IP Library Granted Patent US 8,785,107
Granted Patent B2
US 8,785,107 · App. 13/825,136 · Granted Jul 22, 2014

Lithographic printing plate precursor

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Quick Facts
Patent No.
US 8,785,107
App. No.
13/825,136
Granted
Jul 22, 2014
Kind
B2
Abstract

A lithographic printing plate precursor is provided that exhibits less blooming without using a specific polymerization initiator, infrared radiation absorbing agent and the like. The lithographic printing plate precursor comprises a substrate having thereon an image forming layer comprising a radiation-sensitive composition which comprises a radical polymerizable component, an infrared radiation absorbing agent and a radical polymerization initiator, wherein the radiation-sensitive composition comprises a fluorinated copolymer substantially having no hydrophilic moiety.

Claims (22)

1. A lithographic printing plate precursor comprising a substrate having thereon an image forming layer comprising a radiation-sensitive composition which comprises a radical polymerizable component, an infrared radiation absorbing agent and a radical polymerization initiator, wherein

the radiation-sensitive composition comprises a fluorinated copolymer having no hydrophilic moiety selected from cationic, anionic, acidic and polyoxyethylene groups.

2. The lithographic printing plate precursor according to claim 1 , wherein the fluorinated copolymer is represented by the following Formula (A) and comprises at least two monomer units represented by the following formulas (I) and (II):

wherein

R 1 and R 2 are hydrogens or methyl groups,

Rf represents an aliphatic group substituted with a fluorine atom,

Z represents a divalent organic group, and

X represents an optional organic group which does not contain a hydrophilic moiety selected from a cationic group, an anionic group, an acidic group and polyoxyethylene group.

3. The lithographic printing plate precursor according to claim 2 , wherein the fluorinated copolymer comprises 10 to 97 mol % of a monomer unit of the formula (I) and 3 to 90 mol % of a monomer unit of the formula (II).

4. The lithographic printing plate precursor according to claim 2 , wherein Rf of the formula (A) is an aliphatic group having 1 to 20 carbon atoms in which at least two hydrogen atoms of the terminal carbon are substituted with a fluorine atom.

5. The lithographic printing plate precursor according to claim 2 , wherein X of the formula (A) represents a —CO-A-Y group, A represents an oxygen atom or NR 4 —, in which R 4 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms, and Y is selected from the group consisting of an alkyl group which may have a substituent, an aryl group which may have a substituent, and a monovalent organic group having an unsaturated group.

6. The lithographic printing plate precursor according to claim 1 , wherein the fluorinated copolymer having no hydrophilic moiety selected from cationic, anionic, acidic and polyoxyethylene groups further comprises a monomer unit having a maleimide structure represented by the following formula (1):

wherein R represents a hydrogen atom or a hydrocarbon group selected from the group consisting of an alkyl group, an alkenyl group and an aryl group.

7. The lithographic printing plate precursor according to claim 1 , wherein the radical polymerization initiator is selected from the group consisting of a sulfonium salt, an iodonium salt, a diazonium salt, and a triazine compound comprising a halomethyl moiety.

8. The lithographic printing plate precursor according to claim 1 , wherein the radiation-sensitive composition further comprises at least one boron salt compound comprising a boron anion represented by the formula (III):

wherein R 1 , R 2 , R 3 and R 4 each independently represents an alkyl, aryl, alkenyl, alkynyl, cycloalkyl or heterocyclic group, or two or more of R 1 , R 2 , R 3 and R 4 are combined together to form a heterocyclic ring having the boron atom.

9. The lithographic printing plate precursor according to claim 1 , wherein the radiation-sensitive composition further comprises a binder resin.

10. The lithographic printing plate precursor according to claim 1 , wherein the image forming layer can be developed with an aqueous alkali solution.

11. The lithographic printing plate precursor according to claim 1 , wherein the image forming layer can be developed with a fountain solution or a printing ink, or both a fountain solution and a printing ink.

12. A method for providing a lithographic printing plate, comprising:

imagewise exposing the lithographic printing plate precursor of claim 1 to provide an exposed precursor, and

developing the exposed precursor to provide a lithographic printing plate.

Assignments (14)
NOTICE OF SECURITY INTERESTS Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 056984/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0233 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056733/0681 →
RELEASE OF SECURITY INTEREST Recorded Jan 24, 2020
From: BARCLAYS BANK PLC
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST) INC.; KODAK AMERICAS LTD.; KODAK REALTY INC.; LASER PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES LTD.; NPEC INC.
Reel/Frame 052773/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 30, 2019
From: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; PFC, INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX, INC.; KODAK PHILIPPINES, LTD.; NPEC, INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
Reel/Frame 049901/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 22, 2019
From: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: QUALEX, INC.; EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC, INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER PACIFIC MEDIA CORPORATION; PAKON, INC.; KODAK PHILIPPINES, LTD.; NPEC, INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
Reel/Frame 050239/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BANK OF AMERICA N.A., AS AGENT
Reel/Frame 031162/0117 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 031159/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC; KODAK AMERICAS, LTD.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE
Reel/Frame 031158/0001 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Sep 5, 2013
From: CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT; WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT
To: EASTMAN KODAK COMPANY; PAKON, INC.
Reel/Frame 031157/0451 →
PATENT SECURITY AGREEMENT Recorded Apr 1, 2013
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 030122/0235 →
PATENT SECURITY AGREEMENT SUPPLEMENT Recorded Mar 25, 2013
From: EASTMAN KODAK COMPANY
To: CITICORP NORTH AMERICA, INC., AS AGENT
Reel/Frame 030081/0373 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 20, 2013
From: HAYASHI, KOJI
To: EASTMAN KODAK COMPANY
Reel/Frame 030047/0489 →