Stiff polypropylene composition with excellent elongation at break
View Patent ↗Polypropylene composition comprising (a) a high melt strength polypropylene having a melt flow rate MFR2 (230° C.) of equal or below 15 g/10 min and a branching index g′ of below 1.0, (b) a first heterophasic propylene copolymer comprising a polypropylene having a melt flow rate MFR2 (230° C.) in the range of 50 to 500 g/10 min and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-% and an intrinsic viscosity (IV) of equal or more than 2.5 dl/g, (c) a second heterophasic propylene copolymer comprising a random propylene copolymer having a melt flow rate MFR2 (230° C.) in the range of 1 to 40 g/10 min, a branching index g′ of 1.0, and a comonomer content of more than 0.5 wt.-%, and an elastomeric propylene copolymer having a propylene content in the range of 50 to 80 wt.-%, and an intrinsic viscosity (IV) of equal or below 2.4 dl/g, (d) a polyethylene plastomer having an ethylene content of at least 50 wt.-%, and (e) a mineral filler (F).
1. Polypropylene composition comprising:
(A) a first heterophasic propylene copolymer (HECOI) comprising (i) a polypropylene (PP1) having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 50 to 500 g/10 min, and (ii) an elastomeric propylene copolymer (E1) having (a) a propylene content in the range of 50 to 80 wt. %, and (b) an intrinsic viscosity (IV) measured according to ISO 1628-1 (at 135° C. in decaline) of equal or more than 2.5 dl/g, (B) a high melt strength polypropylene (HMS-PP) having (i) a branching index g′ of below 1.0, and (ii) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of equal or below 15 g/10 min, (c) a second heterophasic propylene copolymer (HECO2) comprising (i) a random propylene copolymer (R-PP2) having (a) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 1 to 40 g/10 min, a branching index g′ being higher than the branching index g′ of the high melt strength polypropylene (HMS-PP), and (c) a comonmer content of equal or more than 0.5 wt. %, the comonomers are ethylene and/or C 4 to C 12 α-olefins, (ii) an elastomeric propylene copolymer (E2) having (a) a propylene content in the range of 50 to 80 wt. %, and (b) an intrinsic viscosity (IV) measured according to ISO 1628-1 (at 135° C. in decaline) of equal or below 2.4 dl/g,(d) a polyethylene plastomer (PE) having (i) an ethylene content of at least 50 wt. %, and (ii) a density measured according to ISO 1183-187 in the range of 820 to 920 kg/m 3 , and (e) a mineral filler (F).
2. Polypropylene composition according to claim 1 , wherein the composition has (a) a melt flow rate MFR 2 (230° C.) measured according to according to ISO 1133 in the range of 5 to 50 g/10 min, and/or (b) a tensile modulus measured according to ISO 527-3 of at least 1500 MPa and/or (c) a tensile strain at break measured according to ISO 527-3 of at least 200%.
3. Polypropylene composition according to claim 1 , wherein the first heterophasic propylene copolymer (HECO1) has (a) a melt flow rate MFR 2 (230° C.) measured according to according to ISO 1133 in the range of 15 to 70 g/10 min, and/or (b) a xylene cold soluble (XCS) fraction measured according to ISO 6427 of 15.0 to 50.0 wt. %.
4. Polypropylene composition according to claim 1 , wherein the second heterophasic propylene copolymer (HECO2) has (a) a melt flow rate MFR 2 (230° C.) measured according to according to ISO 1133 in the range of 1 to below 15 g/10 min, and/or (b) a xylene cold soluble (XCS) fraction measured according to ISO 6427 of 10.0 to 35.0 wt. %.
5. Polypropylene composition according to claim 1 , wherein (a) the polypropylene (PP1) is a propylene homopolymer (H-PP1) and/or (b) the random propylene copolymer (R-PP2) has a comonomer content in the range of 0.5 to 5.0 wt. %, the comonmers are ethylene and optionally at least one C 4 to C 12 α-olefin.
6. Polypropylene composition according to claim 1 , wherein (a) the comonmers of the elastomeric propylene copolymers (E1) and (E2) are identical, and/or (b) the first heterophasic propylene copolymer (HECO1) and/or the second heterophasic propylene copolymer (HECO2) comprise a polymeric α-nucleating agent selected from the group consisting of vinylcycloalkane polymer and/or vinylalkane polymer.
7. Polypropylene composition according to claim 1 , wherein the high melt strength polypropylene (HMS-PP) has (a) a strain hardening behavior with a haul-off force F max of at least 10.0 cN and a draw down velocity V max of at least 200 mm/s, and/or (b) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of 0.5 to 10.0 g/10 min.
8. Polypropylene composition according to claim 1 , wherein the high melt strength polypropylene (HMS-PP) (a) comprises units derived from (i) propylene and (ii) bifunctionally unsaturated monomer(s) and/or multifunctionally unsaturated low molecular weight polymer(s), and/or (b) has a xylene hot insoluble fraction (XHI) of not more than 1.0 wt. %.
9. Polypropylene composition according to claim 1 , wherein the polyethylene plastomer (PE) is an elastomeric ethylene-octene copolymer.
10. Polypropylene composition according to claim 1 , wherein the mineral filler (F) is talc.
11. Polypropylene composition according to claim 1 , wherein the composition comprises an α-nucleating agent (NA) selected from the group consisting of (a) salts of monocarboxylic acids and polycarboxylic acids, (b) dibenzylidenesorbitol and C 1 -C 8 -alkyl-substituted dibenzylidenesorbitol derivatives, (c) substituted nonitol-derivatives, (d) salts of diesters of phosphoric acid, (e) trisamide-benze derivatives, and (f) mixtures thereof.
12. Polypropylene composition according to claim 1 , wherein the composition comprises (a) 40 to 70 wt. % of the first heterophasic propylene copolymer (HECO1), (b) 10 to 40 wt. % of the second heterophasic propylene copolymer (HECO2) (c) 1 to 10 wt. % of the high melt strength polypropylene (HMS-PP), (d) 1 to 10 wt.% of the polyethylene plastomer (PE), (e) 5 to 30 wt. % of the mineral filler (F), and (f) optionally 0.0005 to 1.0 wt. % of the nucleating agent (NA).
13. Polypropylene composition being a heterophasic system comprising:
(a) a high melt strength polypropylene (HMS-PP) having (i) a branching index g′ of below 1.0, and (ii) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of equal or below 15 g/10 min,(b) a polypropylene (PP1) having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 50 to 500 g/10 min, (c) a random propylene copolymer (R-PP2) having (i) a melt flow rate MFR 2 (230° C.) measured according to according to ISO 1133 in the range of 1 to 40g/10 min, (ii) a branching index g′ being higher than the branching index g′ of the high melt strength polypropylene (HMS-PP), and (iii) a comonmer content of equal or more than 0.5 wt. %, the comonomers are ethylene and/or C 4 to C 12 α-olefins, (d) an elastomeric propylene copolymer system having (i) a propylene content in the range of 50 to 80 wt. %, and (ii) an intrinsic viscosity (IV) measured according to ISO 1628-1 (at 135° C. in decaline) in the range of 2.0 to 3.0 dl/g, (e) a polyethylene plastomer (PE) having (i) an ethylene content of at least 50 wt. %, and (ii) a density measured according to ISO 1183-187 in the range of 820 to 920 kg/m 3 , and (f) a mineral filler (F), wherein the polypropylene (PP1), the random propylene copolymer (R-PP2), and the high melt strength polypropylene (HMS-PP) constitute the matrix of the heterophasic system in which the elastomric propylene copolymer system, the polyethylene plastomer (PE) and the mineral filler (F) are dispersed, and wherein further the polypropylene composition has (g) a tensile modulus measured according to ISO 527-3 of at least 1500 MPa and (h) tensile strain at break measured according to ISO 527-3 of at least 200%.
14. Automotive article comprising a composition according to claim 1 .
15. Process for producing a composition according to claim 1 , comprising the step of mixing up of the first heterophasic propylene copolymer (HECO1), the second heterophasic propylene copolymer (HECO2), the high melt strength polypropylene (HMS-PP), the polyethylene plastomer (PE), the mineral filler (F), and optionally the a-nucleating agent (NA) in an extruder.