Cellulose ethers and their use
View Patent ↗Cellulose ethers are described which are useful in compositions for extrusion-molded bodies. In these cellulose ethers the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl, the cellulose ether has an MS (hydroxyalkyl) of 0.11 to 1.00, and hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS (hydroxyalkyl)] is 0.35 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups.
1. A composition for extrusion-molded bodies comprising
a) an inorganic material and
b) a cellulose ether wherein
the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl,
the cellulose ether has a viscosity of more than 150 mPa·s, measured as a 1.5% weight solution in water at 20° C. at a shear rate of 2.55 s −1 , and
the cellulose ether has an MS (hydroxyalkyl) of 0.11 to 1.00 and
hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS (hydroxyalkyl)] is 0.30 or less,
wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with a methyl group and
wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with a methyl group.
2. The composition of claim 1 wherein the cellulose ether is a hydroxyalkyl methyl cellulose.
3. The composition of claim 2 wherein the cellulose ether is a hydroxypropyl methylcellulose and
[s23/s26−0.2*MS (hydroxyalkyl)] is 0.27 or less.
4. The composition of claim 2 wherein the cellulose ether is a hydroxyethyl methylcellulose and
[s23/s26−0.2*MS (hydroxyalkyl)] is 0.27 or less.
5. The composition of claim 1 wherein the cellulose ether has a DS(methyl) of 1.2 to 2.2.
6. The composition of claim 1 wherein the cellulose ether has an MS (hydroxyalkyl) of 0.18-0.60.
7. The composition of claim 1 wherein a 1.5 wt.-% aqueous solution of the cellulose ether does not have a detectable precipitation temperature at atmospheric pressure or has a gelation temperature that is not more than 3 degrees Celsius above the precipitation temperature of the cellulose ether,
wherein the gelation temperature is the temperature at which G′/G″=1,
G′ being the storage modulus and G″ being the loss modulus of the 1.5 wt.-% aqueous solution of the cellulose ether.
8. The composition of claim 1 wherein the cellulose ether has a storage modulus G′ of at least 50 Pa, measured as a 1.5 weight percent aqueous solution at 80° C.
9. The composition of claim 8 , wherein the cellulose ether has a storage modulus G′ of at least 200 Pa, measured as a 1.5 weight percent aqueous solution at 80° C.
10. The composition of claim 9 , wherein the cellulose ether is a hydroxyalkyl methyl cellulose which has a DS(methyl) of 1.2 to 2.2 and an MS (hydroxyalkyl) of 0.18-0.60.
11. The composition of claim 1 wherein the inorganic material is selected from materials that set as a result of baking or sintering.
12. An extrusion-molded body produced from the composition of claim 1 .
13. The extrusion-molded body of claim 12 having a ceramic honeycomb structure.
14. A carrier for a catalyst, a catalyst, a heat exchanger, or a filter produced from the extrusion-molded body of claim 12 .
15. The composition of claim 1 wherein the cellulose ether is a hydroxypropyl methylcellulose having a DS(methyl) of 1.40 to 2.00, a MS(hydroxyalkyl) of 0.11-0.30, a storage modulus G′ of at least 100 Pa, measured as a 1.5 weight percent aqueous solution at 80° C., a [s23/s26−0.2*MS (hydroxyalkyl)] of 0.10 to 0.25, and a viscosity of 1000 to 60,000 mPa·s, determined in a 1.5% by weight aqueous solution at 20° C.
16. An extrusion-molded body produced from the composition of claim 15 and having a ceramic honeycomb structure.