Phosphor and light-emitting device using same
View Patent ↗Provided is a phosphor having enhanced luminance with respect to that of conventional β-type sialon phosphors. A phosphor having enhanced luminance is obtained by causing Al, O (oxygen) and Eu to be present at specific concentrations in a produced β-type sialon phosphor. Specifically, provided is a β-type sialon phosphor containing Si, Al, O, N and Eu, wherein the Al concentration in the phosphor ranges from 0.80 mass % or higher to 2.25 mass % or lower, the O concentration ranges from 0.36 mass % or higher to 1.15 mass % or lower, the Eu concentration ranges from 0.40 mass % or higher to 0.80 mass % or lower and a ratio (Al/O) of the Al concentration with respect to the O concentration ranges from 2.0 or higher to 3.0 or lower.
1. A β-type sialon phosphor, comprising Si, Al, O, N, and Eu, wherein
an Al concentration in the phosphor ranges from 0.90 mass % or higher to 2.25 mass % or lower,
an O concentration ranges from 0.36 mass % or higher to 1.15 mass % or lower,
an Eu concentration ranges from 0.40 mass % or higher to 0.80 mass % or lower, and
a ratio (Al/O) of the Al concentration with respect to the O concentration ranges from 2.0 or higher to 3.0 or lower.
2. The β-type sialon phosphor according to claim 1 , wherein a x value in the CIE color coordinates ranges from 0.335 or grater to 0.365 or smaller, and a y value in the CIE color coordinates ranges from 0.600 or greater to 0.630 or smaller.
3. The β-type sialon phosphor according to claim 1 , wherein
the O concentration is greater than 0.60 mass % and 1.15 mass % or lower.
4. The β-type sialon phosphor according to claim 1 , wherein the phosphor is produced by way of a thermal treatment process.
5. The β-type sialon phosphor according to claim 1 , wherein the phosphor is produced by way of a washing process.
6. The β-type sialon phosphor according to claim 5 , wherein the phosphor is produced by using, in the washing process, an aqueous solution A of a fluoride that is solid at 20° C. and that has a solubility at 20° C. ranging from 0.01 g/100 ml of water or higher to 400 g/100 ml of water or lower, and an aqueous solution B that comprises at least one inorganic acid other than hydrofluoric acid.
7. A method for producing the β-type sialon phosphor according to claim 1 , comprising:
firing a phosphor starting material in the presence of a compound that comprises carbon and one or more elements selected from the group consisting of Si, Al, Eu and N.
8. A method for producing the β-type sialon phosphor according to claim 1 , comprising: firing a phosphor starting material in the presence of SiO 2 .
9. A light-emitting device, comprising:
a first luminous body; and
a second luminous body that can emit light through conversion, to visible light, of light from the first luminous body,
wherein the second luminous body comprises at least the phosphor according to claim 1 .