IP Library Granted Patent US 10,308,567
Granted Patent B2
US 10,308,567 · App. 13/830,189 · Granted Jun 4, 2019

Processes and systems for obtaining aromatics from catalytic cracking hydrocarbons

Inventors: Weihua Jin (Katy, TX); Zhongyi Ding (Katy, TX); Mircea Cretoiu (Sugar Land, TX); Joseph C. Gentry (Houston, TX); Mark Lockhart (Bellaire, TX); Calambur Shyamkumar (Missouri City, TX); Pinti Wang (Katy, TX)
Assignee: GTC Technology US LLC
C07C5/2729C07C2/76C07C5/2732C10G11/18C10G35/04C10G55/06C10G2300/1074C10G2300/1077Y02P20/52
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Quick Facts
Patent No.
US 10,308,567
App. No.
13/830,189
Granted
Jun 4, 2019
Kind
B2
Abstract

Methods and processes for producing paraxylene from catalytic cracking hydrocarbons, particularly C 4 and C 5+ streams, are disclosed. Each of the processing steps may be tailored to the overall objective of high paraxylene yield from a relative inexpensive feedstock.

Claims (37)

1. A process for producing paraxylene from a C4 stream and a C5+ catalytic naphtha stream from catalytic cracking unit, said process comprising:

a) separating, in a first separation section, a C5-C9 non-aromatics stream and a first C6-C10 aromatics stream from the C5+ catalytic naphtha stream;

b) forming, in an aromatization section, a second C6-C10 aromatics stream from the C4 stream, the C5-C9 non-aromatics stream, and an olefin rich feedstock;

c) removing, via an impurity removal section, impurities from the first and second C6-C10 aromatics streams to create a purified C6-C10 aromatics stream;

d) providing a reformate and pygas feedstock to a second separation section;

e) separating, in the second separation section, a C6-C7 stream, a first C8 stream, a C9-C10 stream, a C11+ stream, and non-aromatics from the C6-C7 stream and the first C8 stream from the purified C6-C10 aromatics streams and the reformate and pygas feedstock;

f) feeding the C6-C7 stream and the C9-C10 stream into a xylene formation section to form a second C8 stream; and

g) feeding the first and second C8 streams into a paraxylene production section to produce a high-purity paraxylene product, the paraxylene production section comprising a paraxylene recovery zone and a xylene isomerization zone; and

wherein the second separation section comprises a distillation zone that includes a benzene column and a toluene column, and wherein the xylene formation section of step f) shares the benzene column and the toluene column of the second separation section.

2. The process of claim 1 , wherein step a) includes a distillation step and an extraction step.

3. The process of claim 2 , wherein said extraction step is carried out by using extractive distillation method or liquid-liquid extraction method.

4. The process of claim 1 , wherein step b) is carried out in a single reactor or multiple reactors that are fixed bed reactors or continuous regeneration (CCR) type reactor systems.

5. The process of claim 1 , wherein said C5-C9 non-aromatics in step b) contains 15-85 wt % olefins.

6. The process of claim 1 , wherein the removing of impurities in step c) is carried out using hydrogenation, adsorption, absorption, or solvent extraction, or a combination thereof.

7. The process of claim 1 , wherein step e) includes a distillation step and an extraction step.

8. The process of claim 7 , wherein said extraction step is carried out by using an extractive distillation or liquid-liquid extraction.

9. The process of claim 1 , wherein xylene isomerization uses an EB-isomerization catalyst or an EB-dealkylation catalyst.

10. The process of claim 1 , wherein the paraxylene recovery zone comprises crystallization and adsorption.

11. A process for producing paraxylene from a C4 stream and a C5+ naphtha stream from catalytic cracking unit, said process comprising:

a) separating a feed stream into C4+ and C5-C10+ streams;

b) distilling a C5-C9 non-aromatics stream and a C6-C10 aromatics stream from the C5-C10+ stream;

c) feeding the C4+ stream, the C5-C9 non-aromatics stream, and a feed stream rich in olefins into a reactor to form aromatics from the C4+ stream and the C5-C9 non-aromatics stream;

d) feeding an output stream from the reactor and the C6-C10 aromatics stream to an impurity removal section to remove impurities from the output stream and the C6-C10 aromatics stream;

e) providing a reformate and pygas feedstock to a separation section;

f) feeding an output stream from the impurities removal section into the separation section to separate the output stream and the reformate and pygas feedstock into a C6-C7 stream, a first C8 stream, a C9-C10 stream, a C11+ stream, and non-aromatics from the C6-C7 stream and the first C8 stream; and

g) feeding the C6-C7 and the C9-C10 stream into a xylene formation section to form a second C8 stream; and

h) feeding the first and second C8 streams into a paraxylene production section to produce paraxylene, the paraxylene production section comprising a paraxylene recovery zone and a xylene isomerization zone; and

wherein the separation section comprises a distillation zone that includes a benzene column and a toluene column, and wherein the xylene formation section of step g) shares the benzene column and the toluene column of the separation section.

12. The process of claim 11 , wherein step c) is carried out in a single reactor or multiple reactors that are fixed bed reactors or continuous regeneration (CCR) type reactor systems.

13. The process of claim 11 , wherein said C5-C9 non-aromatics in step b) contains 15-85 wt % olefins.

14. The process of claim 11 , wherein the removing of impurities in step d) is carried out using hydrogenation, adsorption, absorption, or solvent extraction, or a combination thereof.

15. The process of claim 11 , wherein the separation section comprises a distillation step and an extraction step.

16. The process of claim 15 , wherein said extraction step is carried out by using an extractive distillation method or a liquid-liquid extraction.

17. The process of claim 11 , wherein paraxylene recovery is carried out by using crystallization or adsorption or a combination thereof.

18. The process of claim 11 , wherein xylene isomerization uses an EB-isomerization catalyst or an EB-dealkylation catalyst.

19. The process of claim 11 , wherein the production of xylenes uses benzene methylation, toluene methylation, benzene/toluene methylation, benzene/C9-C10 transalkylation, toluene/C9-C10 transalkylation, benzene/toluene/C9-C10 transalkylation, toluene disproportionation (TDP), selective toluene disproportionation (STDP) or a combination thereof.

20. The process of claim 11 , wherein the paraxylene recovery zone comprises crystallization and adsorption.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 26, 2021
From: SULZER GTC TECHNOLOGY US INC.
To: SULZER MANAGEMENT AG
Reel/Frame 056046/0676 →
CHANGE OF NAME Recorded Mar 15, 2021
From: GTC TECHNOLOGY US, LLC
To: SULZER GTC TECHNOLOGY US INC.
Reel/Frame 055934/0098 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 20, 2013
From: WANG, PINTI; JIN, WEIHUA; DING, ZHONGYI; CRETOIU, MIRCEA; GENTRY, JOSEPH C.; LOCKHART, MARK; SHYAMKUMAR, CALAMBUR
To: GTC TECHNOLOGY US LLC
Reel/Frame 030256/0728 →
Continuity (2)
Provisional Application 61711934 · Oct 10, 2012
Related Publication 20140100398A1 · Apr 10, 2014