IP Library Granted Patent US 8,936,893
Granted Patent B2
US 8,936,893 · App. 13/837,043 · Granted Jan 20, 2015

Fluorescing yellow toner particles and methods of use

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Quick Facts
Patent No.
US 8,936,893
App. No.
13/837,043
Granted
Jan 20, 2015
Kind
B2
Abstract

A fluorescing yellow polymeric toner particle comprises one or more non-fluorescing yellow colorants, and one or more fluorescing yellow colorants having one or more emission peak wavelengths of at least 480 nm and up to and including 600 nm. These fluorescing yellow polymeric toner particles can be used to provide multicolor toner images with increased yellow color gamut.

Claims (16)

1. A fluorescing yellow polymeric toner particle comprising a polymeric binder phase, and having distributed therein:

one or more non-fluorescing yellow colorants having one or more absorbance peak wavelengths of at least 480 nm and up to and including 600 nm, and one or more fluorescing yellow colorants having one or more emission peak wavelengths of at least 480 nm and up to and including 600 nm,

wherein:

the molar ratio of the one or more fluorescing yellow colorants to the one or more non-fluorescing yellow colorants is such that the covering power of the fluorescing yellow polymeric toner particle is greater than the covering power of non-fluorescing yellow polymeric toner particles having the same composition and size except that the one or more fluorescing yellow colorants are absent,

the molar ratio of the one or more fluorescing yellow colorants to the one or more non-fluorescing yellow colorants is such that the L* value of the one or more non-fluorescing yellow colorants, when present in a non-fluorescing yellow polymeric toner particle comprising the same polymeric binder phase, is increased by at least 50% in the presence of the one or more fluorescing yellow colorants in the non-fluorescing yellow polymeric toner particle the molar ratio of the one or more fluorescing yellow colorants to one or more non-fluorescing yellow colorants is at least 2:1 and up to 8:1, and

the one or more non-fluorescing yellow colorants are selected from group consisting of coumarins, naphthalimides, perylenes, and anthrones.

2. The fluorescing yellow polymeric toner particle of claim 1 , wherein the one or more fluorescing yellow colorants are selected from the group consisting of coumarins, naphthalimides, perylenes, and anthrones.

3. The fluorescing yellow polymeric toner particle of claim 1 , wherein the polymeric binder phase comprises one or more polyesters or styrene-acrylate copolymers.

4. The fluorescing yellow polymeric toner particle of claim 1 having a mean volume weighted diameter (D vol ) before fixing of at least 4 μm and up to and including 15 μm.

5. The fluorescing yellow polymeric toner particle of claim 1 , wherein the molar ratio of the one or more fluorescing yellow colorants to the one or more non-fluorescing yellow colorants is such that the covering power of the fluorescing yellow polymeric toner particle to the covering power of the non-fluorescing yellow polymeric toner particles having the same composition and size except that the one or more fluorescing yellow colorants are absent, is at least 1:1 and up to and including 10:1.

6. The fluorescing yellow polymeric toner particle of claim 1 , wherein the total amount of the one or more non-fluorescing yellow colorants is up to and including 40% of the total amount of the one or more fluorescing yellow colorants, by weight.

7. A two-component developer comprising carrier particles and one or more of the fluorescing yellow polymeric toner particles of claim 1 .

8. The fluorescing yellow polymeric toner particle of claim 1 , wherein:

the one or more fluorescing yellow colorants are selected from the group consisting of coumarins, naphthalimides, perylenes, and anthrones,

the one or more non-fluorescing yellow colorants and one or more fluorescing yellow colorants, independently have one or more absorbance peak wavelengths of at least 480 nm and up to and including 580 nm, and

the fluorescing yellow polymeric toner particle has a mean volume weighted diameter (D vol ) before fixing of at least 4 μm and up to and including 15 μm.

Assignments (14)
NOTICE OF SECURITY INTERESTS Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 056984/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0233 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056733/0681 →
RELEASE OF SECURITY INTEREST Recorded Jan 24, 2020
From: BARCLAYS BANK PLC
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST) INC.; KODAK AMERICAS LTD.; KODAK REALTY INC.; LASER PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES LTD.; NPEC INC.
Reel/Frame 052773/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 30, 2019
From: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; PFC, INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX, INC.; KODAK PHILIPPINES, LTD.; NPEC, INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
Reel/Frame 049901/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 22, 2019
From: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: QUALEX, INC.; EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC, INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER PACIFIC MEDIA CORPORATION; PAKON, INC.; KODAK PHILIPPINES, LTD.; NPEC, INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
Reel/Frame 050239/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BANK OF AMERICA N.A., AS AGENT
Reel/Frame 031162/0117 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 031159/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC; KODAK AMERICAS, LTD.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE
Reel/Frame 031158/0001 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Sep 5, 2013
From: CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT; WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT
To: EASTMAN KODAK COMPANY; PAKON, INC.
Reel/Frame 031157/0451 →
PATENT SECURITY AGREEMENT Recorded Apr 1, 2013
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 030122/0235 →
PATENT SECURITY AGREEMENT SUPPLEMENT Recorded Mar 25, 2013
From: EASTMAN KODAK COMPANY
To: CITICORP NORTH AMERICA, INC., AS AGENT
Reel/Frame 030081/0373 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 15, 2013
From: TYAGI, DINESH; KUO, CHUNG-HUI; GRANICA, LOUISE
To: EASTMAN KODAK COMPANY
Reel/Frame 030016/0131 →