IP Library Granted Patent US 11,535,762
Granted Patent B2
US 11,535,762 · App. 13/841,888 · Granted Dec 27, 2022

Fast drying aqueous amine free coating composition(s)

Inventors: George Ganghua Teng (Greensboro, NC); Robert W. Greer (Lexington, NC); Kevin Newell (Greensboro, NC)
Assignee: Ennis Flint
C09D7/45C07C209/68C07C215/08C07C227/02C07C229/16C07D251/30C07D403/14C08F220/14C08G59/1477C08G73/0206C08K5/3492C08K5/34924C08K5/34926C09D5/024C09D5/14C09D7/63C09D133/12C09D153/02E01F9/518C08K5/103C08K5/17C08K5/175C09D5/00
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Quick Facts
Patent No.
US 11,535,762
App. No.
13/841,888
Granted
Dec 27, 2022
Kind
B2
Abstract

Coating compositions and methods providing a high build, fast drying, fast hardening non-amine containing aqueous latex binders are provided, wherein the coating composition is applied to a substrate at a wet film thickness to about 15 mils that ensure drying times of less than 10 minutes. The binder requires the use of at least one specific coalescent solvent with both anionic and non-anionic surfactants.

Claims (30)

1. An amine free aqueous coating composition comprising:

an amine free latex binder; and

only one coalescing solvent,

wherein the amine free latex binder comprises at least one anionic surfactant, a non-ionic surfactant, and a polymer prepared from at least one hard monomer, at least one soft monomer, and at least one acid functional monomer, the amounts of the monomers and the anionic surfactant being:

(i) 35 to 65% by weight of the at least one hard monomer, based on a total weight of said latex binder;

(ii) 25 to 55% by weight of the at least one soft monomer, based on the total weight of said latex binder weight;

(iii) 0.5 to 15% by weight of the at least one acid functional monomer, based on the total weight of said latex binder weight; and

(iv) 0.1% to 4% by weight of the at least one anionic surfactant, based on the total weight of said latex binder weight;

wherein said latex binder has a glass transition temperature less than 45 degrees Centigrade, and wherein said latex binder is amine free, ammonia free, and ammonium hydroxide free, and has an average particle size diameter consisting of between 210 nanometers and 290 nanometers, and

wherein said coating composition exhibits a drying time of less than 10 minutes as measured by ASTM test method D711-2010.

2. The composition of claim 1 , wherein the glass transition temperature of the latex binder is between 23 degrees Centigrade and 36 degrees Centigrade.

3. The composition of claim 1 , wherein said composition is operable to be dried at ambient temperature when the composition is applied to a surface at or above 15 mils film thickness.

4. The composition of claim 1 , wherein the coalescing solvent is selected from the group consisting of: propyl glycol n-propyl ether, propylene glycol methyl ether, dipropyl glycol methyl ether, ethylene glycol monopropyl ether, dipropylene glycol monobutyl ether, propylene glycol, diethylene glycol monobutyl ether, trimethyl pentanediol monoisobutyrate, and methanol.

5. The coating composition of claim 1 , wherein said hard monomer comprises a methacrylic monomer.

6. The coating composition of claim 1 , wherein said soft monomer comprises butyl acrylate.

7. The composition of claim 1 , wherein the at least one acid functional monomer is present in an amount between 2.5 and 3.1 weight percent, based on the total weight of said latex binder weight, and the latex binder has an acid number of 17.

8. The composition of claim 1 , wherein said latex binder has an average particle size diameter consisting of between 250 nanometers and 290 nanometers.

9. An amine free aqueous coating composition comprising: only one coalescing solvent; and

an amine free latex binder comprising a surfactant and a polymer prepared from at least one hard monomer, at least one soft monomer, and at least one acid functional monomer, the amounts of the monomers and the surfactant being:

(i) 35 to 65% by weight of the at least one hard monomer, based on a total weight of said latex binder;

(ii) 25 to 55% by weight of the at least one soft monomer, based on the total weight of said latex binder;

(iii) 0.5 to 15% by weight of the at least one acid functional monomer, based on the total weight of said latex binder;

(iv) 1 to 10% by active weight of the surfactant, based on the total weight of said latex binder, wherein the surfactant comprises at least one non-ionic surfactant and at least one anionic surfactant;

wherein the coating composition is substantially free of amine, ammonia, and ammonium hydroxide, and wherein the coating composition has a drying time of less than 10 minutes as measured by ASTM test method D711-2010.

10. The composition of claim 9 , wherein the latex binder has a glass transition temperature less than 45 degrees Centigrade.

11. The composition of claim 9 , wherein the latex binder has a glass transition temperature of between 23 degrees Centigrade and 36 degrees Centigrade.

12. The composition of claim 9 , wherein the coating composition comprises particles having an average particle size diameter of between 210 nanometers and 290 nanometers.

13. The composition of claim 9 , wherein at least one acid functional monomer is present in an amount between 2.5 and 3.1 weight percent, based on the total weight of latex binder.

14. The composition of claim 9 , wherein said coating composition is operable to be dried at ambient temperature when the composition is applied to a surface at or above 15 mils film thickness.

15. The composition of claim 9 , wherein the latex binder has an acid number of 17.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Dec 30, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: ENNIS PAINT INC.; FLINT TRADING INC.; EBERLE DESIGN INC.; RENO A&E LLC
Reel/Frame 054896/0344 →
RELEASE OF SECURITY INTEREST Recorded Dec 27, 2020
From: ANTARES CAPITAL LP, AS ADMINISTRATIVE AGENT
To: EBERLE DESIGN, INC.; ENNIS PAINT, INC.; FLINT TRADING, INC.; RENO A&E, LLC
Reel/Frame 054864/0024 →
SECURITY INTEREST Recorded Jun 23, 2016
From: ENNIS PAINT, INC.; FLINT TRADING, INC.; EBERLE DESIGN, INC.; RENO A&E, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039128/0732 →
SECURITY INTEREST Recorded Jun 13, 2016
From: ENNIS PAINT, INC.; FLINT TRADING, INC.; EBERLE DESIGN, INC.; RENO A&E, LLC
To: ANTARES CAPITAL LP
Reel/Frame 038978/0976 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 24, 2013
From: TENG, GEORGE GANGHUA; GREER, ROBERT W.; NEWELL, KEVIN
To: ENNIS-FLINT
Reel/Frame 031467/0173 →
Continuity (2)
Provisional Application 61702458 · Sep 18, 2012
Related Publication 20140079888A1 · Mar 20, 2014