Process for treating liquid effluents and recovering metals
A method for treating liquid effluents and recovering metals is described, which comprises the steps of: a) liquid effluent equalization; b) sulphide addition and precipitation of metals in the form of metal sulphides; c) solid/liquid separation of the metal sulphides produced in step (b) and formation of a metal-free liquid phase; d) addition of a 50 to 250 g/L amine solution to the liquid phase precipitating magnesium in the form of magnesium hydroxide (Mg(OH)2); and e) recovery of amine by stripping and rectification.
1. A process for treating liquid effluents and recovering metals, comprising the steps of:
a) equalizing a liquid effluent;
b) adding sulfides and metal precipitation in the form of metal sulfides;
c) separating solid/liquid from the metal sulfides obtained in step (b) and forming a liquid phase free of metals;
d) adding amine solution comprising amine at a rate of 50 to 250 g/L to the liquid phase to produce a slurry comprising magnesium hydroxide —Mg(OH) 2 ; and
e) recovering the amine by depletion and rectification.
2. The process of claim 1 , wherein in step (d) adding the amine solution to the liquid phase occurs at a temperature of 25 to 70° C., solid content of 1 to 10% w/w, and residence time of 0.5 to 2 hours.
3. The process of claim 1 , wherein in step (d) the amine added comes from currents of recovered amine and replacement amine.
4. The process of claim 1 , wherein after step (d) and before step (e) the slurry comprising magnesium hydroxide is conducted to a thickener.
5. The process of claim 4 , wherein magnesium hydroxide is withdrawn from the thickener, transferred to a solid/liquid separator and washed with water.
6. The process of claim 5 , wherein the washed magnesium hydroxide is subject to a step of drying and calcination forming magnesia.
7. The process of claim 5 , wherein in step (e), the amine depletion comprises:
heating the thickener after the magnesium hydroxide is removed by low pressure steam to obtain i) a mass current comprising weak acids and traces of amide and ii) a current of amine-rich steams.
8. The process of claim 7 , wherein the mass current comprising the weak acids and the traces of amide is transferred to activated charcoal columns, in which residual amine is removed and resulting weak acids are transferred for storage.
9. The process of claim 7 , further comprising sending the current of amine-rich steams to the rectification step, heating with a low pressure steam current and condensing through heat exchangers to produce high quality recovered amine.
10. The process of claim 7 , wherein the pressure of the low pressure steam is 1 to 10 kgf/cm 2 .