Flexible pipe body and method of producing same
View Patent ↗A flexible pipe body and methods of producing a flexible pipe body are disclosed. The method may include providing a tubular length of polymeric material for forming a polymeric layer of flexible pipe body; providing a strength layer radially outwards of the polymeric layer; and treating the polymeric layer with a non-ambient temperature and pressure.
1. A method of producing a flexible pipe body for sub-sea transporting of production fluids, the method comprising:
forming a pipe body comprising an inner tubular thermoplastic layer and a strength layer lying radially outwards over a radially outer portion of the thermoplastic layer, the strength layer having gaps between adjacent windings thereof; and
treating a radially inner surface of the thermoplastic layer with an organic solvent so as to increase elasticity of the thermoplastic layer only at the inner surface, said treating conducted by pumping the solvent through the pipe body so as to only contact the inner surface without dissolving polymer of the thermoplastic layer,
wherein said treating reduces microcrazing in the thermoplastic layer that would otherwise result from internal pressurization of the pipe body causing the radially outer portion of the thermoplastic layer to push between said gaps.
2. A method as claimed in claim 1 wherein material of the thermoplastic layer is selected from the group consisting of PVDF, PA-12, PPS, or a combination thereof.
3. A method as claimed in claim 1 wherein the thermoplastic layer comprises a composite mix of polymer and another component.
4. A method as claimed in claim 1 wherein the solvent is selected from the group consisting of acetone, hydrocarbon oil or fluid, polar solvent, non-polar solvent, ionic solvent, and supercritical solvent.
5. A method as claimed in claim 1 wherein the solvent is acetone.
6. A method as claimed in claim 1 wherein said treating is carried out for around 2 minutes to around 24 hours.
7. A method as claimed in claim 1 wherein said treating is carried out for up to 2 hours.
8. A method as claimed in claim 1 wherein said pumping is carried out at a pressure up to 350 MPa.
9. A method as claimed in claim 1 wherein said pumping is carried out at a temperature up to 100° C.
10. A method as claimed in claim 1 wherein said treating changes one or more additional physical properties of the thermoplastic layer selected from the group consisting of shape, stress-strain relationship, threshold strain for crazing, surface hardness, surface tension, friction for movement of polymer fibre chains, microstructure of polymer chain distribution, and density.
11. A method as claimed in claim 1 wherein said treating softens polymer of the thermoplastic layer without dissolving the polymer of the thermoplastic layer.
12. A method as claimed in claim 1 wherein the increase in elasticity is accompanied by an increase in toughness.
13. A method as claimed in claim 1 wherein said treating completely prevents any microcrazing in the thermoplastic layer resulting from said application of internal pressure.
14. A method as claimed in claim 1 wherein the strength layer is an armour layer formed from interlocking wires having the gaps present between adjacent windings thereof.