadentate or hexadentate ligand system and/or a substituent R may additionally be coordinated to the metal.

23. An electronic device which comprises the compound according to claim 17 .

24. An electronic device which comprises the compound according to claim 22 .

25. An organic electroluminescent device which comprises the compound according to claim 17 is employed as emitting compound in one or more emitting layers.

26. An organic electroluminescent device which comprises the compound according to claim 22 is employed as emitting compound in one or more emitting layers.