Graphene-coated steel sheet, and method for manufacturing same
View Patent ↗A graphene-coated steel sheet and a method for manufacturing the same are provided. The graphene-coated steel sheet includes a steel sheet and a graphene layer formed on the steel sheet. Therefore, the graphene-coated steel sheet can be useful in preventing corrosion of iron, such as oxidation of iron, and has remarkably excellent thermal conductivity and electrical conductivity, as well as excellent heat resistance resulting from thermal stability of graphene. Also, the method can be useful in manufacturing a high-quality graphene-coated steel sheet having a monocrystalline form and showing substantially no defects or impurities.
1. A graphene-coated steel sheet comprising:
a steel sheet including carbon; and
a graphene layer formed on the steel sheet,
wherein a graphene domain of the graphene layer has an average diameter of 300 to 1000 Å, and
the graphene-coated steel sheet satisfies the following Expression 1:
X≦0.8 eV, Expression 1
wherein X represents a full width at half maximum (FWHM) of graphene included in the steel sheet on the 1S core level spectra of carbon (C) as measured using a high-resolution photoelectron spectrometer (HRPES).
2. The graphene-coated steel sheet of claim 1 , wherein X is 0.2 eV to 0.8 eV.
3. The graphene-coated steel sheet of claim 1 , wherein a graphene domain of the graphene layer has two dominant domain directions.
4. The graphene-coated steel sheet of claim 1 , wherein the graphene layer is formed in a single-layer or multilayered structure.
5. The graphene-coated steel sheet of claim 4 , wherein the multilayered structure is composed of 2 to 10 layers.
6. The graphene-coated steel sheet of claim 1 , wherein a graphene domain of the graphene layer is a monocrystalline or polycrystalline form.
7. The graphene-coated steel sheet of claim 1 , wherein carbon (C) remaining in an intermediate layer at an interface between the steel sheet and the graphene layer is present at a content of 15 parts by weight or less, based on 100 parts by weight of the carbon included in a single graphene layer.
8. The graphene-coated steel sheet of claim 1 , wherein sulfur (S) remaining in an interface between the steel sheet and the graphene layer is present at a content of 4 parts by weight or less, based on 100 parts by weight of the carbon included in a single graphene layer.
9. A method for manufacturing a graphene-coated steel sheet, comprising:
washing a surface of a steel sheet including carbon in a vacuum container with inert gas ions by repeatedly performing inert gas ion sputtering and electron beam heating on the surface of the steel sheet; and
forming a graphene layer on the steel sheet by heating the washed steel sheet at a temperature in a range of 400° C. to 1100° C. and injecting hydrocarbon into the vacuum container to dissociatively absorb the hydrocarbon onto the steel sheet by crystallizing the carbon,
wherein a graphene domain of the graphene layer has an average diameter of 300 to 1000 Å.
10. The method of claim 9 , wherein a pressure in the vacuum container in the washing of the surface of the steel sheet is in a range of 10 −5 Pa to 10 −2 Pa.
11. The method of claim 9 , wherein repeated inert gas ion sputtering and electron beam heating on the surface of the steel sheet is performed 10 to 200 times.
12. The method of claim 9 , wherein carbon (C) remaining on a surface of the washed steel sheet is present at a content of 15 parts by weight or less, based on 100 parts by weight of the carbon included in a single graphene layer.
13. The method of claim 9 , wherein sulfur (S) remaining on a surface of the washed steel sheet is present at a content of 4 parts by weight or less, based on 100 parts by weight of the carbon included in a single graphene layer.
14. The method of claim 9 , wherein a heating temperature of the washed steel sheet is in a range of 500° C. to 900° C.
15. The method of claim 9 , wherein the hydrocarbon is injected at an amount of 10 Langmuirs or more.
16. The method of claim 9 , wherein the hydrocarbon is an alkyne-based hydrocarbon, an alkene-based hydrocarbon, or an alkane-based hydrocarbon.
17. A method for manufacturing a graphene-coated steel sheet, comprising:
washing a surface of a steel sheet including carbon in a vacuum container with inert gas ions by repeatedly performing inert gas ion sputtering and electron beam heating on the surface of the steel sheet; and
forming a graphene layer on the steel sheet by heating the washed steel sheet at a temperature in a range of 400° C. to 1100° C. to separate carbon included in the steel sheet by crystallizing the carbon,
wherein a graphene domain of the graphene layer has an average diameter of 300 to 1000 Å.
18. The method of claim 17 , wherein a pressure in the vacuum container in the washing of the surface of the steel sheet is in a range of 10 −5 Pa to 10 −2 Pa.
19. The method of claim 17 , wherein repeated inert gas ion sputtering and electron beam heating on the surface of the steel sheet is performed 10 to 200 times.
20. The method of claim 17 , wherein carbon (C) remaining on a surface of the washed steel sheet is present at a content of 15 parts by weight or less, based on 100 parts by weight of the carbon included in a single graphene layer.
21. The method of claim 17 , wherein sulfur (S) remaining on a surface of the washed steel sheet is present at a content of 4 parts by weight or less, based on 100 parts by weight of the carbon included in a single graphene layer.
22. The method of claim 17 , wherein a heating temperature of the washed steel sheet is in a range of 500° C. to 900° C.