Polymer compositions, method of manufacture, and articles formed therefrom
View Patent ↗An impact resistant polycarbonate composition having improved resistance to polymer degradation comprises an aromatic polycarbonate in admixture with an elastomer-modified graft copolymer that is the product of an emulsion polymerization process, wherein composition is a product of compounding the aromatic polycarbonate and the elastomer-modified graft copolymer in the presence of a buffer comprising a potassium salt of phosphoric acid.
1. An impact resistant polycarbonate composition having improved resistance to polymer degradation comprising an aromatic polycarbonate in admixture with an elastomer-modified graft copolymer that is the product of an emulsion polymerization process, the composition further comprising metallic salts of phosphoric acid, at least one of which is a potassium salt of phosphoric acid, wherein the metallic salts of phosphoric acid are present in the composition in an amount that provides a phosphorus content of 0.01 to 0.16 mol/10 lbs (0.0022 to 0.035 mol/kg), based on the weight of the composition,
wherein the metallic salts of phosphoric acid comprise a weak acid form and a conjugate base form and wherein the weak acid and conjugate base are pairs selected from the group consisting of monopotassium phosphate/dipotassium phosphate, lithium phosphate monobasic/dipotassium phosphate, aluminum phosphate monobasic/dipotassium phosphate, monozinc phosphate/dipotassium phosphate, and combinations thereof; and
wherein after aging molded ISO T-bars of the composition in an oven for 1000 hours at 90±2° C. and 95±3% RH, the melt flow rate (MFR) of the polycarbonate composition does not change by more than 5.0 g/10 minutes units measured in accordance with ISO 1133 standard at 230° C. using a 3.8 kg load and 300 sec dwell time.
2. The composition of claim 1 , wherein the metallic salts of phosphoric acid comprise a weak acid form and a conjugate base that are present in a relative amount that is capable of forming a buffer in distilled water having a pH of 6.4 to 7.0.
3. The composition of claim 1 , wherein the phosphorus atoms in the metallic salt of phosphoric acid are present in an amount of between 0.020 to 0.12 mol/10 pounds (0.0044 to 0.026 mol/kg] of the composition.
4. The composition of claim 3 , wherein the ratio of the weak acid form to the conjugate base form is capable of providing a pH of 6.5 to 6.8 in distilled water.
5. The composition of claim 1 , comprising in admixture about 48 to about 75 weight percent of the aromatic polycarbonate and about 52 to about 25 weight percent of the elastomer-modified graft copolymer polymer and optional polymeric flow promoter, based on the total weight of polycarbonate, elastomer-modified graft copolymer, and polymeric flow promoter.
6. The composition of claim 1 , wherein the metallic salts comprise a conjugate base form in which potassium is a metal cation and a weak acid form having a different metal cation.
7. The composition of claim 1 , wherein metallic salts comprise a conjugate base form and a weak acid form that are both potassium salts in which potassium is the metal cation.
8. The composition of claim 1 , further comprising residual surfactant used during the emulsion polymerization process of making the elastomer-modified graft copolymer.
9. The composition of claim 8 , wherein the surfactant is selected from the group consisting of alkali metal salts of fatty acids and alkali metal carbonates.
10. The composition of claim 1 , further comprising residual strong acid used to coagulate the elastomer-modified graft copolymer.
11. The composition of claim 10 , comprising residual sulfuric acid used as a coagulant.
12. The composition of claim 1 , wherein the elastomer-modified graft copolymer was prepared without using a phosphate compound for buffering, wherein any phosphate compound used during the preparation of the elastomer-modified copolymer was not capable of effectively providing a pH of 6.4 to 7.0.
13. The composition of claim 1 , wherein after aging in an oven for 1000 hours at 90±2° C. and 95±3% RH, the polycarbonate composition exhibits a change in the melt flow rate (MFR) that is at least 10 g/10 minutes less than the change in the same composition in which the metallic salt of phosphoric acid is not present, wherein melt flow rate is measured in accordance with ISO 1133 standard at 230° C. using a 3.8 kg load and 300 sec dwell time.
14. The composition of claim 1 , wherein after aging the polycarbonate composition in an oven for 1000 hours at 90±2° C. and 95±3% RH, at least 60 percent of the molecular weight of the polycarbonate is retained, measured by Gel Permeation Chromatography (GPC).
15. The composition of claim 1 , wherein after aging the polycarbonate composition in an oven for 1000 hours at 90±2° C. and 95±3% RH, the molecular weight retention of the polycarbonate is at least 10 percent greater than the same composition in which the metallic salt of phosphoric acid is not present.
16. The composition of claim 1 , wherein the polycarbonate has a M w of 20,000 to 200,000.
17. An impact resistant polycarbonate composition having improved resistance to polymer degradation comprising an aromatic polycarbonate in admixture with an elastomer-modified graft copolymer that is the product of an emulsion polymerization process, wherein the composition is a product of compounding the aromatic polycarbonate and the elastomer-modified graft copolymer in the presence of a buffer comprising metallic salts of phosphoric acid, wherein the buffer comprises a weak acid form and a conjugate base form that is capable of providing a pH of 6.4 to 7.0 in distilled water, wherein at least one of the weak acid form and conjugate base form comprises a potassium salt of phosphoric acid.
18. The composition of claim 17 , wherein the metallic salts of phosphoric acid comprises phosphorus in the amount of 0.01 to 0.16 mol/10 lbs (0.0022 to 0.035 mol/kg) of the composition.
19. The composition of claim 17 , wherein the metallic salts of phosphoric acid comprise a weak acid form and a conjugate base form, both of which is a potassium salt of phosphoric acid.
20. A method of preparing a polycarbonate composition having improved resistance to polymer degradation comprising:
carrying out emulsion polymerization of a monomer mixture comprising a diene monomer, thereby forming an elastomer polymer;
grafting monomers onto the elastomer polymer to obtain an elastomer-modified graft copolymer; and
compounding the elastomer-modified graft copolymer with an aromatic polycarbonate in the presence of a buffer comprising metallic salts of phosphoric acid, at least one of which comprises a potassium salt of phosphoric acid.
21. The method of claim 20 , wherein the metallic salts of phosphoric acid comprise a weak acid form and a conjugate base form and is capable of providing a pH of 6.4 to 7.0 in distilled water.
22. The method of claim 20 , wherein the metallic salts of phosphoric acid comprise a weak acid form and a conjugate base form, at least one of which is a potassium salt of phosphoric acid.
23. The method of claim 20 , wherein the elastomer-modified graft copolymer is compounded with the aromatic polycarbonate and the metallic salts of phosphoric acid in an extruder.
24. The method of claim 20 , wherein an aqueous solution of the buffer comprising the metallic salts of phosphoric acid is introduced into a blend of the elastomer-modified graft copolymer and aromatic polycarbonate, which polymers are in the form of particulate solids, and wherein compounding comprises introducing the buffer and polymers into an extruder.
25. The method of claim 20 , wherein the elastomer-modified graft copolymer is prepared by an emulsion polymerization process in the presence of a surfactant and is coagulated with an acidic coagulant.
26. The method of claim 25 , wherein the elastomer-modified graft copolymer is prepared by an emulsion polymerization process in the presence of a surfactant selected from the group consisting of metallic salts of a C 8 -C 48 organic carboxylic acids and mixtures thereof.
27. The method of claim 20 , wherein the method further comprises coagulating a latex of the elastomer-modified graft copolymer and drying the coagulated elastomer-modified graft copolymer prior to compounding with the aromatic polycarbonate.
28. The method of claim 27 , wherein the elastomer-modified graft copolymer is coagulated with an acid having a pK a of less than 5.0.
29. An article made from the composition of claim 1 .
30. The article of claim 29 , wherein the article is a molded automotive part selected from the group consisting of spoilers, instrument panels, instrument panel retainers, interior trim, truck roof fairings, truck hoods, car hoods, bumpers, mirror housings, and electroplated wheel covers, hub caps, emblem logos, exterior trim, and door handles.