Fuel part and process for preparation of a fuel part
The present invention relates to a fuel part, comprising a polymer composition comprising: i. a polyamide A, and ii. micro talcum in an amount of 0.001 to 1 weight percent with respect to the total amount of the polymer composition, wherein the polymer composition has a melt volume flow rate (MVR) of at most 70 cm 3 /10 min at a weight of 21.6 kg and at a temperature of T measure as measured according to ISO 1133. The invention also relates to a process for preparation of such fuel part wherein a blow-molding or roto-molding process is applied.
1. A blow-moulded or roto-moulded fuel part, wherein the fuel part is formed of a polymer composition comprising:
i. a polyamide A which is at least one polyamide selected from the group consisting of polyamide-6 (PA-6) and polyamide-66 (PA-66), and
ii. an amount of 0.05 to 0.5 weight percent with respect to the total amount of the polymer composition of micro talcum having a median diameter of less than 0.6 μm, wherein
the polymer composition has a melt volume flow rate (MVR) of at most 70 cm 3 /10 min at a weight of 21.6 kg and at a temperature of T measure as measured according to ISO 1133, and wherein
the polyamide A has a ratio of terminal carboxy group concentration to terminal amino group concentration which is equal to or greater than 1, and wherein
the fuel part exhibits a fuel permeation rate for a hydrocarbon fuel measured by a weight loss method according to ASTM E96BW using ASTM fuel CE10 which is at least 36% less than a comparable fuel part formed of an identical polymer composition not containing the micro talcum.
2. The fuel part according to claim 1 , wherein the MVR is at most 60 cm 3 /10 min.
3. The fuel part according to claim 1 , wherein the MVR is at most 50 cm 3 /10 min.
4. The fuel part according to claim 1 , wherein the amount of micro talcum is between 0.05 to 0.2 weight percent with respect to the total amount of the polymer composition.
5. The fuel part according to claim 1 , wherein the amount of micro talcum is between 0.05 to 0.1 weight percent with respect to the total amount of the polymer composition.
6. The fuel part according to claim 1 , wherein the polymer composition further comprises a polyamide B, wherein the polyamide B is polyamide-410 (PA410) in an amount of at least 0.1 wt % based on the total amount of the polymer composition.
7. A process for preparation of a fuel part according to claim 1 , wherein the process comprises forming the fuel part by blow-molding the polymer composition.
8. A fuel part which formed of a blow-moulded or roto-moulded polymer composition comprising:
i. a polyamide A which comprises at least one polyamide selected from the group consisting of polyamide polyamide-6 (PA-6) and polyamide-66 (PA-66), and
ii. an amount of 0.04 to 0.2 weight percent with respect to the total amount of the polymer composition of micro talcum having a median diameter of less than 0.6 μm, wherein
the polymer composition has a melt volume flow rate (MVR) of at most 70 cm 3 /10 min at a weight of 21.6 kg and at a temperature of T measure as measured according to ISO 1133, and wherein
the polyamide A has a ratio of terminal carboxy group concentration to terminal amino group concentration which is equal to or greater than 1, wherein
the fuel part exhibits a fuel permeation rate (P) of 2.4 gmm/m 2 day or less measured according to ASTM E96BW using ASTM fuel CE10.
9. The fuel part according to claim 8 , further comprising a blend of the polyamide A with a polyamide B, wherein the polyamide B is polyamide-410 (PA-410).
10. The fuel part according to claim 9 , wherein the polyamide B is present in an amount of at least 0.1 wt % based on the total amount of the polymer composition.
11. The fuel part according to claim 8 , wherein the MVR is at most 60 cm 3 /10 min.
12. The fuel part according to claim 8 , wherein the MVR is at most 50 cm 3 /10 min.
13. A process for preparation of a fuel part according to claim 8 , wherein the process comprises forming the fuel part by blow-molding the polymer composition.