Heterophasic polypropylene copolymer composition
View Patent ↗Heterophasic polypropylene composition comprising (A) 45 to 70 wt % of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of ≧80 g/10 min and (B) 25 to 40 wt % of an elastomeric propylene-ethylene copolymer, having an intrinsic viscosity IV (ISO 1628, with decalin as solvent) of ≧3.3 dl/g and an ethylene content of 20 to 50 wt %, (C) 0-15 wt % of an elastomeric ethylene/alpha-olefin random copolymer (D) 3-25 parts per weight of inorganic filler, the heterophasic polypropylene compositions having a total MFR 2 (230° C./2.16 kg) in accordance with ISO 1133 of ≧5 g/10 min, a Charpy notched impact strength according to ISO 179/1eA at +23° C. of ≧15.0 kJ/m 2 , preferably ≧25.0 kJ/m 2 , a minimum value for the Charpy notched impact strength according to ISO 179/1eA at −20° C. of ≧7.0 kJ/m 2 , preferably ≧10.0 kJ/m 2 and a tensile modulus according to ISO 527-3 of ≧1200 MPa; their preparation and use for producing injection moulded articles being free of flow marks.
1. Heterophasic polypropylene composition consisting of:
(A) 45 to 70 wt % of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of ≧80 g/10 min and
(B) 25 to 40 wt % of an elastomeric propylene-ethylene copolymer, having an intrinsic viscosity IV (ISO 1628, with decalin as solvent) of ≧3.3 dl/g and an ethylene content of 20 to 50 wt %,
(C) 0-15 wt % of an elastomeric ethylene/alpha-olefin random copolymer
(D) 3-25 parts per weight of inorganic filler,
the heterophasic polypropylene compositions having a total MFR 2 (230° C./2.16 kg) in accordance with ISO 1133 of ≧5 g/10 min, a Charpy notched impact strength according to ISO 179/1eA at +23° C. of ≧15.0 kJ/m 2 , a minimum value for the Charpy notched impact strength according to ISO 179/1eA at −20° C. of ≧7.0 kJ/m 2 , and a tensile modulus according to ISO 527-3 of ≧1200 MPa.
2. Heterophasic polypropylene composition according to claim 1 , comprising a propylene homopolymer matrix (A) with an MFR 2 in accordance with ISO 1133 (230° C. 2.16 kg load) of ≧100 g/10 min.
3. Heterophasic polypropylene composition according to claim 1 , comprising 30 to 40 wt % of the elastomeric propylene-ethylene copolymer (B) with an ethylene content of 30 to 40 wt %.
4. Heterophasic polypropylene composition according to claim 1 , comprising as component (C) 1 to 10 wt % of an elastomeric ethylene/alpha-olefin random copolymer selected from the group consisting of ethylene-1-butene copolymers, ethylene-1-hexene copolymers and ethylene-1-octene copolymers.
5. Heterophasic polypropylene composition according to claim 4 , comprising as elastomeric ethylene/alpha-olefin random copolymer an ethylene-1-octene copolymer having an octene content of at least 20 wt %, a melt index MI (ASTM D-1238; 190° C., 2.16 kg) of 0.3-30 g/10 min and a density of <880 kg/m 3 (ASTM D-792).
6. Heterophasic polypropylene composition according to claim 1 , wherein said inorganic filler is selected from the group consisting of talc, chalk, clay, mica, clay fibres, glass fibres and carbon fibres up to a length of 6 mm.
7. Heterophasic polypropylene composition according to claim 6 , comprising as inorganic filler 5 to 15 wt % of talc.
8. Heterophasic polypropylene composition according to claim 1 ,
wherein the heterophasic polypropylene composition forms injection moulded articles.
9. Injection moulded articles produced from heterophasic polypropylene compositions consisting of:
(A) 45 to 70 wt % of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of ≧80 g/10 min and
(B) 25 to 40 wt % of an elastomeric propylene-ethylene copolymer, having an intrinsic viscosity IV (ISO 1628, with decalin as solvent) of ≧3.3 dl/g and an ethylene content of 20 to 50 wt %,
(C) 0-15 wt % of an elastomeric ethylene/alpha-olefin random copolymer
(D) 3-25 parts per weight of inorganic filler,
the heterophasic polypropylene compositions having a total MFR 2 (230° C./2.16 kg) in accordance with ISO 1133 of ≧5 g/10 min, a Charpy notched impact strength according to ISO 179/1eA at +23° C. of ≧15.0 kJ/m 2 , a minimum value for the Charpy notched impact strength according to ISO 179/1eA at −20° C. of ≧7.0 kJ/m 2 , and a tensile modulus according to ISO 527-3 of ≧1200 MPa,
said injection moulded articles being free of flow marks.
10. Heterophasic polypropylene composition according to claim 1 , wherein said Charpy notched impact strength according to ISO 179/1eA at +23° C. is ≧25.0 kJ/m 2 .
11. Heterophasic polypropylene composition according to claim 1 , wherein said minimum value for the Charpy notched impact strength according to ISO 179/1eA at −20° C. is ≧10.0 kJ/m 2 .
12. Heterophasic polypropylene composition according to claim 1 , wherein said Charpy notched impact strength according to ISO 179/1eA at +23° C. is ≧25.0 kJ/m 2 , and wherein said minimum value for the Charpy notched impact strength according to ISO 179/1eA at −20° C. is ≧10.0 kJ/m 2 .
13. Injection moulded articles according to claim 9 , wherein said Charpy notched impact strength according to ISO 179/1eA at +23° C. is ≧25.0 kJ/m 2 .
14. Injection moulded articles according to claim 9 , wherein said minimum value for the Charpy notched impact strength according to ISO 179/1eA at −20° C. is ≧10.0 kJ/m 2 .
15. Injection moulded articles according to claim 9 , wherein said Charpy notched impact strength according to ISO 179/1eA at +23° C. is ≧25.0 kJ/m 2 , and wherein said minimum value for the Charpy notched impact strength according to ISO 179/1eA at −20° C. is ≧10.0 kJ/m 2 .