Electrode for electrochemical capacitor and electrochemical capacitor using same
View Patent ↗A negative electrode for an electrochemical capacitor includes a current collector having electric conductivity, and an electrode layer formed on a surface of the current collector and having cations stored therein. In at least a part of the electrode layer, a value of ratio I a /I b of peak value I a indicating a presence of an anion decomposition compound and peak value I b indicating a presence of an electrolyte in a spectrum of an atom forming the anion is 0.45 or more and less than 2.55 as measured using X-ray photoelectron spectroscopy.
1. An electrode for an electrochemical capacitor, comprising:
a current collector having electric conductivity; and
an electrode layer formed on a surface of the current collector, having a cation stored therein, and including an anion,
wherein in at least a part of the electrode layer, a value of I a /I b falls within a range of 0.45 or more and less than 2.55,
where I a and I b are peak values measured by X-ray photoelectron spectroscopy method in a spectrum of an atom forming the anion, and I a indicates a presence of a decomposition compound of the anion and peak value I b indicates a presence of an electrolyte composed of the cation and the anion.
2. The electrode for electrochemical capacitor according to claim 1 ,
wherein in at least a part of the electrode layer, the I a is a peak value in a range of 130 eV or more and less than 135 eV in a spectrum of P2p, and the I b is a peak value in a range from 135 eV to 140 eV, inclusive, in the spectrum of P2p.
3. The electrode for electrochemical capacitor according to claim 1 ,
wherein in at least a part of the electrode layer, a value of I c /I d falls within a range of 0.50 or more and less than 2.20,
where I c and I d are peak values measured by X-ray photoelectron spectroscopy method in a spectrum of F1s, and I c is a peak value in a range form 685 eV to 690 eV, inclusive, I d is a peak value in a range of 680 eV or more and less than 685 eV.
4. An electrochemical capacitor comprising:
a capacitor element including:
a positive electrode including a first current collector having electric conductivity, and a first electrode layer formed on a surface of the first current collector;
a negative electrode including a second current collector having electric conductivity, and a second electrode layer formed on a surface of the second current collector; and
a separator interposed between the positive electrode and the negative electrode,
an electrolytic solution with which the capacitor element is impregnated and which includes an electrolyte containing a cation and an anion; and
an exterior member housing the capacitor element and the electrolytic solution,
wherein the first electrode layer is capable of adsorbing and desorbing the anion,
the second electrode layer has the cation stored therein, and
in at least a part of the second electrode layer, a value of I a /I b falls within a range of 0.45 or more and less than 2.55,
where I a and I b are peak values measured by X-ray photoelectron spectroscopy method in a spectrum of an atom forming the anion, and I a indicates a presence of a decomposition compound of the anion and peak value I b indicates a presence of the electrolyte.
5. The electrochemical capacitor according to claim 4 ,
wherein in at least a part of the second electrode layer, the I a is a peak value in a range of 130 eV or more and less than 135 eV in a spectrum of P2p, and the I b is a peak value in a range from 135 eV to 140 eV, inclusive, in the spectrum of P2p.
6. The electrochemical capacitor according to claim 4 ,
wherein in at least a part of the second electrode layer, a value of I c /I d falls within a range of 0.50 or more and less than 2.20,
where I c and I d are peak values measured by X-ray photoelectron spectroscopy method in a spectrum of F1s, and I c is a peak value in a range form 685 eV to 690 eV, inclusive, I d is a peak value in a range of 680 eV or more and less than 685 eV.