Solution Processed Neutron Detector
View Patent ↗A low-cost neutron detector is formed on a substrate includes a sensor formed by an active material layer sandwiched between two electrodes, and a neutron capture layer formed in close proximity to (i.e., over and/or under) the sensor. The sensor active material layer includes a bulk heterojunction or bilayer structure that is formed by depositing particulate solutions incorporating at least one type of high atomic number nanoparticle using low-temperature (i.e., below 400° C.) solution processing techniques. The sensor electrode material and neutron capture material are similarly disposed in associated solutions (e.g., conductive inks) that are also deposited using low-temperature solution processing techniques, whereby the fabrication process can be carried out on low-cost flexible substrate material (e.g., PET) using high efficiency roll-to-roll production techniques. The neutron capture material is optionally patterned as an array of pillars, and the active layer materials are backfilled between the pillars.
1. A neutron detector comprising:
a substrate having an upper substrate surface;
a sensor disposed on the upper substrate surface, the sensor including a first electrode and a second electrode disposed parallel to the upper substrate surface, and an active material layer sandwiched between the first and second electrodes; and
a neutron capture layer disposed on the substrate and contacting the sensor, said neutron capture layer including a neutron capture material for capturing thermal neutrons directed onto the neutron detector and for converting each said captured thermal neutron into a charged particle,
wherein the active material layer comprises a donor material and an acceptor material operably formulated and arranged to convert said charged particles into electron-hole pairs, and to separate and transport the electrons-holes to the first and second electrodes,
wherein at least one of the donor material and the acceptor material comprises nanoparticles, and
wherein the first electrode is disposed directly on the upper substrate surface such that the sensor is disposed between at least a portion of the neutron capture layer and the substrate.
2. The neutron detector of claim 1 ,
wherein nanoparticles of the active material layer consist essentially of a metal chalcogenide, and
wherein the active material layer further comprises one of an inorganic particulate material and a soluble organic material.
3. The neutron detector of claim 1 , wherein the active material layer has a thickness in the range of 500 nm to 10 microns.
4. The neutron detector of claim 1 , wherein the substrate comprises a flexible material including at least one of PEN, PET, polyimide and stainless steel foil.
5. The neutron detector of claim 1 , wherein each of the first and second electrodes comprise one of silver, copper, gold, and a conducting polymer.
6. The neutron detector of claim 1 ,
wherein the first electrode comprises a first conductive material,
wherein the second electrode comprises a second conductive material, and
wherein the first conductive material is different from the second conductive material.
7. The neutron detector of claim 1 , wherein the neutron capture layer comprises one of Boron-10 (B 10 ), Lithium-6, Gadolinium-157 and Uranium-235.
8. The neutron detector of claim 1 , wherein the neutron capture layer has a thickness in the range of 0.5 microns and 10 microns.
9. A neutron detector comprising:
a substrate having an upper substrate surface;
a sensor disposed on the upper substrate surface, the sensor including a first electrode and a second electrode disposed parallel to the upper substrate surface, and an active material layer sandwiched between the first and second electrodes; and
a neutron capture layer disposed on the substrate and contacting the sensor, said neutron capture layer including a neutron capture material for capturing thermal neutrons directed onto the neutron detector and for converting each said captured thermal neutron into a charged particle,
wherein the active material layer comprises a donor material and an acceptor material operably formulated and arranged to convert said charged particles into electron-hole pairs, and to separate and transport the electrons-holes to the first and second electrodes,
wherein at least one of the donor material and the acceptor material comprises nanoparticles, and
wherein at least a portion of the neutron capture layer is disposed between the sensor and the substrate such that the first electrode is disposed on said portion of the neutron capture layer.
10. A neutron detector comprising:
a substrate having an upper substrate surface;
a sensor disposed on the upper substrate surface, the sensor including a first electrode and a second electrode disposed parallel to the upper substrate surface, and an active material layer sandwiched between the first and second electrodes; and
a neutron capture layer disposed on the substrate and contacting the sensor, said neutron capture layer including a neutron capture material for capturing thermal neutrons directed onto the neutron detector and for converting each said captured thermal neutron into a charged particle,
wherein the active material layer comprises a donor material and an acceptor material operably formulated and arranged to convert said charged particles into electron-hole pairs, and to separate and transport the electrons-holes to the first and second electrodes,
wherein at least one of the donor material and the acceptor material comprises nanoparticles, and
wherein the neutron capture layer is patterned include a plurality of pillars, and
wherein the active material layer is disposed between said pillars.
11. The neutron detector of claim 9 ,
wherein nanoparticles of the active material layer consist essentially of one of a metal chalcogenide, and
wherein the active material layer further comprises one of an inorganic particulate material and a soluble organic material.
12. The neutron detector of claim 9 , wherein the active material layer has a thickness in the range of 500 nm to 10 microns.
13. The neutron detector of claim 9 , wherein the substrate comprises a flexible material including at least one of PEN, PET, polyimide and stainless steel foil.
14. The neutron detector of claim 9 , wherein each of the first and second electrodes comprise one of silver, copper, gold, and a conducting polymer.
15. The neutron detector of claim 9 ,
wherein the first electrode comprises a first conductive material,
wherein the second electrode comprises a second conductive material, and
wherein the first conductive material is different from the second conductive material.
16. The neutron detector of claim 9 , wherein the neutron capture layer comprises one of Boron-10 (B 10 ), Lithium-6, Gadolinium-157 and Uranium-235.
17. The neutron detector of claim 9 , wherein the neutron capture layer has a thickness in the range of 0.5 microns and 10 microns.
18. The neutron detector of claim 10 ,
wherein nanoparticles of the active material layer consist essentially of one of Cadmium-Selenide, Cadmium-Tellurie, and a metal chalcogenide, and
wherein the active material layer further comprises one of an inorganic particulate material and a soluble organic material.
19. The neutron detector of claim 10 , wherein the substrate comprises a flexible material including at least one of PEN, PET, polyimide and stainless steel foil.
20. The neutron detector of claim 10 , wherein each of the first and second electrodes comprise one of silver, copper, gold, and a conducting polymer.