IP Library Granted Patent US 8,883,694
Granted Patent B2
US 8,883,694 · App. 13/864,871 · Granted Nov 11, 2014

Polysaccharide slurries with environmentally friendly activator solvents

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,883,694
App. No.
13/864,871
Granted
Nov 11, 2014
Kind
B2
Abstract

A stable polysaccharide particle suspension composition comprising: a carrier; an activator solvent comprising a) at least one dibasic methyl or ethyl ester; b) at least one compound of the formula R 3 OOC-A-CONR 4 R 5 (IIa), wherein R 3 represents a C 1 -C 36 alkyl group; wherein R 4 and R 5 individually represents a C 1 -C 36 alkyl group, wherein R 4 and R 5 can optionally together form a ring; and wherein A is a linear or branched divalent C 2 -C 6 alkyl group; or c) a combination a) and b); an organo clay compound; and optionally, a surfactant; the composition being stable and capable of suspending polysaccharide particles. Slurries of polysaccharide particles in such suspension composition and methods of making the compositions and the slurries.

Claims (44)

1. A polysaccharide slurry composition comprising polysaccharide particles suspended in a stable polysaccharide particle suspension composition comprising:

a carrier;

an activator solvent comprising:

a) at least one dibasic methyl or ethyl ester;

b) at least one compound of formula (IIa):

R 3 OOC-A-CONR 4 R 5   (IIa),

wherein R 3 represents a C 1 -C 36 alkyl group; wherein R 4 and R 5 individually represents a C 1 -C 36 alkyl group, wherein R 4 and R 5 can optionally together form a ring; and wherein A is a linear or branched divalent C 2 -C 6 alkyl group; or

c) a combination a) and b);

an organo clay compound; and

optionally, a surfactant;

wherein the concentration of polysaccharide is greater than 4 pounds per gallon.

2. The polysaccharide slurry composition of claim 1 wherein the concentration of polysaccharide is at least 5 pounds per gallon.

3. The stable composition of claim 1 wherein the carrier is

a non-aqueous carrier fluid that is not a dibasic ester or ester amide.

4. The stable composition of claim 1 further comprising an acid component.

5. The stable composition of claim 1 further comprising an acid component selected from the group consisting of fumaric acid, adipic acid, maleic acid, malic acid, and mixtures thereof.

6. The stable composition of claim 1 wherein the carrier is present in an amount ranging from about 25 to about 99 wt %, the activator solvent is present in an amount ranging from about 0.1 to about 10 wt %, the organo clay compound is present in an amount ranging from about 1 to about 10 wt %, and the surfactant is present in an amount ranging from about 0.1 to about 5 wt % based on the total weight of the stable polysaccharide particle suspension composition.

7. The stable composition of claim 1 wherein the carrier is present in an amount ranging from about 50 to about 99 wt %, the activator solvent is present in an amount ranging from about 0.1 to about 5 wt %, the organo clay compound is present in an amount ranging from about 1 to about 5 wt %, and the surfactant is present in an amount ranging from about 0.1 to about 3 wt % based on the total weight of the stable polysaccharide particle suspension composition.

8. The stable composition of claim 1 wherein the activator solvent ester diacid or a derivative thereof comprises at least one compound of formula (IIa) wherein R 3 , R 4 , and R 5 individually represents methyl or ethyl.

9. The stable composition of claim 1 wherein the activator solvent ester diacid or a derivative thereof comprises a diester selected from the group consisting of dialkyl methylglutarate, dialkyl ethylsuccinate, dialkyl adipate, dialkyl succinate, dialkyl glutarate, and a combination thereof, wherein each dialkyl is dimethyl or diethyl.

10. The stable composition of claim 1 wherein the activator solvent is a blend of dibasic esters comprising:

(i) a first dibasic ester of formula:

(ii) a second dibasic ester of formula:

and

(iii) optionally, a third dibasic ester of formula:

wherein R 1 and R 2 individually represent a C 1 -C 8 alkyl group.

11. The stable composition of claim 1 wherein the carrier comprises mineral oil.

12. The stable composition of claim 1 wherein the organo clay compound comprises a modified bentonite, a modified attapulgite, a modified kaolinite, a modified halloysite, a modified chlorite, a modified vermiculite, a modified smectite, a modified montmorillonite, a modified hectorite, or a mixture thereof.

13. The stable composition of claim 1 wherein the organo clay compound comprises bentonite, hydrophobically modified bentonite, or a mixture thereof.

14. The stable composition of claim 1 wherein the surfactant is present and comprises at least one-nonionic surfactant.

15. The stable composition of claim 1 wherein the surfactant is present and comprises at least one alcohol ethoxylate, at least one alkyl phenol ethoxylate, at least one terpene alkoxylate, or any mixture thereof.

16. The stable composition of claim 1 wherein the surfactant comprises at least one cationic surfactant, at least one amphoteric surfactant, at least one zwitterionic surfactant, at least one anionic surfactant, at least one nonionic surfactant, or a combination thereof.

17. A method comprising:

mixing a carrier;

an activator solvent comprising

a) at least one dibasic methyl or ethyl ester;

b) at least one compound of formula (IIa):

R 3 OOC-A-CONR 4 R 5   (IIa),

wherein R 3 represents a C 1 -C 36 alkyl group; wherein R 4 and R 5 individually represents a C 1 -C 36 alkyl group, wherein R 4 and R 5 can optionally together form a ring; and wherein A is a linear or branched divalent C 2 -C 6 alkyl group; or

c) a combination a) and b);

an organo clay compound; and

optionally, a surfactant; to form a stable polysaccharide particle suspension composition; and

suspending polysaccharide particles in the stable polysaccharide particle suspension composition to form a stable slurry of polysaccharide particles wherein the concentration of polysaccharide is greater than 4 pounds per gallon.

18. The method of claim 17 wherein the concentration of polysaccharide is greater than 5 pounds per gallon.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2023
From: RHODIA OPERATIONS
To: ENERGY SOLUTIONS (US) LLC
Reel/Frame 063149/0540 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 1, 2013
From: SEHGAL, AMIT; KESAVAN, SUBRAMANIAN; PABALAN, RUELA; AYMES, CHARLES
To: RHODIA OPERATIONS
Reel/Frame 030720/0789 →