Catalyst and method for the production of chlorine by gas phase oxidation
View Patent ↗The present invention relates to a catalyst for preparation of chlorine by catalytic gas phase oxidation of hydrogen chloride with oxygen, in which the catalyst comprises calcined tin dioxide as a support and at least one halogen-containing ruthenium compound, and to the use thereof.
1. A catalyst composition comprising tin dioxide as a support material and a ruthenium-containing compound as a catalytically active material, wherein the support material has been subjected, prior to the application of the catalytically active material, to a calcination in the presence of oxidizing gases at a temperature of at least 450° C., wherein the tin dioxide is more than 90% in the cassiterite structure.
2. The composition of claim 1 , wherein the ruthenium-containing compound is a halogen- and/or oxygen-containing ruthenium compound.
3. The composition of claim 2 , wherein the halogen in the ruthenium-containing compound is selected from the group consisting of chlorine, bromine, and iodine.
4. The composition of claim 2 , wherein the catalyst composition is obtained by calcining the support material laden with a halogen-containing ruthenium compound at a temperature of at least 200° C.
5. The composition of claim 4 , wherein the proportion of ruthenium from the halogen-containing ruthenium compound in relation to the overall catalyst composition is 0.5 to 5% by weight.
6. The composition of claim 1 , wherein the catalytically active ruthenium-containing compound is selected from the group consisting of ruthenium chloride, ruthenium oxychloride, and mixtures of ruthenium chloride and ruthenium oxide.
7. The composition of claim 6 , wherein the catalytically active ruthenium-containing compound is a mixed compound corresponding to the formula RuClxOy wherein x is a number from 0.8 to 1.5 and y is a number from 0.7 to 1.6.
8. The composition of claim 1 , wherein the temperature in the course of calcination of the support material prior to application of the catalytically active material is at least 500° C.
9. The composition of 1 , wherein the duration of calcination of the support material prior to application of the catalytically active material has been conducted over 0.5 to 10 hours.
10. The composition of claim 1 , wherein the oxidizing gases in the calcination of the support material prior to application of the catalytically active material have an oxygen content in the range of from 10% by volume to 50% by volume.
11. The composition of claim 1 , wherein the catalyst is obtained by a process comprising removing solvent by drying at a temperature of at least 80° C.
12. A process for preparing chlorine comprising the step of catalytically oxidizing hydrogen chloride in the gas phase with oxygen over a solid catalyst, wherein the catalyst is the composition of claim 1 .
13. The process of claim 12 , wherein the catalytically oxidizing hydrogen chloride in the gas phase comprises passing a gas comprising hydrogen chloride and oxygen at a temperature of 180 to 500° C. and the chlorine formed is separated from the water of reaction and any unconverted oxygen and hydrogen chloride.
14. The process of claim 12 , wherein the catalytically oxidizing hydrogen chloride in the gas phase is conducted at a pressure of 1 to 25 bar.
15. The process of claim 12 , wherein the gas phase oxidation is conducted adiabatically or isothermally.
16. A process for preparing a catalyst comprising calcining a tin dioxide containing support material in the presence of an oxidizing gas at a temperature of at least 450° C. and applying at least one ruthenium-containing compound as a catalytically active material to the calcined tin dioxide containing support material, wherein the tin dioxide is more than 90% in the cassiterite structure.
17. The process of claim 16 , wherein the calcining time is from 30 min to 24 hours.