Method of fabricating membrane electrode assembly and gas diffusion layer
View Patent ↗A method of fabricating a membrane electrode assembly, comprising: obtaining a mixture by mixing and kneading electrically conductive particles, a polymer resin, a surfactant, and a dispersion solvent (S 1 ); obtaining a sheet-like mixture by rolling out and shaping the mixture (S 2 ); obtaining a carbon sheet by heat-treating the sheet-like mixture at a first heat treatment temperature such that the surfactant and the dispersion solvent are removed from the sheet-like mixture (S 3 ); obtaining a dispersion liquid by mixing electrically conductive particles, a polymer resin, a surfactant, and a dispersion solvent (S 4 ); forming, on the carbon sheet, a dispersion liquid layer thinner than the carbon sheet by forming and drying a coating of the dispersion liquid on the carbon sheet (S 5 ); obtaining a gas diffusion layer in which a carbon layer is formed on the carbon sheet, by heat-treating the carbon sheet on which the dispersion liquid layer is formed at a second heat treatment temperature lower than the first heat treatment temperature such that the surfactant and the dispersion solvent are removed from the dispersion liquid layer (S 6 ); and stacking a catalyst layer and an electrolyte membrane in said order on the carbon layer (S 7 ).
1. A method of fabricating a membrane electrode assembly, the method comprising:
obtaining a mixture by mixing first electrically conductive particles, a first polymer resin, a first surfactant, and a first dispersion solvent;
obtaining a sheet-like mixture by shaping the mixture;
obtaining a carbon sheet by heat-treating the sheet-like mixture at a first heat treatment temperature;
obtaining a dispersion liquid by mixing second electrically conductive particles, a second polymer resin, a second surfactant, and a second dispersion solvent;
forming, on the carbon sheet, a dispersion liquid layer thinner than the carbon sheet by forming and drying a coating of the dispersion liquid on the carbon sheet;
obtaining a gas diffusion layer in which a carbon layer is formed on the carbon sheet, by heat-treating the carbon sheet on which the dispersion liquid layer is formed at a second heat treatment temperature lower than the first heat treatment temperature, the second heat treatment temperature being lower than 260 degrees Celsius; and
stacking a catalyst layer and an electrolyte membrane in said order on the carbon layer.
2. The method of fabricating a membrane electrode assembly according to claim 1 , wherein the dispersion liquid layer is formed by spray coating.
3. The method of fabricating a membrane electrode assembly according to claim 1 , comprising:
bringing a stack structure, which is a stack of the electrolyte membrane and the catalyst layer, into contact with the gas diffusion layer such that the carbon layer and the catalyst layer come into contact with each other; and
performing thermocompression bonding at a third heat ent temperature lower than the second heat treatment temperature.
4. The method of fabricating a membrane electrode assembly according to claim 1 , wherein
the second surfactant is a non-ionic surfactant.
5. The method of fabricating a membrane electrode assembly according to claim 2 , wherein
the heat treatment at the second heat treatment temperature is performed in air.
6. The method of fabricating a membrane electrode assembly according to claim 1 , wherein
the carbon layer has a thickness of not less than 10 μm and not more than 100 μm, and
the second heat treatment temperature is not lower than a decomposition temperature of the second surfactant.
7. The method of fabricating a membrane electrode assembly according to claim 1 , wherein
the carbon sheet has a thickness of not less than 100 μm and not more than 1000 μm, and
the first heat treatment temperature is not lower than 260 degrees Celsius and not higher than a melting point of the polymer resin that serves as a raw material of the mixture.
8. The method of fabricating a membrane electrode assembly according to claim 1 , wherein a polymer resin content in the carbon layer is higher than a polymer resin content in the carbon sheet.
9. A method of fabricating a gas diffusion layer, the method comprising:
obtaining a mixture by mixing first electrically conductive particles, a first polymer resin, a first surfactant, and a first dispersion solvent;
obtaining a sheet-like mixture by shaping the mixture;
obtaining a carbon sheet by heat-treating the sheet-like mixture at a first heat treatment temperature;
obtaining a dispersion liquid by mixing second electrically conductive particles, a second polymer resin, a second surfactant, and a second dispersion solvent;
forming, on the carbon sheet, a dispersion liquid layer thinner than the carbon sheet by forming and drying a coating of the dispersion liquid on the carbon sheet; and
obtaining a gas diffusion layer in which a carbon layer is formed on the carbon sheet, by heat-treating the carbon sheet on which the dispersion liquid layer is formed at a second heat treatment temperature lower than the first heat treatment temperature, the second heat treatment temperature being lower than 260 degrees Celsius.
10. The method of fabricating a membrane electrode assembly according to claim 1 , wherein the second heat treatment temperature is not lower than 220 degrees Celsius.
11. The method of fabricating a membrane electrode assembly according to claim 1 , wherein the second heat treatment temperature is not lower than 240 degrees Celsius.
12. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the first electrically conductive particles contained in the mixture is not less than 10 wt % and not more than 50 wt %.
13. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the second electrically conductive particles contained in the dispersion liquid is not less than 1 wt % and not more than 30 wt %.
14. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the first polymer resin contained in the mixture is not less than 1 wt % and not more than 20 wt %.
15. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the second polymer resin contained in the dispersion liquid is not less than 0.1 wt % and not more than 10 wt %.
16. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the first surfactant contained in the mixture is not less than 0.1 wt % and not more than 5 wt %.
17. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the second surfactant contained in the dispersion liquid is not less than 0.1 wt % and not more than 5 wt %.
18. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the first dispersion solvent contained in the mixture is not less than 30 wt % and not more than 88 wt %.
19. The method of fabricating a membrane electrode assembly according to claim 1 , wherein an amount of the second dispersion solvent contained in the dispersion liquid is not less than 55 wt % and not more than 98 wt %.