Method and apparatus for recharging a battery
View Patent ↗The present invention provides a novel method for charging silver-zinc rechargeable batteries and an apparatus for practicing the charging method. The recharging apparatus includes recharging management circuitry; and one or more of a silver-zinc cell, a host device or a charging base that includes the recharging management circuitry. The recharging management circuitry provides means for regulating recharging of the silver-zinc cell, diagnostics for evaluating battery function, and safety measures that prevent damage to the apparatus caused by charging batteries composed of materials that are not suited for the charging method (e.g., non-silver-zinc batteries).
1. A method of charging a rechargeable battery having multiple voltage plateaus wherein the battery has a voltage, V Batt , that is less than its highest voltage plateau comprising:
charging the battery with a first charging current, I 1 , wherein the first charging current, I 1 , is applied until the battery is charged to a voltage, V 1 ; and
controlling the first charging current, I 1 , when the voltage of the battery is V 1 , so that the voltage of the battery is maintained at V 1 with a deviation of no more than about ±20% of V 1 ,
wherein voltage, V 1 , is less than the voltage of a natural polarization peak, V PP , associated with a voltage plateau, V P , wherein V P is greater than V Batt , and V 1 is greater than the voltage plateau, V P ; and
charging the battery with a second charging current, I 2 , wherein the second charging current, I 2 , is applied after the first charging current, I 1 , until the battery voltage reaches a voltage, V 2 , wherein the voltage, V 2 , is greater than V P , and less than V PP ; and
controlling the second charging current, I 2 , when the voltage of the battery reaches the voltage, V 2 , so that the voltage of the battery is maintained at V 2 with a deviation of no more than about ±20% of V 2 .
2. The method of claim 1 , wherein the second charging current, I 2 , is applied at least until the battery is charged to a SOC of from about 80% to about 150% of the battery's rated capacity.
3. The method of claim 1 , wherein I 1 is substantially constant until the battery is charged to a voltage, V 1 .
4. The method of claim 3 , wherein I 2 is substantially constant until the battery is charged to a voltage, V 2 .
5. The method of claim 1 , wherein the first charging current, I 1 , is sufficient to charge the battery to voltage, V 1 , in a period of from about 1 min to about 300 min when the battery's initial SOC is less than 40% of its rated capacity.
6. The method of claim 1 , wherein the first charging current, I 1 , is controlled when the voltage of the battery is V 1 , so that the voltage of the battery is maintained at V 1 with a deviation of no more than about ±20% of V 1 , for a period of from about 6 s to about 1500 s.
7. The method of claim 1 , further comprising:
terminating the first charging current, I 1 , after the voltage of the battery is maintained at V 1 with a deviation of no more than about ±20% of V 1 , for a period of from about 6 s to about 1200 s; and
applying the second charging current, I 2 , when the first charging current, I 1 , terminates.
8. The method of claim 1 , wherein I 1 is greater than or equal to I 2 during the period before the battery is charged to a voltage of V 1 .
9. The method of claim 8 , wherein V 1 is greater than or equal to V 2 .
10. The method of claim 1 , wherein V Batt is from about 50% to about 87% of the voltage, V 1 .
11. The method of claim 1 , wherein the method excludes counting Coulombs.
12. The method of claim 11 , further comprising generating an electrical signal that indicates a soft short in the battery if V Batt is lower than V P for a period of more than 1 second after the battery has been charged to a voltage of V 2 .
13. The method of claim 12 , further comprising charging the battery with a diagnostic charge current, I Diag , for a period of less than about 30 s, detecting the voltage of the battery, V Batt , and terminating charging of the battery if V Batt is about 1.65 V or less.
14. The method of claim 13 , wherein I Diag is greater than or equal to I 1 .