Silicon-based active materials for lithium ion batteries and synthesis with solution processing
View Patent ↗Silicon based anode active materials are described for use in lithium ion batteries. The silicon based materials are generally composites of nanoscale elemental silicon with stabilizing components that can comprise, for example, silicon oxide-carbon matrix material, inert metal coatings or combinations thereof. High surface area morphology can further contribute to the material stability when cycled in a lithium based battery. In general, the material synthesis involves a significant solution based processing step that can be designed to yield desired material properties as well as providing convenient and scalable processing.
1. A silicon-silicon oxide-carbon composite composition comprising a matrix, nanoscale elemental silicon embedded within the matrix, and particulate carbon, the matrix comprising a silicon oxide-carbon composite and the particulate carbon comprising particulate graphite, particulate nanoscale carbon or mixtures thereof, wherein the composite comprises from about 40 weight percent to about 85 weight percent nanoscale elemental silicon, wherein the nanoscale elemental silicon is crystalline elemental silicon having an average particle diameter of no more than about 250 nm.
2. The silicon-silicon oxide-carbon composite composition of claim 1 wherein the nanoscale elemental silicon comprises crystalline nanoparticles.
3. The silicon-silicon oxide-carbon composite composition of claim 1 having a BET surface area of at least about 30 m 2 /g.
4. The silicon-silicon oxide-carbon composite composition of claim 1 having from about 45 weight percent to about 80 weight percent nanoscale elemental silicon.
5. The silicon-silicon oxide-carbon composite composition of claim 1 wherein the silicon oxide-carbon matrix is formed from the pyrolysis of sol-gel precursor.
6. The silicon-silicon oxide-carbon composite composition of claim 1 wherein the silicon oxide-carbon matrix is formed from the pyrolysis of a precursor material comprising a crosslinked polysiloxane polymer.
7. The silicon-silicon oxide-carbon composite composition of claim 1 wherein the composite composition has a specific capacity of at least about 850 mAh/g at a discharge rate of C/3 when discharged at room temperature from 1.5V to 0.005V against lithium metal.
8. The silicon-silicon oxide-carbon composite composition of claim 1 further comprising an inert metal coating.
9. The silicon-silicon oxide-carbon composite composition of claim 8 having a specific capacity of at least about 750 mAh/g at a discharge rate of C/3 at the 50th cycle when discharged at room temperature from 1.5V to 0.005V against lithium metal.
10. The silicon-silicon oxide-carbon composite composition of claim 1 having a discharge specific capacity of at least about 1700 mAh/g at a rate of C/20 and a 50th cycle discharge specific capacity of at least about 90% of the 5th cycle discharge capacity when discharged at a rate of C/3 from 1.5V to 0.005V against lithium.
11. The silicon-silicon oxide-carbon composite material of claim 10 wherein the composite comprises from about 45 weight percent to about 85 weight percent elemental silicon.
12. The silicon-silicon oxide-carbon composite material of claim 10 wherein the nanoscale silicon comprises porous nanostructured elemental silicon.
13. The silicon-silicon oxide-carbon composite material of claim 10 wherein the nanoscale silicon comprises silicon nanoparticles.
14. The silicon-silicon oxide-carbon composite material of claim 10 wherein the silicon oxide-carbon matrix material is synthesized from the pyrolysis of highly crosslinked polysiloxane polymer.
15. The silicon-silicon oxide-carbon composite material of claim 10 having a BET surface area of at least about 20 m 2 /g.
16. The silicon-silicon oxide-carbon composite composition of claim 1 wherein the carbon comprises particulate graphite.
17. The silicon-silicon oxide-carbon composite composition of claim 1 wherein the carbon comprises particulate nanoscale carbon selected from the group consisting of carbon nanofibers, carbon black, carbon nanotubes, and mixtures thereof.
18. A silicon-silicon oxide-carbon composite composition comprising a matrix, nanoscale elemental silicon embedded within the matrix, and an inert metal coating, the matrix comprising a silicon oxide-carbon composite, wherein the composite comprises from about 40 weight percent to about 85 weight percent nanoscale elemental silicon and from about 0.1 to about 20 weight percent metal coating, and wherein the nanoscale elemental silicon is crystalline elemental silicon having an average particle diameter of no more than about 250 nm, nanostructured elemental silicon having a BET surface area from about 20 m 2 /g to about 150 m 2 /g or a combination thereof.
19. The silicon-silicon oxide-carbon composite composition of claim 18 wherein the inert metal coating comprises copper.
20. The silicon-silicon oxide-carbon composite of claim 18 comprising from about 1 to about 12 weight percent inert metal.