Precipitated magnesium carbonate
The present invention relates to a process for preparing hydromagnesite in an aqueous environment. The invention further relates to such hydromagnesite having a specific platy-like morphology in combination with a specific average particle size and to their use as minerals, fillers and pigments in the paper, paint, rubber and plastics industries and to the use as flame-retardant.
1. A hydromagnesite suspension obtained by the process comprising the steps of:
a) providing at least one magnesium oxide source, wherein the magnesium oxide source is a calcined, calcium magnesium carbonate;
b) providing gaseous CO 2 and/or carbonate-comprising anions;
c) slaking the magnesium oxide source of step a) in an aqueous environment to obtain a slaked product comprising magnesium hydroxide, calcium hydroxide and magnesium oxide;
d) contacting the slaked product with the gaseous CO 2 and/or carbonate-comprising anions to obtain a product comprising precipitated nesquehonite and precipitated calcium carbonate; and
e) treating the product comprising precipitated nesquehonite and precipitated calcium carbonate to heat-ageing to form a suspension comprising an admixture of hydromagnesite and precipitated calcium carbonate,
wherein the suspension so obtained has (i) 30 to 60 wt. % of hydromagnesite based on the total weight of the solid contents of the suspension, (ii) 40 to 70 wt. % of precipitated calcium carbonate based on the total weight of the solids content of the suspension, (iii) hydromagnesite and precipitated calcium carbonate particles having an average particle size d 50 of 0.1 to 10 μm, and (iv) hydromagnesite and precipitated calcium carbonate particles having a specific BET surface area of 40 to 100 m 2 /g.
2. The hydromagnesite suspension according to claim 1 , wherein the calcined, calcium magnesium carbonate in step a) is dolomite, huntite or a mixture thereof that was calcined.
3. The hydromagnesite suspension according to claim 1 , wherein the calcined, calcium magnesium carbonate in step a) is dolomite that was calcined.
4. The hydromagnesite suspension according to claim 3 , wherein the dolomite was calcined at a temperature of between 900° C. and 1200° C.
5. The hydromagnesite suspension according to claim 3 , wherein the dolomite was calcined at a temperature of between 600° C. and 900° C.
6. The hydromagnesite suspension according to claim 1 , wherein gaseous CO 2 is provided in step b) from an external CO 2 supply or from the recirculation of CO 2 or both.
7. The hydromagnesite suspension according to claim 1 , wherein carbonate-comprising anions are provided in step b) and are selected from the group consisting of sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate and mixtures thereof.
8. The hydromagnesite suspension according to claim 1 , wherein step c) is performed at a temperature of between 35° C. and 60° C.
9. The hydromagnesite suspension according to claim 1 , wherein step c) is performed for 5 min to 50 min.
10. The hydromagnesite suspension according to claim 1 , wherein the weight ratio of magnesium oxide and magnesium hydroxide to the weight of calcium hydroxide in the slaked product obtained in step c) is 2:1 to 1:2.
11. The hydromagnesite suspension according to claim 1 , wherein step d) is carried out at a temperature of between 10° C. and 30° C.
12. The hydromagnesite suspension according to claim 1 , wherein step d) is carried out at a temperature of between 20° C. and 28° C.
13. The hydromagnesite suspension according to claim 1 , wherein the starting temperature of step d) is between 7° C. and 15° C. and the temperature is permitted to raise during step d) to not more than 50° C.
14. The hydromagnesite suspension according to claim 1 , wherein the product comprising precipitated nesquehonite and the precipitated calcium carbonate obtained in step d) has particles having an average particle size d 50 of 0.5 to 5 μm.
15. The hydromagnesite suspension according to claim 1 , wherein the weight ratio of precipitated nesquehonite to precipitated calcium carbonate in the product obtained in step d) is from 3:1 to 1:3.
16. The hydromagnesite suspension according to claim 1 , wherein the heat-ageing step e) is carried out at a temperature of between 90° C. and 150° C.
17. The hydromagnesite suspension according to claim 1 , wherein the heat-ageing step e) is carried out at a temperature of between 110° C. and 140° C.
18. The hydromagnesite suspension according to claim 1 , wherein the heat-ageing step e) is carried out at a temperature of between 120° C. and 135° C.
19. The hydromagnesite suspension according to claim 1 , wherein the heat-ageing step e) is carried out for 20 min to 60 min.
20. The hydromagnesite suspension according to claim 1 , wherein the heat-ageing step e) is carried out for 20 min to 40 min.
21. The hydromagnesite suspension according to claim 1 , wherein the heat-ageing step e) is carried out for 25 min to 35 min.
22. The hydromagnesite suspension according to claim 1 , wherein the composition obtained in step e) has 35 to 50 wt. % of hydromagnesite based on the total weight of the solids content of the suspension.
23. The hydromagnesite suspension according to claim 1 , wherein the hydromagnesite and precipitated calcium carbonate particles of the suspension obtained in step e) have specific BET surface area of 45 to 80 m 2 /g.
24. The hydromagnesite suspension according to claim 1 , wherein the composition obtained in step e) comprises hydromagnesite and precipitated calcium carbonate particles having an average particle size d50 of 0.5 to 5 μm.
25. The hydromagnesite suspension according to claim 1 , wherein the composition obtained in step e) comprises hydromagnesite and precipitated calcium carbonate particles having an average particle size d50 of 1 to 4 μm.
26. The hydromagnesite suspension according to claim 1 , wherein the particles of the suspension obtained in step e) is treated further with one or more fatty acids.
27. The hydromagnesite suspension according to claim 26 , wherein the one or more fatty acids is selected from the group consisting of stearic acid, palmitic acid, behenic acid, montanic acid, capric acid, lauric acid, myristic acid, isostearic acid and cerotic acid.
28. Paper comprising the hydromagnesite suspension according to claim 1 .
29. A paper coating or mineral filler comprising the hydromagnesite suspension according to claim 1 .
30. A paper wrapper for a smoking article comprising the hydromagnesite suspension according to claim 1 .
31. A flame-retardant comprising the hydromagnesite suspension according to claim 1 .
32. The flame-retardant according to claim 31 , for use in electric and electronic parts, constructional materials, waste pipes, gutter, automobile parts, cabinets for televisions, computers, profiles and fittings, fittings for cables and electric switches, sealants, plasters or paints.