Shell-and-tube reactor for carrying out catalytic gas phase reactions
View Patent ↗A tube bundle reactor for carrying out catalytic gas phase reactions, particularly methanation reactions, has a bundle of catalyst-filled reaction tubes through which reaction gas flows and around which heat carrier flows during operation. In the region of the catalyst filling, the reaction tubes run through at least two heat carrier zones which are separated from one another, the first of which heat carrier zones extends over the starting region of the catalyst filling. The reaction tubes each have a first reaction tube portion with a first hydraulic diameter of the catalyst filling and, downstream thereof in flow direction of the reaction gas, at least a second reaction tube portion with a second hydraulic diameter of the catalyst filling that is greater than the first hydraulic diameter of the catalyst filling.
1. A tube bundle reactor for carrying out a catalytic gas phase reaction, comprising:
a bundle of catalyst-filled reaction tubes through which a reaction gas flows and around which a heat carrier flows during operation; and
at least two heat carrier zones separated from one another, wherein:
in a region of a catalyst filling, the reaction tubes run through the at least two heat carrier zones,
a first of the at least two heat carrier zones extends over a starting region of the catalyst filling,
during operation heat carrier temperatures for the at least two heat carrier zones can be adjusted in such a way that the heat carrier temperatures decrease from zone to zone in a flow direction of the reaction gas,
each of the reaction tubes has a first reaction tube portion with a first hydraulic diameter of the catalyst filling and, downstream thereof in the flow direction of the reaction gas, at least a second reaction tube portion with a second hydraulic diameter of the catalyst filling that is greater than the first hydraulic diameter of the catalyst filling,
the first reaction tube portion extends along the starting region of the catalyst filling and into the second of the at least two heat carrier zones,
every reaction tube has a constant inner diameter over its entire length and a displacer arranged at least in the first reaction tube portion,
the displacer includes a tube, the displacer tube including at least one inflow opening and at least one outflow opening through which a portion of the reaction gas flows while bypassing the catalyst filling, and
all of the outflow openings are located in the first heat carrier zone.
2. The tube bundle reactor according to claim 1 , wherein the catalytic gas phase reaction includes a methanation reaction.
3. The tube bundle reactor according to claim 1 , wherein the first hydraulic diameter of the catalyst filling of the first reaction tube portion is in a range of 10 mm to 22 mm.
4. The tube bundle reactor according to claim 1 , wherein the at least one inflow opening is located upstream of a starting surface of the catalyst filling.
5. The tube bundle reactor according to claim 1 , wherein a distance between a final one of the outflow openings in the flow direction of the reaction gas and a downstream end of the first heat carrier zone is at least 10% of a length of the first heat carrier zone.
6. The tube bundle reactor according to claim 1 , wherein the tube bundle reactor includes exactly two heat carrier zones.
7. The tube bundle reactor according to claim 1 , wherein the first heat carrier zone extends over 15% to 40% of a length of one of the reaction tubes.