IP Library Granted Patent US 9,537,139
Granted Patent B2
US 9,537,139 · App. 13/814,069 · Granted Jan 3, 2017

Negative electrode for non-aqueous secondary battery, and a non-aqueous secondary battery

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,537,139
App. No.
13/814,069
Granted
Jan 3, 2017
Kind
B2
Abstract

[Objectives] The present invention provides a non-aqueous secondary battery in which a material containing Si and O as constituent elements is used in a negative electrode. The present invention provides a non-aqueous secondary battery having good charge discharge cycle characteristics, and suppressing the battery swelling associated with the charge and the discharge. Also, the present invention relates to a negative electrode that can provide the non-aqueous secondary battery. [Solution] The negative electrode includes a negative electrode active material, including a composite of a material containing Si and O as constitution elements (atom ratio x of O to Si is 0.5≦x≦1.5) in combination with a carbon material, and graphite. The graphite has an average particle diameter dg (μm) of 4 to 20 μm. The material containing Si and O as constitution elements has an average particle diameter ds (μm) of 1 μm or more. The ratio ds/dg (i.e., ds to dg) is 0.05 to 1. The material containing Si and O as constitution elements has a crystallite diameter of 50 nm or less, the crystallite diameter is calculated from a half width at a (220) plane of Si obtained by an X-ray diffraction method, using Scherrer Formula. In 100 mass % of the composite of the material containing Si and O as constitution elements, and the carbon material, a ratio of the material containing Si and O as constitution elements is 70 to 95 mass %.

Claims (16)

1. A negative electrode for non-aqueous secondary battery, comprising:

a negative electrode active material, comprising

a composite consisting of SiO x , wherein atom ratio x of O to Si is 0.5≦x≦1.5, and a carbon material, and

graphite, and

wherein the graphite has an average particle diameter dg (μm) of 4 to 20 μm,

wherein the SiO x has an average particle diameter ds (μm) of 1 μm or more,

wherein a ratio ds/dg is 0.05 to 1,

wherein the SiO x has a crystallite diameter of 50 nm or less, the crystallite diameter is obtained from a half width at a (220) plane of Si obtained by an X-ray diffraction method, using Scherrer Formula,

wherein in 100 mass % of the composite, a ratio of the SiO x is 70 to 95 mass %.

2. The negative electrode for non-aqueous secondary battery of claim 1 , wherein in 100 mass % of a total of the composite and the graphite, a ratio of the graphite is 70 mass % or more.

3. The negative electrode for non-aqueous secondary battery of claim 1 , wherein in the composite, the carbon material has been obtained by thermolysis when heating a hydrocarbon gas in vapor phase.

4. A non-aqueous secondary battery, comprising

a positive electrode comprising a Li-containing transition metal oxide,

a negative electrode, and

a non-aqueous electrolyte,

wherein the negative electrode is the negative electrode for non-aqueous secondary battery of claim 1 .

Assignments (4)
CHANGE OF NAME Recorded Dec 3, 2021
From: MAXELL HOLDINGS, LTD.
To: MAXELL, LTD.
Reel/Frame 058301/0318 →
CHANGE OF NAME AND ADDRESS Recorded Feb 5, 2018
From: HITACHI MAXELL, LTD.
To: MAXELL HOLDINGS, LTD.
Reel/Frame 045243/0893 →
CHANGE OF NAME Recorded Jul 31, 2013
From: HITACHI MAXELL ENERGY, LTD
To: HITACHI MAXELL LTD.
Reel/Frame 030936/0279 →
CORRECTIVE ASSIGNMENT TO CORRECT THE APPLICATION NUMBER 13/814,067 PREVIOUSLY RECORDED ON REEL 029814 FRAME 0187. ASSIGNOR(S) HEREBY CONFIRMS THE APPLICATION NUMBER IS 13/814,069. Recorded Jun 3, 2013
From: TANAKA, NAOKAGE; INABA, AKIRA; UENAE, KEIICHIRO; YAMADA, MASAYUKI; MATSUMOTO, KAZUNOBU
To: HITACHI MAXELL ENERGY, LTD.
Reel/Frame 030537/0396 →