Positive electrode active material for a lithium secondary battery, method for producing same, and lithium secondary battery comprising same
The present invention relates to a positive electrode active material for a lithium secondary battery having improved thermal stability, a method for producing the positive electrode active material, and a lithium secondary battery containing the same. The positive electrode active material may be represented by the following Chemical Formula 1 and contain particles having an average particle size of 200 nm to 1 μm, wherein the surfaces of the particles are coated with a uniform carbon coating layer. Li a Mn 1-x M x PO 4 [Chemical Formula 1] (Where, M is any one or a mixture of two or more selected from Mg, Fe, Co, Cr, Ti, Ni, Cu, Zn, Zr, Nb, and Mo, and a and x satisfy the following Equations: 0.9≦a≦1.1 and 0≦x<0.5.).
1. A positive electrode active material for a lithium secondary battery comprising particles represented by the following Chemical Formula 1 and having an average particle size of 200 nm to 1 μm, wherein surfaces of the particles are coated with a carbon coating layer having a thickness of 5 to 10 nm,
Li 0.9 Mn 1-x Fe x PO 4 [Chemical Formula 1]
where x satisfies the following Equations: 0.1<x<0.2, and
wherein the positive electrode active material has a capacity of greater than or equal to 160 mAh/g as measured at charging and discharging voltages of 2.7 V to 4.4 V at 0.1 C.
2. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the carbon coating layer is made of amorphous carbon.
3. A lithium secondary battery comprising:
a positive electrode containing the positive electrode active material of claim 1 ;
a negative electrode containing a negative electrode active material; and
a non-aqueous electrolyte solution.
4. A method for producing a positive electrode active material for a lithium secondary battery, the method comprising:
adding a lithium raw material, a manganese raw material, a phosphorus raw material, and an iron raw material to anhydrous ethanol to prepare a metal mixed solution;
milling the metal mixed solution to atomize the metal mixed solution and form an atomized solution;
adding a carbon raw material to the atomized solution and uniformly mixing the carbon raw material with the atomized solution to form a mixture; and
performing heat-treatment on the mixture under an inert atmosphere to form a positive electrode active material for a lithium secondary battery comprising particles represented by the following Chemical Formula 1 and having an average particle size of 200 nm to 1 μm, wherein surfaces of the particles are coated with a carbon coating layer having a thickness of 5 to 10 nm,
Li 0.9 Mn 1-x Fe x PO 4 [Chemical Formula 1]
where x satisfies the following Equations: 0.1≦x≦0.2.
5. The method of claim 4 , wherein at the time of preparing the metal mixed solution, a content of anhydrous ethanol is in a range of 1:1 to 10 by weight ratio based on the total weight of the lithium raw material, the manganese raw material, and the phosphorus raw material, or in a range of 50 to 200 mole % based on the manganese raw material.
6. The method of claim 4 , wherein a mixing ratio of the lithium raw material, the manganese raw material, and the phosphorus raw material is adjusted so that a molar ratio of Li:Mn:P 0.9 : 0.85 to 0.9 : 1.
7. The method of claim 4 , wherein the content of the iron raw material is 10 mole % or more and smaller than 20 mole % when the total amount of the lithium raw material, the manganese raw material, the phosphorus raw material, and the iron raw material is defined as 100 mole %.
8. The method of claim 4 , wherein the carbon raw material is any one or a mixture of two or more selected from soft carbon (low-temperature fired carbon), pitch carbide, mesophase pitch carbide, fired cokes, citric acid, ascorbic acid, polyvinyl alcohol, urea, sucrose, glucose, and cellulose.
9. The method of claim 4 , wherein the heat-treatment under the inert atmosphere is performed at 500 to 800° C.