High durability joints between ceramic articles, and methods of making and using same
Embodiments of the present invention provide high durability joints between ceramic articles, particularly between beta-silicon carbide (β-SiC) articles, and methods of making and using the same. In one embodiment, a joint between first and second articles each comprising a ceramic polymorph comprises a matrix comprising the ceramic polymorph and extending between the first and second articles; a plurality of inclusions comprising the ceramic polymorph and being distributed throughout the matrix; and a sealing layer comprising the ceramic polymorph and being respectively disposed on the first and second articles and the matrix.
1. A method of preparing a joint between first and second articles each comprising a ceramic polymorph, the method comprising:
(a) preparing a slurry comprising a preceramic polymer and a plurality of inclusions, the inclusions comprising the same ceramic polymorph as the first and second articles;
(b) applying the slurry between the first and second articles;
(c) curing the slurry to form a green body;
(d) pyrolyzing the green body to form a solid ceramic containing the plurality of inclusions;
(e) crystallizing the solid ceramic to form a crystalline matrix comprising the same ceramic polymorph as the first and second articles, the plurality of inclusions being disposed within the crystalline matrix; and
(f) reinforcing the joint by applying to the crystalline matrix a substantially gas impermeable sealing layer, the substantially gas impermeable sealing layer comprising the same ceramic polymorph as the first and second articles, the substantially gas impermeable sealing layer being disposed on respective outer surfaces of the first and second articles and penetrating partially or fully into the crystalline matrix.
2. The method of claim 1 , wherein the crystalline matrix, the plurality of inclusions, and the substantially gas impermeable sealing layer each consist essentially of the same ceramic polymorph as the first and second articles.
3. The method of claim 1 , wherein the inclusions comprise spheres, flakes, whiskers, fibers, or irregular shapes comprising the ceramic polymorph.
4. The method of claim 1 , wherein the substantially gas impermeable sealing layer is applied using chemical vapor infiltration.
5. The method of claim 1 , wherein the slurry is cured at a first temperature to form the green body, the green body is pyrolized at a second temperature higher than the first temperature to form the solid ceramic, and the solid ceramic is crystallized at a third temperature higher than the second temperature.
6. The method of claim 1 , wherein the preceramic polymer comprises polycarbosilane.
7. The method of claim 4 , wherein applying the chemical vapor infiltration comprises applying silicon-containing and carbon-containing reactant gases in a carrier gas to the first and second articles and to the crystalline matrix.
8. The method of claim 1 , further comprising repeating steps (b)-(e) one or more additional times.
9. The method of claim 1 , wherein the ceramic polymorph is β-SiC.
10. The method of claim 1 , further including coating the inclusions with an interface coating.
11. The method of claim 5 , wherein the solid ceramic is crystallized at the third temperature for a sufficient amount of time so as to substantially completely crystallize the solid ceramic.
12. The method of claim 5 , wherein the crystalline matrix further comprises cracks, pores, or voids, and wherein the substantially gas impermeable sealing layer penetrates partially or fully into the crystalline matrix via the cracks, pores, or voids.