Nonaqueous electrolytic solution and nonaqueous electrolyte secondary battery
View Patent ↗Provided are a nonaqueous electrolyte solution having improved durability properties in terms of cycling, storage and the like and improved discharge characteristic at a high current density, and a nonaqueous electrolyte battery that uses that nonaqueous electrolyte solution. The nonaqueous electrolyte solution containing a lithium salt and a nonaqueous solvent that dissolves the lithium salt, wherein the nonaqueous electrolyte solution contains a compound represented by formula (1) and at least one compound selected from the group consisting of a compound having a cyano group, a cyclic ester compound having a sulfur atom and a compound having an isocyanate group.
1. A nonaqueous electrolyte solution, comprising a lithium salt and a nonaqueous solvent that dissolves the lithium salt, wherein the nonaqueous electrolyte solution comprises 0.001 to 30 wt % of a compound represented by formula (1) and 0.001 to 5 wt % of a compound having a cyano group represented by formula (3):
wherein
X and Z, which may be identical or different, represent CR′ 2 , C═O, C═N—R′, C═P—R′, O, S, N—R′ and P—R′;
Y represents CR 1 2 , C═O, S═O, S(═O) P(═O)—R 2 and P(═O)—OR 3 ;
R and R 1 , which may be identical or different, are each hydrogen, a halogen, a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom;
R 2 is a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom;
R 3 is Li, NR 4 4 , a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom;
R 4 are mutually identical or different and are a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom; and
n and m are 0 or 1;
wherein adjacent endocyclic carbons may form further bonds with each other, whereupon respective R of the carbons is decreased by one; and
W is hydrogen, a halogen, a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom,
wherein
U is a C1 to C10 V-valent organic group comprising an atom selected from the group consisting of carbon atom, hydrogen atom, nitrogen atom, oxygen atom, sulfur atom, phosphorus atom and halogen atom; and V is an integer from 1 to 3
A(-NCO) n′ (5).
2. The nonaqueous electrolyte solution according to claim 1 , wherein said compound represented by formula (1) is a compound represented by formula (2):
wherein Y represents C═O, S═O, S(═O) 2 , P(═O)—R 2 and P(═O)—OR 3 ;
R 2 is a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom;
R 3 is Li, NR 4 4 , a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom; and
R 4 , which are mutually identical or different, are a C1 to C20 saturated aliphatic hydrocarbon group optionally having a halogen atom, a C1 to C20 unsaturated aliphatic hydrocarbon group optionally having a halogen atom, or a C1 to C20 aromatic hydrocarbon group optionally having a halogen atom.
3. The nonaqueous electrolyte solution according to claim 1 , wherein said compound having a cyano group is a compound represented by NC—(CH 2 ) n —CN(n=2 to 6).
4. The nonaqueous electrolyte solution according to claim 1 , comprising at least one compound selected from the group consisting of a cyclic carbonate having a double bond and a cyclic carbonate having a fluorine atom.
5. A nonaqueous electrolyte battery, comprising a negative electrode and a positive electrode that are capable of absorbing and releasing lithium ions, and the nonaqueous electrolyte solution according to claim 1 .
6. A nonaqueous electrolyte battery, comprising a negative electrode and a positive electrode that are capable of absorbing and releasing lithium ions, and the nonaqueous electrolyte solution according to claim 2 .
7. A nonaqueous electrolyte battery, comprising a negative electrode and a positive electrode that are capable of absorbing and releasing lithium ions, and the nonaqueous electrolyte solution according to claim 3 .
8. A nonaqueous electrolyte battery, comprising a negative electrode and a positive electrode that are capable of absorbing and releasing lithium ions, and the nonaqueous electrolyte solution according to claim 4 .