High-strength steel material having outstanding ultra-low-temperature toughness and a production method therefor
The present invention provides steel containing manganese and nickel that is used as a structural material for a cryogenic storage container for liquefied natural gas (LNG) or the like, and a manufacturing method thereof; and more particularly, to steel having good cryogenic temperature toughness and also high strength by adding low-cost Mn instead of relatively expensive Ni at an optimized ratio, refining a microstructure through controlled rolling and cooling, and precipitating retained austenite through tempering, and a manufacturing method of the steel. To achieve the object, the technical feature of the present invention is a method of manufacturing high-strength steel with cryogenic temperature toughness. In the method, a steel slab is heated to a temperature within a range of 1,000 to 1,250° C., wherein the steel slab includes, by weight: 0.01-0.06% of carbon (C), 2.0-8.0% of manganese (Mn), 0.01-6.0% of nickel (Ni), 0.02-0.6% of molybdenum (Mo), 0.03-0.5% of silicon (Si), 0.003-0.05% of aluminum (Al), 0.0015-0.01% of nitrogen (N), 0.02% or less of phosphorous (P), 0.01% or less of sulfur (S), with a remainder of iron (Fe) and other unavoidable impurities. Then, the heated slab is finish-rolled at a temperature of 950° C. or less at a rolling reduction rate of 40% or more. The rolled steel is cooled to a temperature of 400° C. or less at a cooling rate of 2° C./s or more. Thereafter, the steel is tempered for 0.5-4 hours to a temperature within a range of 550 to 650° C. after the cooling.
1. High-strength steel with good cryogenic temperature toughness, comprising, by weight: 0.01-0.06% of carbon (C), 2.4-8.0% of manganese (Mn), 0.01-6.0% of nickel (Ni), 0.02-0.6% of molybdenum (Mo), 0.03-0.5% of silicon (Si), 0.003-0.05% of aluminum (Al), 0.0015-0.01% of nitrogen (N), 0.02% or less of phosphorous (P), 0.01% or less of sulfur (S), with a remainder of iron (Fe) and other unavoidable impurities,
wherein the Mn and Ni satisfy the condition of 8≦1.5×Mn+Ni≦12, and
wherein the steel has a yield strength of 500 MPa or more and a cryogenic impact energy of 70 J or more at −196° C. or less.
2. The high-strength steel with good cryogenic temperature toughness of claim 1 , further comprising, by weight, at least one selected from the group consisting of 0.003-0.055 of titanium (Ti), 0.1-5.0% of chromium (Cr) and 0.1-3.0% of copper (Cu).
3. The high-strength steel with good cryogenic temperature toughness of claim 2 , wherein said Mn, Ni, Cr and Cu satisfy the condition of 8≦1.5×(Mn+Cr+Cu)+Ni≦12.
4. The high-strength steel with good cryogenic temperature toughness of claim 1 , wherein the steel has a main phase of martensite and 3-15 vol % of retained austenite.
5. The high-strength steel with good cryogenic temperature toughness of claim 1 , wherein the steel has a main phase of martensite with a lath structure and 3-15 vol % of retained austenite.
6. The high-strength steel with good cryogenic temperature toughness of claim 1 , wherein the steel has a main phase of martensite with a lath structure, 10 vol % or less of bainite and 3-15 vol % of retained austenite.
7. A method of manufacturing high-strength steel with cryogenic temperature toughness, comprising:
heating a steel slab to a temperature within a range of 1,000 to 1,250° C., the steel slab comprising, by weight: 0.01-0.06% of carbon (C), 2.4-8.0% of manganese (Mn), 0.01-6.0% of nickel (Ni), 0.02-0.6% of molybdenum (Mo), 0.03-0.5% of silicon (Si), 0.003-0.05% of aluminum (Al), 0.0015-0.01% of nitrogen (N), 0.02% or less of phosphorous (P), 0.01% or less of sulfur (S), with a remainder of iron (Fe) and other unavoidable impurities, wherein the Mn and Ni satisfy the condition of 8≦1.5×Mn+Ni≦12;
finish-rolling the heated slab at a temperature of 950° C. or less at a rolling reduction rate of 40% or more;
cooling the rolled steel to a temperature of 400° C. or less at a cooling rate of 2° C./s or more; and
tempering the steel for 0.5-4 hours to a temperature within a range of 550 to 650° C. after the cooling.
8. The method of claim 7 , wherein the steel slab further comprises, by weight, at least one selected from the group consisting of 0.003-0.055 of titanium (Ti), 0.1-5.0% of chromium (Cr) and 0.1-3.0% of copper (Cu).
9. The method of claim 8 , wherein said Mn, Ni, Cr and Cu satisfy the condition of 8≦1.5×(Mn+Cr+Cu)+Ni≦12.
10. The method of claim 7 , wherein the steel has a main phase of martensite and 3-15 vol % of retained austenite.
11. The method of claim 7 , wherein the steel has a main phase of martensite with a lath structure and 3-15 vol % of retained austenite.
12. The method of claim 7 , wherein the steel has a main phase of martensite with a lath structure, 10 vol % or less of bainite, and 3-15 vol % of retained austenite.