IP Library Granted Patent US 9,065,009
Granted Patent B2
US 9,065,009 · App. 13/859,137 · Granted Jun 23, 2015

Apparatus and method for forming a transparent conductive oxide layer over a substrate using a laser

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Quick Facts
Patent No.
US 9,065,009
App. No.
13/859,137
Granted
Jun 23, 2015
Kind
B2
Abstract

An apparatus and method for converting an amorphous transparent conductive oxide to a crystalline form with the assistance of irradiation of a laser.

Claims (15)

1. A method of forming a transparent conductive oxide layer, the method comprising:

irradiating at least a portion of an amorphous transparent conductive oxide layer on a substrate with a laser beam to form one or more nucleation sites therein,

wherein the irradiated amorphous transparent conductive oxide layer requires less thermal load to crystallize than the amorphous transparent conductive oxide layer.

2. The method of claim 1 , further comprising:

annealing the irradiated amorphous transparent conductive oxide layer at a temperature of between about 400° C. and about 550° C. for between 10 minutes and 20 minutes.

3. The method of claim 1 , further comprising:

annealing the irradiated amorphous transparent conductive oxide layer at a temperature of between about 550° C. and about 750° C. for less than 10 minutes.

4. The method of claim 1 , wherein the transparent conductive oxide layer comprises crystalline cadmium stannate.

5. The method of claim 1 , wherein the amorphous transparent conductive oxide layer comprises a material containing cadmium and tin.

6. The method of claim 5 , wherein the amorphous transparent conductive oxide layer comprises a cadmium tin oxide.

7. The method of claim 1 , wherein the laser irradiation is continuous and forms a nucleation layer within the amorphous transparent conductive oxide layer.

8. The method of claim 1 , further comprising moving the substrate past a laser beam source, wherein the step of irradiating occurs in a laser irradiation pattern that is substantially perpendicular to a movement direction of the substrate.

9. The method of claim 8 , wherein the laser irradiation pattern is linear.

10. The method of claim 8 , wherein the laser irradiation pattern is an arrangement of spots.

11. The method of claim 8 , wherein the laser irradiation pattern is an arrangement of lines.

Assignments (5)
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Nov 15, 2021
From: JPMORGAN CHASE BANK, N.A.
To: FIRST SOLAR, INC.
Reel/Frame 058132/0261 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Nov 15, 2021
From: JPMORGAN CHASE BANK, N.A.
To: FIRST SOLAR, INC.
Reel/Frame 058132/0566 →
PATENT SECURITY AGREEMENT Recorded Jul 12, 2017
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 043177/0581 →
CORRECTIVE ASSIGNMENT TO CORRECT THE PATENT APPLICATION 13/895113 ERRONEOUSLY ASSIGNED BY FIRST SOLAR, INC. TO JPMORGAN CHASE BANK, N.A. ON JULY 19, 2013 PREVIOUSLY RECORDED ON REEL 030832 FRAME 0088. ASSIGNOR(S) HEREBY CONFIRMS THE CORRECT PATENT APPLICATION TO BE ASSIGNED IS 13/633664. Recorded Sep 19, 2014
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 033779/0081 →
SECURITY AGREEMENT Recorded Jul 19, 2013
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 030832/0088 →