Polymer blend compositions
View Patent ↗Thermoplastic compositions having miscible and compatible immiscible polymer blends are disclosed. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.
1. A composition comprising a polymer blend derived from:
(a) a pre-polymer comprising 0.5 to 20 mole % of a component selected from the group consisting of free amine groups, free anhydride groups, and combinations thereof and further comprising structural units derived from a first dianhydride and a first diamine, wherein the pre-polymer is an incompletely imidized oligomer;
(b) a polyetherimide comprising structural units and 0.05 to 0.3 mole % of reactive end groups, wherein the structural units are derived from a second dianhydride and a second diamine,
the reactive end groups are reactive with the free anhydride groups, the free amine groups or combinations thereof, and the reactive end groups are reactive groups on the end units, and
wherein the first dianhydride is the same as the second dianhydride or the first diamine is the same as the second diamine, the polymer blend has a single glass transition temperature and the composition further comprises a second polymer wherein the second polymer is different from the first polymer and the pre-polymer.
2. The composition of claim 1 , wherein the single glass transition temperature is greater than or equal to 100° C.
3. The composition of claim 1 , wherein the first dianhydride or the second anhydride is selected from the group consisting of oxydiphthalic anhydrides, bisphenol-A dianhydrides, and combinations thereof.
4. The composition of claim 1 , wherein the first diamine or the second diamine is selected from the group consisting of diamino diaryl sulfones, metaphenylene diamines, paraphenylene diamines, and combinations thereof.
5. The composition of claim 1 , wherein the pre-polymer is essentially free of benzylic protons.
6. The composition of claim 1 , wherein the polymer blend has a heat deflection temperature greater than or equal to 100° C. according to ASTM D648.
7. The composition of claim 1 , wherein the polymer blend has a tensile strength above 70 MPa according to ASTM D638.
8. The composition of claim 1 , wherein the polymer blend has a coefficient of thermal expansion of less than or equal to 100 ppm/° C. from 30° C.-200° C. as measured by thermal mechanical analysis with a thermal ramp rate of 5° C./minute.
9. The composition of claim 1 , wherein the polymer blend has a continuous use temperature greater than or equal to 150° C.
10. The composition of claim 1 , wherein the pre-polymer comprises carbon atoms, oxygen atoms, nitrogen atoms, sulfur atoms, or a combination thereof and has a ratio of carbon atoms/(nitrogen atoms+oxygen atoms+sulfur atoms) of 2.8 to 4.2.
11. The composition of claim 1 , wherein the pre-polymer has a weight average molecular weight of 2,000 to 20,000 grams per mole as measured by gel permeation chromatography.
12. The composition of claim 1 , wherein the second polymer comprises polyphenylene sulfone, poly(ether imide), polysulfone, polycarbonate, polyphenylene ether, poly methyl methacrylate, acrylonitrile butadiene styrene copolymer, polystyrene, polyvinylchloride, per fluoro alkoxy alkane polymer, co-polymer of tetra fluoro ethylene and perfluorinated vinyl ether, fluorinated ethylene propylene polymers, poly(phenylene sulfide), poly(ether ketone), poly(ether-ether ketone), ethylene chloro trifluoro ethylene polymer, polyvinylidene fluoride, polytetrafluoroethylene, polyethylene terephthalate, polyacetal, polyamide, ultra high molecular weight polyethylene, polypropylene, polyethylene, high density polyethylene, low density polyethylene, polybenzimidizole, poly(amide-imide), poly(ether sulfone), poly(aryl sulfone), polyphenylene, polybenzoxazoles, polybenzthiazoles, blends comprising at least one of the foregoing, or co-polymers of at least one of the foregoing.
13. A composition comprising a polymer blend derived from:
(a) a pre-polymer comprising 0.5 to 20 mole % of a component selected from the group consisting of free amine groups, free anhydride groups, and combinations thereof and further comprising structural units derived from a first dianhydride and a first diamine, wherein the pre-polymer is an incompletely imidized oligomer;
(b) a polyetherimide comprising structural units, and 0.05 to 0.3 mole % of reactive end groups, wherein the structural units are derived from a second dianhydride and a second diamine, the reactive end groups are reactive groups on the end units; and
wherein the first dianhydride is different from the second dianhydride and the first diamine is different from the second diamine, the polymer blend has greater than one glass transition temperature, the composition further comprises a second polymer wherein the second polymer is different from the first polymer and the pre-polymer.
14. The composition of claim 13 , wherein the glass transition temperatures are greater than or equal to 50° C.
15. The composition of claim 13 , wherein the first and the second dianhydride are selected from the group consisting of oxydiphthalic anhydrides and bisphenol-A dianhydrides.
16. The composition of claim 13 , wherein the first and the second diamine are selected from the group consisting of diamino diaryl sulfones, metaphenylene diamines, and paraphenylene diamines.
17. The composition of claim 13 , wherein the pre-polymer is essentially free of benzylic protons.
18. The composition of claim 13 , wherein the polymer blend has a heat deflection temperature greater than or equal to 100° C. according to ASTM D648.
19. The composition of claim 13 , wherein the polymer blend has a tensile strength above 70 MPa according to ASTM D638.
20. The composition of claim 13 , wherein the polymer blend has a coefficient of thermal expansion of less than or equal to 100 ppm/° C. from 30° C.-200° C. as measured by thermal mechanical analysis with a thermal ramp rate of 5° C./minute.
21. The composition of claim 13 , wherein the polymer blend has a continuous use temperature greater than or equal to 150° C.
22. The composition of claim 13 , wherein the pre-polymer has a weight average molecular weight of 2,000 to 20,000 grams per mole as measured by gel permeation chromatography.
23. The composition of claim 13 , wherein the second copolymer comprises polyphenylene sulfone, poly(ether imide), polysulfone, polycarbonate, polyphenylene ether, poly methyl methacrylate, acrylonitrile butadiene styrene copolymer, polystyrene, polyvinylchloride, per fluoro alkoxy alkane polymer, co-polymer of tetra fluoro ethylene and perfluorinated vinyl ether, fluorinated ethylene propylene polymers, poly(phenylene sulfide), poly(ether ketone), poly(ether-ether ketone), ethylene chloro trifluoro ethylene polymer, polyvinylidene fluoride, polytetrafluoroethylene, polyethylene terephthalate, polyacetal, polyamide, ultra high molecular weight polyethylene, polypropylene, polyethylene, high density polyethylene, low density polyethylene, polybenzimidizole, poly(amide-imide), poly(ether sulfone), poly(aryl sulfone), polyphenylene, polybenzoxazoles, polybenzthiazoles, blends comprising at least one of the foregoing, or co-polymers of at least one of the foregoing.