Phosphor and production method thereof, phosphor-containing composition, light emitting device, illuminating device, display, and nitrogen-containing compound
View Patent ↗To provide a new phosphor of which fluorescence contains much red light component and has a large full width at half maximum, the crystal phase represented by the formula [I] is included in the phosphor. R 3−x−y−z+w2 M z A 1.5x+y−w2 Si 6−w1−w2 Al W1+w2 O y+w1 N 11−y−w1 [I] (R represents La, Gd, Lu, Y and/or Sc, M represents Ce, Eu, Mn, Yb, Pr and/or Tb, A represents Ba, Sr, Ca, Mg and/or Zn, and x, y, z, w1 and w2 are the numeric values in the following ranges: (1/7)≦(3− x−y−z+w 2)/6<(1/2), 0<(1.5 x+y−w 2)/6<(9/2), 0< x <3, 0≦ y <2, 0< z <1, 0≦ w 1≦5, 0≦ w 2≦5, and 0≦ w 1+ w 2≦5).
1. A phosphor comprising a crystal phase represented by formula [I],
R 3−x−y−z+w2 M z A 1.5x+y−w2 Si 6−w1−w2 Al w1+w2 O y+w1 N 11−y−w1 [I]
wherein,
R represents at least one kind of a rare-earth element selected from the group consisting of La, Gd, Lu, Y and Sc,
M represents at least one kind of a metal element selected from the group consisting of Ce, Eu, Mn, Yb, Pr and Tb,
A represents at least one kind of a bivalent metal element selected from the group consisting of Ba, Sr, Ca, Mg and Zn, and
x, y, z, w1 and w2 are the numeric values wherein:
(1/7)≦(3 −x−y−z+w 2)/6<(1/2),
x= 0
0 ≦y< 2,
0 <z< 1,
w 1=0,
w 2=0,
the wavelength of emission peak of the emission spectrum when excited with light of 460-nm wavelength is 510 nm or longer and 580 nm or shorter, and
in the powder X-ray diffraction pattern measured with CuKα line (1.54184 Å), a peak exists at 2θ from 17° to 20°,
and a peak intensity ratio I, related to a peak present at 2θ from 21° to 24°, is 0.05 or smaller, where
the peak intensity ratio I is defined by, in the powder X-ray diffraction pattern at 2θ ranging from 10° to 60°, the ratio of height I p of the peak, present at 2θ from 21° to 24°, to height I max of the most-intensive peak, present at 2θ from 17° to 20°, and
the values of the peak intensities are used after background correction.
2. The phosphor according to claim 1 , wherein La is used in an amount of at least 70 Mol % relative to the total amount of R, and
color coordinates x and y, in CIE standard colorimetric system, of the luminescent color when excited with light having 460 nm wavelength are in the ranges of 0.420≦x≦0.600 and 0.400≦y≦0.570, respectively.
3. A phosphor-containing composition comprising:
said phosphor according to claim 1 and a liquid medium.
4. A light emitting device comprising: a first luminous body and a second luminous body that emits visible light when irradiated with light from said first luminous body, wherein
said light emitting device comprises, as said second luminous body, a first phosphor comprising at least one kind of said phosphor according to claim 1 .
5. A light emitting device according to claim 4 , wherein
said light emitting device comprises, as said second luminous body, a second phosphor comprising at least one kind of a phosphor of which wavelength of emission peak is different from that of said first phosphor.
6. An illuminating device comprising a light emitting device according to claim 4 .
7. A display comprising a light emitting device according to claim 4 .