POST-ADDED BUILDER COMPOSITION
A builder that is a post-manufacture addition to detergent compositions includes a total soluble salt content of about 70 wt. % to about 90 wt. %, wherein about 40 wt. % to about 90 wt. % of the soluble salts are in the form of an alkali carbonate; about 2 wt. % to about 12 wt. % polycarboxylate co-builder; and about 2 wt. % to about 12 wt. % water for solubility and bulk density control. The builder will be added to a detergent (active surfactant) composition in an amount of about 5 wt. % to about 40 wt. %, preferably about 10 wt. % to about 30 wt. %, more preferably about 15 wt. % to about 25 wt. %, and most preferably about 20 wt. % of the detergent composition based on the total weight of detergent and builder. Generally, a higher percentage of builder composition achieves better results when the wash water is harder (contains higher levels of calcium and/or magnesium, e.g. 400 ppm calcium carbonate).
1 . A co-granulated, phosphate-free detergent builder composition, in particle form, for post addition to a detergent composition, said builder particles having no anionic or non-ionic surfactant contained therein and having an improved dissolution rate at low temperatures and a lower fabric encrustation or redeposition rate when added to a detergent composition containing an anionic and/or non-ionic active detergent surfactant comprising:
an alkali metal water soluble salt selected from the group consisting of carbonate, bicarbonate, sequicarbonate, citrate, sulfate, and combinations thereof in an amount of 40 wt. % to 90 wt. %, based on the total weight of the composition;
a polycarboxylate co-builder, having a number average molecular weight in the range of about 1,000 to about 60,000, in an amount of about 2 wt. % to about 12 wt. %, based on the total weight of the composition; and
water in an amount of about 2 wt. % to about 12 wt. %, based on the total weight of the composition.
2 . The detergent builder composition of claim 1 , wherein the alkali metal water-soluble salt is a combination of an alkali metal carbonate, in an amount of about 30 wt. % to about 60 wt. %; an alkali metal bicarbonate and/or an alkali metal sequicarbonate in an amount of about 3 wt. % to about 15 wt. %; an alkali metal citrate in an amount of about 5 wt. % to about 29 wt. %; and an alkali metal sulfate and/or alkali metal sulfonate in an amount of about 20 wt. % to about 40 wt. %, based on the total weight of water soluble salts in the builder composition.
3 . The detergent builder composition of claim 2 wherein the water-soluble salts, in powder form, are combined with water in an amount of about 2 wt. % to about 12 wt. %, and the polycarboxylate co-builder, in an amount of about 2 wt. % to about 12 wt. %, and sheared together to agglomerate the powdered salts, water and polycarboxylate co-builder into a co-granulated builder composition.
4 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder has a number average molecular weight in the range of about 3,000 to about 20,000.
5 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder has a number average molecular weight in the range of about 4,000 to about 10,000.
6 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder has a number average molecular weight in the range of about 5,000 to about 7,000.
7 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder is a polymer polymerized from one or more monomers selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, maleic anhydride, 2-acrylanido-2-methylpropane, fumaric acid, mesoconic acid, itaconic acid, glutamic acid, mixtures and copolymers thereof.
8 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder is a co-polymer of two or more monomers selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, maleic anhydride, 2-acrylanido-2-methylpropane, fumaric acid, mesoconic acid, itaconic acid, glutamic acid, mixtures thereof.
9 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder is a copolymer of 60 to 90 mole percent acrylic acid and 10 to 40 mole percent maleic acid.
10 . The detergent builder composition of claim 1 , wherein the polycarboxylate is a copolymer polymerized from a molar majority of acrylic acid and a molar minority of maleic anhydride.
11 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder is a copolymer of acrylic acid and maleic acid wherein the molar percentages of acrylic acid and maleic acid are about 65% to 85% acrylic acid and about 15% to 35% maleic acid.
12 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder is a copolymer of acrylic acid and maleic acid wherein the molar percentages of acrylic acid and maleic acid are about 60% to 90% acrylic acid and about 10% to 40% maleic acid.
13 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder is a copolymer of acrylic acid and maleic acid where in the molar percentages of acrylic acid and maleic acid are about 80% acrylic acid and about 20% maleic acid.
14 . The detergent builder composition of claim 1 , wherein the water-soluble salt comprises about 40 wt. % to about 95 wt. % alkali metal carbonate; about 5 wt. % to about 10 wt. % alkali metal bicarbonate; about 10 wt. % to about 15 wt. % alkali metal citrate; and about 25 wt. % to about 40 wt. % alkali metal sulfate or alkali metal sulfonate.
15 . The detergent builder composition of claim 1 , wherein the alkali metal salt is selected from the group consisting of sodium carbonate; sodium bicarbonate; trisodium citrate; sodium sulfate; sodium sulfonate; and combinations thereof.
16 . The detergent builder composition of claim 15 , wherein the water-soluble salt is a combination of about 30 wt. % to about 60 wt. % sodium carbonate; about 3 wt. % to about 15 wt. % sodium bicarbonate; about 5 wt. % to about 20 wt. % trisodium citrate; and about 20 wt. % to about 40 wt. % sodium sulfate based on the total weight of water-soluble salt in the builder composition.
17 . The detergent builder composition of claim 16 , wherein the water-soluble salt comprises about 40 wt. % to about 55 wt. % sodium carbonate; about 5 wt. % to about 10 wt. % sodium bicarbonate; about 10 wt. % to about 15 wt. % trisodium citrate; and about 25 wt. % to about 40 wt. % sodium sulfate.
18 . The detergent builder composition of claim 1 , wherein the polycarboxylate co-builder is a copolymer comprising a molar majority of acrylic acid monomer and a molar minority of one or more co-monomers selected from the group consisting of methacrylic acid, maleic acid, maleic anhydride, 2-acrylanido-2-methylpropane, fumaric acid, mesoconic acid, itaconic acid, glutamic acid, mixtures and copolymers thereof.
19 . The detergent builder composition of claim 18 wherein acrylic acid comprises about 70-90 mole % of the copolymer.
20 . A method of reducing fabric encrustation and/or increasing stain removal properties of a powdered or granular laundry detergent composition comprising adding to said laundry detergent composition about 5 wt. % to about 40 wt. % of the co-granulated detergent builder composition of claim 1 .
21 . A method of reducing fabric encrustation during a process of washing fabric comprising washing the fabric in wash water containing a laundry detergent composition that includes, as a post-manufactured additive, about 5 wt. % to about 40 wt. % of the co-granulated detergent builder composition of claim 1 .
22 . The method of claim 20 , wherein the detergent builder composition is added to the laundry detergent composition in an amount of about 10 wt. % to about 30 wt. %, based on the total weight of laundry detergent composition and detergent builder composition.
23 . The method of claim 22 , wherein the detergent builder composition is added to the laundry detergent composition in an amount of about 15 wt. % to about 25 wt. %, based on the total weight of laundry detergent composition and detergent builder composition.
24 . A method of manufacturing a powdered or granular laundry detergent formulation comprising anionic and/or non-ionic detergent active raw materials by drying said detergent active raw materials from an aqueous slurry or by pre-mixing the detergent active raw materials and then agglomerating and drying the raw materials to form a laundry detergent composition; and thereafter, mixing into the dried laundry detergent composition the detergent builder composition of claim 1 , to form the laundry detergent formulation.