Metal foil laminate, substrate for mounting LED, and light source device
View Patent ↗Provided is a metal foil laminate that: has heat resistance; has high reflectance in the visible light range; has little decrease in reflectance in environments with a high-temperature thermal load; is compatible with large surface areas; and can be used for printed circuit boards for mounting LEDs that have excellent adhesion with metals. The metal foil laminate is characterized in that: a laminate has metal foil on at least one side of a resin layer (A) containing a polyorganosiloxane and an inorganic filler; the 90° peel strength between said resin layer (A) and said metal foil is at least 0.95 kN/m, and the mean reflectance at wavelengths of 400 to 800 nm on the surface that is exposed when the resin layer (A) is exposed by peeling and removing said metal foil is at least 80%; and the decrease in the reflectance at a wavelength of 470 nm after being treated with heat for 10 minutes at 260° C. is not more than 5%.
1. A metal foil laminate, comprising:
(A) a resin layer comprising a polyorganosiloxane and an inorganic filler; and
(B) a metal foil laminated on at least one surface of the resin layer (A),
wherein:
a 90° peel strength between the resin layer (A) and the metal foil (B) is 0.95 kN/m or greater;
an average reflectance for a wavelength of 400 nm to 800 nm at an exposed surface obtained by peeling and removing the metal foil (B) and thereby exposing the resin layer (A), is 80% or higher; and
a decrement of reflectances for a wavelength of 470 nm at exposed surfaces, obtained before and after the metal foil laminate is heat treated at 260° C. for 10 minutes, is 5% or less.
2. The metal foil laminate according to claim 1 , wherein the resin layer (A) is a layer cured by radiation.
3. The metal foil laminate according to claim 2 , wherein in the metal foil (B), a surface on the side that is laminated on the resin layer (A) is treated with a silane coupling agent.
4. The metal foil laminate according to claim 2 , wherein the resin layer (A) further comprises a crosslinking agent in an amount of 0% to 5% by mass relative to a total amount of components of the resin layer (A).
5. The metal foil laminate according to claim 2 , wherein the resin layer (A) further comprises titanium oxide as an inorganic filler.
6. The metal foil laminate according to claim 2 , wherein the resin layer (A) has a thickness of from 3 μm to 500 μm.
7. A substrate for mounting LED, the substrate comprising the metal foil laminate according to claim 2 .
8. A light source device, comprising:
the substrate for mounting LED according to claim 7 ;
a conductor circuit formed on the substrate; and
a LED mounted on the substrate,
wherein the light source device is encapsulated with a resin, and the substrate and the LED are conductively connected.
9. The metal foil laminate according to claim 1 , wherein in the metal foil (B), a surface on the side that is laminated on the resin layer (A) is treated with a silane coupling agent.
10. The metal foil laminate according to claim 1 , wherein the resin layer (A) further comprises a crosslinking agent in an amount of 0% to 5% by mass relative to a total amount of components of the resin layer (A).
11. The metal foil laminate according to claim 1 , wherein the resin layer (A) further comprises titanium oxide as an inorganic filler.
12. The metal foil laminate according to claim 1 , wherein the resin layer (A) has a thickness of from 3 μm to 500 μm.
13. A substrate for mounting LED, the substrate comprising the metal foil laminate according to claim 1 .
14. A light source device, comprising:
the substrate for mounting LED according to claim 13 ;
a conductor circuit formed on the substrate; and
a LED mounted on the substrate,
wherein the light source device is encapsulated with a resin, and the substrate and the LED are conductively connected.