Electrophoretic dispersion
View Patent ↗The present invention is directed to an electrophoretic dispersion, in particular, an electrophoretic dispersion comprising uncharged or lightly charged additive particles for improving bistability of an electrophoretic display. The average diameter of the additive particles is about 1% to about 25% of the average hydrodynamic diameter of the charged pigment particles.
1. An electrophoretic dispersion comprising charged pigment particles and uncharged or lightly charged additive particles dispersed in a solvent or solvent mixture, wherein
a) the average diameter of the additive particles is about 1% to about 25% of the average hydrodynamic diameter of the charged pigment particles, and
b) the additive particles are excluded from depletion zones around the charged pigment particles to induce flocculation of the charged pigment particles.
2. The dispersion of claim 1 , wherein the concentration of the additive particles is from about 5% to about 40% by volume of the dispersion.
3. The dispersion of claim 1 , wherein the concentration of the additive particles is from about 10% to about 40% by volume of the dispersion.
4. The dispersion of claim 1 , which comprises two types of charged pigment particles having opposite charge polarities and of contrasting colors.
5. The dispersion of claim 1 , wherein the additive particles are formed from a polymer, metal or metal oxide.
6. The dispersion of claim 1 , wherein the additive particles are formed from polystyrene, poly(2-vinylnapthalene), polymethylmethacrylate, titanium dioxide, silicon dioxide, or gold.
7. The dispersion of claim 1 , wherein the charged pigment particles have a hydrodynamic diameter in the range of 0.1 μm to 1 μm.
8. The dispersion of claim 1 , further comprising non-charged or lightly charged neutral buoyancy particles.
9. The dispersion of claim 8 , wherein the non-charged or lightly charged neutral buoyancy particles are formed from a polymeric material.
10. The dispersion of claim 8 , wherein the non-charged or lightly charged neutral buoyancy particles are formed from polyacrylate, polymethacrylate, polystyrene, polyaniline, polypyrrole, polyphenol, or polysiloxane.
11. The dispersion of claim 8 , wherein the non-charged or lightly charged neutral buoyancy particles are formed from poly(pentabromophenyl methacrylate), poly(2-vinylnapthalene), poly(naphthyl methacrylate), poly(alpha-methystyrene), poly(N-benzyl methacrylamide), or poly(benzyl methacrylate).
12. The dispersion of claim 8 , wherein the refractive index of the uncharged or lightly charged neutral buoyancy particles is different from that of the solvent or solvent mixture in which the particles are dispersed.
13. The dispersion of claim 8 , wherein the average diameter of the uncharged or lightly charged neutral buoyancy particles is in the range of about 100 nanometers to about 5 microns.
14. The disersion of claim 13 , wherein the average diameter of the additive particles is smaller than the average diameter of the neutral buoyancy particles.
15. The dispersion of claim 8 , wherein the concentration of the uncharged or lightly charged neutral buoyancy particles in the electrophoretic dispersion is more than 2.5% by weight, but not exceeding about 25% by weight.
16. The dispersion of claim 8 , further comprising a charge controlling agent.