Apparatus and method for exfoliation of graphene
View Patent ↗Provided is an apparatus and method for exfoliation of graphene, comprising a chamber which has a through-hole formed at one surface thereof; a cylinder which receives graphite and a volatile material to be vaporized at room temperature and has an opening to be corresponding to the through-hole of the chamber, and which is disposed at an outside of the chamber; a clamp which is disposed in the chamber to pass through the through-hole of the chamber and thus selectively seal the opening of the cylinder; and an operation mechanism which is connected with the clamp and moves the clamp so that the opening of the cylinder is selectively sealed by the clamp. Therefore, it is not necessary to use an acid like sulfuric acid, and it is also not necessary to perform a thermal treatment process for removing sulfuric acid.
1. An apparatus for exfoliation of graphene, comprising:
a chamber which has a through-hole formed at one surface thereof;
a cylinder which receives graphite and a volatile material to be vaporized at room temperature and has an opening corresponding to the through-hole of the chamber, and which is mounted at an outside of the chamber, said cylinder having a flange at the lower end thereof;
a clamp to vertically move inside the chamber so as to pass through the through-hole of the chamber and thus selectively seal the opening of the cylinder;
an operation mechanism which is connected with the clamp and vertically moves the clamp so that the opening of the cylinder is selectively sealed by the clamp; and
a jig outside of the chamber to enclose the through-hole, said jig having a lateral slot therein to slidably receive the flange of said cylinder.
2. The apparatus of claim 1 , wherein the operation mechanism comprises an operation lever which is installed at an outside of the chamber, and a link member which is connected between the operation lever and the clamp in the chamber so as to move the clamp through operation of the operation lever.
3. The apparatus of claim 2 , wherein the cylinder is vertically installed on an upper surface of the chamber, and the clamp is interlocked with the link member through operation of the operation lever and then moved vertically.
4. The apparatus of claim 1 , wherein the cylinder has an installation hole formed at an end thereof opposed to an end having the opening, and a pressure gauge for measuring the internal pressure of the cylinder is installed in the installation hole.
5. The apparatus of claim 1 , wherein a seal packing is provided around the opening of the cylinder.
6. The apparatus of claim 1 , wherein the volatile material is liquid nitrogen, liquid oxygen, solid carbon dioxide (dry ice) or liquid carbon dioxide.
7. An apparatus for exfoliation of graphene, comprising:
a chamber which has a through-hole formed at one surface thereof;
a cylinder which receives graphite and a material having a boiling point of 200° C. or less and has an opening to be corresponding to the through-hole of the chamber, and which is disposed at an outside of the chamber;
a clamp which is vertically movable in the chamber so as to pass through the through-hole of the chamber and thus selectively seal the opening of the cylinder;
an operation mechanism which is connected with the clamp and vertically moves the clamp so that the opening of the cylinder is selectively sealed by the clamp;
a heating unit which heats the cylinder; and
a jig which is provided at an outside of the chamber to enclose the through-hole, and which laterally and slidably receives the cylinder.
8. The apparatus of claim 7 , wherein the material having a boiling point of 200° C. or less is water, methanol, ethanol, isopropyl alcohol, acetone, tetrahydrofuran, dimethylacetamide, dimethylformamide, normal hexane, cyclohexane, heptanes, toluene, benzene, ethyl acetate or a mixture thereof.