IP Library Granted Patent US 9,034,568
Granted Patent B2
US 9,034,568 · App. 13/849,256 · Granted May 19, 2015

Liquid deposition photolithography

Inventors: Robert R. McLeod (Boulder, CO); Adam Urness (Boulder, CO); Michael Cole (Longmont, CO); Eric Moore (Boulder, CO)
Assignee: The Regents of the University of Colorado, a body corporate
G03F7/70G03F7/0035G03F7/2022G03F7/2041
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Quick Facts
Patent No.
US 9,034,568
App. No.
13/849,256
Granted
May 19, 2015
Kind
B2
Abstract

Systems and methods for liquid deposition photolithography are described. In particular, some embodiments relate to systems and methods for using photolithography to control the 2D structure of a thin layer of material (e.g., photopolymer) using various masks, projection optics and materials. In one or more embodiments, this thin layer can be manipulated by micro-fluidic techniques such that it can be formed, patterned and post-processed in a liquid environment, vastly simplifying the creation of multi-layer structures. Multiple layers are rapidly built up to create thick structures of possibly multiple materials that are currently challenging to fabricate by existing methods.

Claims (33)

1. A method of liquid deposition photolithography comprising:

inserting a layer of photo-sensitive liquid between a structure and an optical window, wherein the structure is on a base platform;

projecting an optical pattern through the optical window to modify properties of the layer of the photo-sensitive liquid to pattern the layer;

moving the base platform relative to the optical window by a precise distance to thereby make room for a subsequent next layer;

repeating the above steps a plurality of times to build the structure layer by layer; and

releasing, at least once while repeating the above steps, a chemical inhibitor to create a layer of material precursors that is not photo-sensitive between the optical window and the photo-sensitive liquid.

2. The method of liquid deposition photolithography of claim 1 , wherein the properties of the layer being modified include liquid/solid phase, density, index, or chemical composition.

3. The method of liquid deposition photolithography of claim 1 , further comprising adjusting the optical pattern for each layer.

4. The method of liquid deposition photolithography of claim 1 , further comprising adjusting the layer of material precursors before inserting the next layer of photo-sensitive liquid.

5. The method of liquid deposition photolithography of claim 1 , further comprising transporting, via laminar flow, a non-photosensitive layer directly adjacent to the optical window.

6. The method of liquid deposition photolithography of claim 1 , wherein the optical pattern is generated by a spatial light modulator.

7. The method of liquid deposition photolithography of claim 1 , wherein the structure includes a customized refractive index.

8. A method of liquid deposition photolithography comprising:

selecting a photo-sensitive liquid to build a layer of a structure on a base platform;

inserting a layer of the photo-sensitive liquid within an exposure chamber between an optical window and a mold for creating the structure;

releasing a radical inhibitor to maintain a layer of material precursors adjacent to the optical window, wherein the layer of material precursors is not photo-sensitive;

modifying the properties of the layer of the photo-sensitive liquid to pattern the layer, wherein modifying the properties include projecting an optical pattern through the optical window; and

adjusting a position or orientation of the base platform in accordance with a trajectory profile before repeating the above steps a plurality of times to build the structure layer by layer.

9. The method of liquid deposition photolithography of claim 8 , further comprising coating the mold with a chemical release agent using photo-nanoimprint lithography.

10. The method of liquid deposition photolithography of claim 8 , further comprising maintaining a constant thickness of the layer of material precursors.

11. The method of liquid deposition photolithography of claim 8 , wherein an interior side of the optical window is used to shape the structure.

12. A method of liquid deposition photolithography comprising:

inserting a layer of photo-sensitive liquid between a structure on a base platform and an optical window;

projecting an optical pattern through the optical window to modify properties of the layer of the photo-sensitive liquid to pattern the layer;

moving the base platform relative to the optical window by a precise distance to thereby make room for a subsequent next layer;

repeating the above steps a plurality of times to build the structure layer by layer; and

transporting, via laminar flow, a non-photosensitive layer directly adjacent to the optical window.

13. The method of liquid deposition photolithography of claim 12 , wherein the properties of the layer being modified include liquid/solid phase, density, index, or chemical composition.

14. The method of liquid deposition photolithography of claim 12 , further comprising adjusting the optical pattern for each layer.

15. The method of liquid deposition photolithography of claim 12 , further comprising releasing a chemical inhibitor to create a layer of material precursors that is not photo-sensitive between the optical window and the photo-sensitive liquid.

16. The method of liquid deposition photolithography of claim 15 , further comprising adjusting the layer of material precursors before inserting the next layer of photo-sensitive liquid.

17. The method of liquid deposition photolithography of claim 12 , wherein the optical pattern is generated by a spatial light modulator.

18. The method of liquid deposition photolithography of claim 12 , wherein the structure includes a customized refractive index.

Assignments (2)
CONFIRMATORY LICENSE Recorded May 13, 2015
From: UNIVERSITY OF COLORADO
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 035627/0104 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2013
From: MCLEOD, ROBERT R.; URNESS, ADAM; COLE, MICHAEL; MOORE, ERIC
To: THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODY CORPORATE
Reel/Frame 030701/0860 →
Continuity (2)
Provisional Application 61614356 · Mar 22, 2012
Related Publication 20130252178A1 · Sep 26, 2013