Surface modification method of calcite
Provided is a surface modification method of calcite powder prepared from desulfurized gypsum and heat-treated at a high temperature. According to the surface modification method, hydrophilic calcite powder having polarity may be changed into hydrophobic non-polar calcite powder by safely adsorbing a surface modifier onto a surface of the calcite powder and coating the surface with non-polar fatty acid. Particularly, in the case in which calcite powder heat-treated at a high temperature is hydrophobized, a significantly excellent hydrophobic surface property may be implemented.
1. A surface modification method of calcite powder comprising:
a) mixing fatty acid with an organic solvent to prepare a mixture;
b) heat-treating calcite powder prepared from desulfurized gypsum, wherein the calcite powder is heat-treated at 150 to 300° C.; and
c) adding the heat-treated calcite powder to the mixture in step a) at room temperature without additional thermal energy to react with each other,
wherein the calcite powder is heat-treated at 150 to 400° C.
2. The surface modification method of calcite powder of claim 1 , wherein a content of the fatty acid is 0.1 to 50 parts by weight, and a content of the calcite powder is 1 to 200 parts by weight, based on 100 parts by weight of the organic solvent.
3. The surface modification method of calcite powder of claim 1 , wherein the calcite powder is heat-treated at 200 to 400° C. in step b).
4. The surface modification method of calcite powder of claim 1 , wherein the calcite powder has a particle size of 100 to 350 mesh.
5. The surface modification method of calcite powder of claim 4 , wherein the calcite powder has a specific surface area (BET value) of 1 to 20 m 2 /g.