Temperature response sensing and classification of analytes with porous optical films
Methods and systems of the invention can determine the identity and quantity of analytes in a vapor. In preferred methods, a porous optical film is exposed to vapor which contains analyte. The porous optical film is heated and its optical response is monitored during heating. An optical response observed via heating can determine the identity and/or quantity of the analyte. In preferred embodiments, optical response during a thermal pulse is compared to a database of sensor responses that are characteristic of various analytes. Preferred methods are conducted a relatively low temperatures, for example below about 200° C. In preferred methods, a heating and cooling cycle produces a hysteresis curve in the optical response that is indicative of analytes. In preferred embodiments, a thermal reset pulse resets the porous optical film for later use and also provides an optical response that can be used for sensing.
1. A method for sensing vapor, comprising steps of:
exposing a porous optical film to vapor which contains analyte;
heating the porous optical film;
monitoring an optical response of the porous optical film for a sensing time period during said heating; and
determining identity or quantity of the analyte from a response curve obtained during the sensing time period of said monitoring, wherein said heating comprises heating to a desorption temperature and the sensing time period covers a period of desorption.
2. The method of claim 1 , wherein said determining determines identity and quantity of the analyte.
3. The method of claim 2 , further comprising ceasing said heating after a heating time period to cycle the porous optical film over a heating cycle and cooling cycle, wherein said sensing time period encompasses at least a portion of said heating cycle and said cooling cycle.
4. The method of claim 3 , wherein said determining comprises determining a hysteresis curve from the optical response and comparing the hysteresis curve to a set of predetermined curves developed and stored in advance.
5. The method of claim 4 , wherein said heating is conducted over temperature range below about 200° C.
6. The method of claim 1 , wherein said heating is conducted over temperature range below about 200° C.
7. The method of claim 1 , wherein said monitoring includes monitoring optical peaks and shifts of the optical peaks over the sensing time period and said step of determining determines identity or quantity of analyte from the shifts of the optical peaks.
8. The method of claim 1 , wherein said porous optical film comprises silicon.
9. The method of claim 8 , wherein said porous optical film is a photonic crystal.
10. The method of claim 1 , wherein said porous optical film comprises oxidized silicon.
11. The method of claim 1 , further comprising a step of changing the vapor pressure during said monitoring.
12. A method for sensing vapor, comprising steps of:
exposing a porous optical film to vapor which contains analyte;
heating the porous optical film;
monitoring an optical response of the porous optical film for a sensing time period during said heating; and
determining identity or quantity of the analyte from a response curve obtained during the sensing time period of said monitoring, further comprising ceasing said heating after a heating time period to cycle the porous optical film over a heating cycle and cooling cycle, wherein said sensing time period encompasses at least a portion of said heating cycle and said cooling cycle.
13. A method for sensing vapor, comprising steps of:
exposing a porous optical film to vapor which contains analyte;
heating the porous optical film;
monitoring an optical response of the porous optical film for a sensing time period during said heating; and
determining identity or quantity of the analyte from a response curve obtained during the sensing time period of said monitoring, wherein said determining comprises determining a hysteresis curve from the optical response and comparing the hysteresis curve to a set of predetermined curves developed and stored in advance.
14. A method for sensing vapor, comprising steps of:
exposing a porous optical film to vapor which contains analyte;
heating the porous optical film;
monitoring an optical response of the porous optical film for a sensing time period during said heating; and
determining identity or quantity of the analyte from a response curve obtained during the sensing time period of said monitoring, wherein the porous optical film comprises a Rugate filter.
15. A method for sensing vapor, comprising steps of:
exposing a porous optical film to vapor which contains analyte;
heating the porous optical film;
monitoring an optical response of the porous optical film for a sensing time period during said heating; and
determining identity or quantity of the analyte from a response curve obtained during the sensing time period of said monitoring, wherein said porous optical film comprises carbonized silicon.
16. The method of claim 15 , wherein the porous optical film comprises a Rugate filter.
17. A method for sensing vapor, comprising steps of:
exposing a porous optical film to a vapor which contains analyte;
heating the porous optical film;
monitoring on optical response of the porous optical film for a sensing time period during said heating for a shift in spectral position of an optical band gap during said exposing and heating;
ceasing said heating after a heating time period to cycle the porous optical film over a heating cycle and cooling cycle, wherein said monitoring encompasses at least a portion of said heating cycle and said cooling cycle;
identifying analyte in the vapor by comparing an observed shift in spectral position of the optical bandgap with a database of previously determined analyte specific shifts in spectral positions.
18. The method of claim 17 , further comprising quantifying analyte identified by said step of identifying.
19. The method of claim 17 , further comprising a step of changing the vapor pressure during said monitoring.
20. A system for sensing analyte in vapor, the system comprising:
a porous optical film;
a heater for heating the porous optical film;
an optical sensor for sensing optical response of the optical film; and
controllers and nontransient computer readable medium for storing code that performs the method of claim 17 .
21. A method for sensing vapor, comprising steps of:
adsorbing analyte into a porous optical film;
heating the porous optical film; and
monitoring on optical response of the porous optical film for a sensing time period during said heating for a shift in spectral position of an optical band gap during said adsorbing and heating;
wherein said heating comprises heating to a desorption temperature and the sensing time period covers a period of desorption; and
identifying analyte adsorbed into the porous optical film through one of changes in the wavelength position of the optical film's spectral peak(s), and rate of change, shape, or functional form of the sensor optical response.
22. The method of claim 21 , wherein said identifying comprises comparing an observed shift in spectral position of the optical bandgap with a database of previously determined analyte specific shifts in spectral positions.
23. The method of claim 22 , further comprising a step of changing the vapor pressure during said monitoring.