IP Library Granted Patent US 10,543,509
Granted Patent B2
US 10,543,509 · App. 13/859,607 · Granted Jan 28, 2020

Nanotube material having conductive deposits to increase conductivity

Inventors: David S. Lashmore (Lebanon, NH); Paul Jarosz (Merrimack, NH); Joseph E. Johnson (Nashua, NH)
Assignee: Nanocomp Technologies, Inc.
B05D5/12H01B1/02H01B1/04B82Y30/00B82Y40/00
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Quick Facts
Patent No.
US 10,543,509
App. No.
13/859,607
Granted
Jan 28, 2020
Kind
B2
Abstract

An apparatus having a conductive body defined by a plurality of nanotubes forming a planar structure. The apparatus further includes a plurality of junctions, formed by adjacent nanotubes, and a plurality of conductive deposits positioned at the junctions to electrically join the adjacent nanotubes at the junctions and reduce electrical resistance between the nanotubes, thereby increasing overall conductivity of the body.

Claims (22)

1. A nanostructured material comprising:

a conductive body defined by a plurality of non-aligned;

a dispersant comprising (i) a plurality of conductive metal element deposits and (ii) at least one of glassy carbon, carbide, carbon 13 , irradiated carbon nanotube materials, bucky balls, and a crosslinking agent selected from divinyl benzene, 1,5-hexane diene, and/or other organic molecules with a high degree of pi-bonding, wherein such dispersants are dispersed within the conductive body; and

a plurality of conductive connections formed by the dispersants at junctions between non-aligned nanotubes.

2. A nanostructured material as set forth in claim 1 , wherein the connections are selected from physical connections, bridges, chemical bonds, inter-molecular forces, or a combination thereof.

3. A nanostructured material as set forth in claim 1 , wherein the plurality of conductive metal element deposits are selected from nickel, gold, palladium, copper, platinum, cobalt, and molybdenum deposits.

4. A nanostructured material as set forth in claim 1 , wherein the conductive body is a non-woven sheet.

5. A sheet comprising:

a non-woven sheet defined by a plurality of non-aligned adjacent double wall and/or multiwall nanotubes, the non-woven sheet having a plurality of layers;

a dispersant comprising (i) a plurality of conductive metal element deposits and (ii) at least one of glassy carbon, carbide, carbon 13 , irradiated carbon nanotube materials, bucky balls, and a crosslinking agent selected from divinyl benzene, 1,5-hexane diene, and/or other organic molecules with a high degree of pi-bonding, wherein

such dispersants are dispersed within the non-woven sheet; and

a plurality of conductive connections formed by the dispersants at junctions between non-aligned nanotubes,

wherein the sheet has a strength of greater than 400 MPa.

6. A nanostructured material comprising:

a conductive body defined by a plurality of nanotubes, the conductive body having a plurality of layers;

a dispersant comprising (i) a plurality of conductive metal element deposits and (ii) at least one of glassy carbon, carbide, carbon 13 , irradiated carbon nanotube materials, bucky balls, and a crosslinking agent selected from divinyl benzene, 1,5-hexane diene, and/or other organic molecules with a high degree of pi-bonding, wherein

such dispersants are dispersed within the conductive body;

a plurality of conductive connections formed by the dispersant at junctions between non- aligned nanotubes,

wherein the plurality of connections formed by the plurality of conductive metal element deposits are obtained by treating the body with a transition metal salt solution to infiltrate spaces between individual nanotubes and reducing the transition metal salt by exposing the body to heated hydrogen gas to allow the reduced transition metal salt to form the conductive metal element deposits at junctions between the individual nanotubes, so as to reduce electrical resistance between the individual nanotubes at the junctions.

7. A material as set forth in claim 6 , wherein the transition metal salt solution is a nickel chloride solution and wherein the heated hydrogen gas reduces the nickel chloride to metallic nickel deposits.

8. A material as set forth in claim 6 , wherein water is allowed to evaporate from the transition metal salt solution before reducing the transition metal salt.

9. A material as set forth in claim 6 , further comprising exposing the body to a solvent so as to increase the thickness and pore size of the body, before the step of treating the body with the transition metal salt solution.

Assignments (8)
RELEASE OF SECURITY INTEREST Recorded Jul 28, 2026
From: SECTOR CAPITAL GROUP, LLC
To: HUNTSMAN NANOCOMP LLC
Reel/Frame 075425/0284 →
RELEASE OF SECURITY INTEREST Recorded Jul 28, 2026
From: PIVOTAL CAPITAL FUND, LP
To: HUNTSMAN NANOCOMP LLC
Reel/Frame 075425/0272 →
SECURITY INTEREST Recorded May 4, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCOMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK N.A.
Reel/Frame 075498/0663 →
PATENT SECURITY AGREEMENT Recorded Mar 10, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCAMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK, N.A.
Reel/Frame 075106/0238 →
SECURITY INTEREST Recorded Jan 21, 2018
From: NANOCOMP TECHNOLOGIES, INC.
To: SECTOR CAPITAL GROUP, LLC
Reel/Frame 044683/0242 →
RELEASE OF SECURITY INTEREST Recorded May 12, 2017
From: HORIZON TECHNOLOGY FINANCE CORPORATION
To: NANOCOMP TECHNOLOGIES, INC.
Reel/Frame 042364/0414 →
SECURITY INTEREST Recorded May 12, 2017
From: NANOCOMP TECHNOLOGIES, INC.
To: PIVOTAL CAPITAL FUND, LP
Reel/Frame 042364/0279 →
SECURITY INTEREST Recorded Apr 8, 2016
From: NANOCOMP TECHNOLGIES, INC.
To: HORIZON TECHNOLOGY FINANCE CORPORATION
Reel/Frame 038231/0494 →