IP Library Granted Patent US 9,090,731
Granted Patent B2
US 9,090,731 · App. 13/853,938 · Granted Jul 28, 2015

Liquid kraft lignin compositions

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Quick Facts
Patent No.
US 9,090,731
App. No.
13/853,938
Granted
Jul 28, 2015
Kind
B2
Abstract

Liquid kraft lignin compositions, methods of their production, and various methods of their use, including in preparing kraft lignin-containing LPF resins, which may in turn be used in producing OSB or other wood-based composites, and methods of assaying lignin content in such compositions, are disclosed. In an illustrative and non-exclusive embodiment, a liquid kraft lignin composition includes water in the amount of about 60-95% by weight, urea about 5-30% by weight, a group 1 alkaline metal hydroxide about 0.5-3.0% by weight, and kraft about 5-25% by weight on a dry basis.

Claims (29)

1. A liquid kraft lignin-containing composition comprising:

water in the amount of approximately 60-89.5% by weight;

urea in the amount of approximately 5-30% by weight;

a group 1 alkaline metal hydroxide in the amount of approximately 0.5-3.0% by weight; and

kraft lignin in the amount of approximately 5-25% by weight on a dry basis;

wherein the composition is a solution; and

wherein the composition exhibits phase stability for 1-4 weeks.

2. The composition of claim 1 , wherein the pH is in the range of 8 to 12.

3. The composition of claim 1 , wherein the viscosity of the composition is 5-1,000 cps.

4. The composition of claim 3 , wherein the viscosity of the composition is 50-500 cps.

5. The composition of claim 3 , wherein the viscosity of the composition is 50-300 cps.

6. The composition of claim 1 , wherein the kraft lignin is present in the amount of approximately 15-25% by weight on a dry basis.

7. The composition of claim 1 , wherein the kraft lignin has a molecular weight greater than about 1000 Da.

8. The composition of claim 1 , wherein the group 1 alkaline metal hydroxide includes one or more of sodium hydroxide and potassium hydroxide.

9. The composition of claim 1 , wherein the water is present in the amount of about 61.5% by weight, the urea in the amount of about 14.9% by weight, the group 1 alkaline metal hydroxide in the amount of about 1.5% by weight, and the kraft lignin in the amount of about 20.6% by weight.

10. An aqueous kraft lignin-containing LPF resin produced from the composition of claim 1 .

11. A method of producing a kraft lignin-containing composition, the method comprising:

combining urea and kraft lignin in an aqueous, alkaline medium in a reaction vessel to form a mixture, wherein water is present in the mixture in the amount of approximately 60-89.5% by weight, urea in the amount of approximately 5-30% by weight, a group 1 alkaline metal hydroxide in the amount of approximately 0.5-3.0% by weight, and kraft lignin in the amount of approximately 5-25% by weight on a dry basis, and wherein the pH of the mixture is 8-13;

heating the mixture to a temperature sufficient to dissolve the kraft lignin;

maintaining the mixture at the temperature until the lignin is substantially dissolved; and

subsequently cooling the mixture containing the dissolved kraft lignin, to yield a liquid kraft lignin-containing composition, wherein the composition exhibits phase stability for 1-4 weeks.

12. The method of claim 11 , wherein the group 1 alkaline metal hydroxide includes one or more of sodium hydroxide and potassium hydroxide.

13. The method of claim 11 , wherein the temperature is approximately 95° C.

14. The method of claim 11 , wherein the cooling includes cooling to approximately 20° C.

15. The method of claim 11 , wherein the cooling is performed prior to significant urea hydrolysis occurring in the heated mixture.

16. The method of claim 11 , further comprising subsequently assaying the lignin content of the liquid kraft lignin-containing composition via UV spectroscopy.

17. The method of claim 11 , further comprising reacting the liquid kraft lignin-containing composition with phenol and paraformaldehyde in an alkaline solution to produce a kraft lignin-containing LPF resin.

18. The method of claim 11 , wherein water is present in the mixture in an amount of about 61.5% by weight, urea in the amount of about 14.9% by weight, kraft lignin in the amount of about 20.6% by weight, and a group 1 alkaline metal hydroxide in the amount of about 1.5% by weight.

19. The liquid kraft lignin-containing composition produced by the method of claim 11 .

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 14, 2025
From: INTERNATIONAL PAPER COMPANY
To: GCF US HOLDINGS LLC
Reel/Frame 073563/0717 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 13, 2025
From: INTERNATIONAL PAPER CANADA PULP HOLDINGS ULC,
To: INTERNATIONAL PAPER COMPANY
Reel/Frame 069836/0767 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 11, 2017
From: WEYERHAEUSER NR COMPANY
To: INTERNATIONAL PAPER CANADA PULP HOLDINGS ULC
Reel/Frame 043811/0956 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 5, 2014
From: WINTEROWD, JACK G.
To: WEYERHAEUSER NR COMPANY
Reel/Frame 032388/0001 →