Engine coolant additive
View Patent ↗An engine coolant additive for use in combination with a major amount of a coolant liquid is described. The engine coolant additive has an alkaline pH, and includes a salt of a monobasic carboxylic acid compound, a salt of an azole compound, and from about 25 weight percent to about 35 weight percent water. The additive may optionally include a transition metal compound such as molybdenum-containing compounds to assist in corrosion inhibition.
1. An engine coolant additive comprising:
a. a salt of an aliphatic monobasic carboxylic acid compound in the range from about C 6 to about C 12 , wherein the carboxylic acid is present in a range from about 40 weight percent to about 70 weight percent of the engine coolant additive based on the molecular weight of the carboxylic acid;
b. a salt of an azole compound; and
c. water, in an amount from about 25 weight percent to about 35 weight percent;
wherein the engine coolant additive excludes other solvents.
2. The engine coolant additive of claim 1 wherein said carboxylic acid is selected from the acid group consisting of hexanoic, heptanoic, isoheptanoic, octanoic, 2-ethylhexanoic, nonanoic, decanoic, neononanoic, undecanoic, dodecanoic, neodecanoic, and combinations thereof.
3. The engine coolant additive of claim 1 wherein a metal hydroxide or ammonium hydroxide is used to form the monobasic salt from the carboxylic acid selected from the group consisting of hexanoic, heptanoic, isoheptanoic, octanoic, 2-ethylhexanoic, nonanoic, decanoic, neononanoic, undecanoic, dodecanoic, neodecanoic, and combinations thereof.
4. The engine coolant additive of claim 1 wherein the azole compound comprises at least three nitrogen atoms.
5. The engine coolant additive of claim 1 wherein the azole compound is present in a range from about 1 weight percent to about 10 weight percent.
6. The engine coolant additive of claim 1 further comprising a transition metal compound.
7. The engine coolant additive of claim 6 , wherein said transition metal compound is present in an amount of from about 0.01 percent by weight to about 10 percent by weight.
8. The engine coolant additive of claim 6 wherein said transition metal compound is a molybdate compound selected from the group consisting of sodium molybdate, potassium molybdate, lithium molybdate, ammonium molybdate, ammonium dimolybdate, ammonium heptamolybdate, molybdenum trioxide, heteropolymolybdates, silicoheteropolymolybdates, phosphoroheteropolymolybdates, and mixtures thereof.
9. The engine coolant additive of claim 1 including an effective amount of a defoamer.
10. The engine coolant additive of claim 1 including an effective amount of a dye.
11. The engine coolant additive of claim 1 including an effective amount of a buffering agent.
12. The engine coolant additive of claim 1 including an effective amount of a biocide agent.
13. The engine coolant additive of claim 1 wherein said water does not exceed about 31% weight percent.
14. The engine coolant additive of claim 1 wherein said engine coolant additive has a pH in a range of greater than 7.0 to 14.0.
15. A method of making an engine coolant additive, the method comprising:
a) mixing an aqueous solution of at least one of a metal hydroxide or ammonium hydroxide with an aliphatic monobasic carboxylic acid in the range from about C 6 to about C 12 to form a salt of the carboxylic acid; and
b) adding an azole compound to the mixture from step a),
wherein the salt of the carboxylic acid is present in the formulation in a range from about 40 weight percent to about 70 weight percent of the engine coolant additive based on the molecular weight of the carboxylic acid and the formulation includes water in a range from about 25 weight percent to about 35 weight percent;
wherein the engine coolant additive excludes other solvents.
16. The method of claim 15 wherein the carboxylic acid is selected from the group consisting of hexanoic, heptanoic, isoheptanoic, octanoic, 2-ethylhexanoic, nonanoic, decanoic, undecanoic, dodecanoic, neodecanoic, and/or combinations thereof.
17. The method of claim 15 further comprising the addition of a transition metal compound.
18. The method of claim 17 wherein said transition metal compound is a molybdate compound and is selected from the group consisting of sodium molybdate, potassium molybdate, lithium molybdate, ammonium molybdate, ammonium dimolybdate, ammonium heptamolybdate, molybdenum trioxide, heteropolymolybdates, silicoheteropolymolybdates, phosphoroheteropolymolybdates, and mixtures thereof.
19. The method of claim 15 further comprising the addition of an effective amount of a defoaming agent.
20. The method of claim 15 further comprising the addition of an effective amount of a dye.
21. The method of claim 15 further comprising the addition of an effective amount of a buffering agent.
22. The method of claim 15 further comprising the addition of an effective amount of a biocide agent.
23. The method of claim 15 , wherein said water does not exceed about 31% weight percent.
24. The method of claim 15 wherein the azole compound comprises at least three nitrogen atoms.
25. An engine coolant additive composition consisting essentially of:
a. a salt of an aliphatic monobasic carboxylic acid compound in the range from about C 6 to about C 12 , wherein the carboxylic acid is present in a range from about 40 weight percent to about 70 weight percent of the engine coolant additive based on the molecular weight of the carboxylic acid;
b. a salt of an azole compound;
c. water, in an amount from about 25 weight percent to about 35 weight percent; and
d. optionally an effective amount of at least one of a transition metal compound, a defoamer, a dye, a buffering agent, a biocide agent, and a bittering agent; wherein the engine coolant additive excludes other solvents.