Electrophotographic photoreceptor, process cartridge, and image forming apparatus
View Patent ↗An electrophotographic photoreceptor includes a conductive substrate, an organic photosensitive layer that is provided on the conductive substrate, and an inorganic protective layer that is provided on the organic photosensitive layer, wherein the inorganic protective layer includes a first layer, a second layer, and a third layer in this order from the organic photosensitive layer side and satisfies the relationship of the following expression (1): ρ3≦ρ1<ρ2 Expression (1): wherein ρ 1 represents a volume resistivity (Ω·cm) of the first layer, ρ 2 represents a volume resistivity (Ω·cm) of the second layer, and ρ 3 represents a volume resistivity (Ω·cm) of the third layer.
1. An electrophotographic photoreceptor comprising:
a conductive substrate;
an organic photosensitive layer that is provided on the conductive substrate; and
an inorganic protective layer that is provided on the organic photosensitive layer,
wherein the inorganic protective layer includes a first layer, a second layer, and a third layer in this order from the organic photosensitive layer side and satisfies the relationship of the following expression (1):
ρ3≦ρ1<ρ2 Expression (1):
wherein ρ 1 represents a volume resistivity (Ω·cm) of the first layer, ρ 2 represents a volume resistivity (Ω·cm) of the second layer, and ρ 3 represents a volume resistivity (Ω·cm) of the third layer,
wherein the first layer, the second layer, and the third layer of the inorganic protective layer each include gallium and oxygen, and
wherein the first or the third layer of the inorganic protective laver includes gallium, oxygen, and zinc.
2. The electrophotographic photoreceptor according to claim 1 ,
wherein the organic photosensitive layer contains a p-type charge-transporting organic material, and
the inorganic protective layer contains an n-type or i-type charge-transporting inorganic material.
3. The electrophotographic photoreceptor according to claim 2 , wherein the inorganic protective layer has a thickness of from 0.4 μm to 5.0 μm.
4. The electrophotographic photoreceptor according to claim 2 , wherein the first layer has a thickness of from 0.05 μm to 1.0 μm.
5. The electrophotographic photoreceptor according to claim 2 ,
wherein the inorganic protective layer satisfies the relationship of the following expression (2):
C3≦C1<C2 Expression (2):
wherein C 1 represents a ratio (oxygen/gallium) of the number of oxygen atoms to the number of gallium atoms in the first layer, C 2 represents a ratio (oxygen/gallium) of the number of oxygen atoms to the number of gallium atoms in the second layer, and C 3 represents a ratio (oxygen/gallium) of the number of oxygen atoms to the number of gallium atoms in the third layer.
6. The electrophotographic photoreceptor according to claim 1 , wherein the inorganic protective layer has a thickness of from 0.4 μm to 5.0 μm.
7. The electrophotographic photoreceptor according to claim 1 , wherein the first layer has a thickness of from 0.05 μm to 1.0 μm.
8. The electrophotographic photoreceptor according to claim 1 ,
wherein the inorganic protective layer satisfies the relationship of the following expression (2):
C3≦C1<C2 Expression (2):
wherein C 1 represents a ratio (oxygen/gallium) of the number of oxygen atoms to the number of gallium atoms in the first layer, C 2 represents a ratio (oxygen/gallium) of the number of oxygen atoms to the number of gallium atoms in the second layer, and C 3 represents a ratio (oxygen/gallium) of the number of oxygen atoms to the number of gallium atoms in the third layer.
9. A process cartridge comprising an electrophotographic photoreceptor,
wherein the electrophotographic photoreceptor is the electrophotographic photoreceptor according to claim 1 .
10. The process cartridge according to claim 9 ,
wherein the organic photosensitive layer of the electrophotographic photoreceptor contains a p-type charge-transporting organic material, and
the inorganic protective layer of the electrophotographic photoreceptor contains an n-type or i-type charge-transporting inorganic material.
11. An image forming apparatus comprising:
an electrophotographic photoreceptor;
a charging unit that charges a surface of the electrophotographic photoreceptor;
a latent image forming unit that forms an electrostatic latent image on a charged surface of the electrophotographic photoreceptor;
a developing unit that develops the electrostatic latent image, formed on the surface of the electrophotographic photoreceptor, using a toner to form a toner image; and
a transfer unit that transfers the toner image, formed on the surface of the electrophotographic photoreceptor, onto a recording medium,
wherein the electrophotographic photoreceptor is the electrophotographic photoreceptor according to claim 1 .
12. The image forming apparatus according to claim 11 ,
wherein the organic photosensitive layer of the electrophotographic photoreceptor contains a p-type charge-transporting organic material, and
the inorganic protective layer of the electrophotographic photoreceptor contains an n-type or i-type charge-transporting inorganic material.