Interior train components having low smoke and low heat release, and methods of their manufacture
View Patent ↗Seat components and claddings for railway molded or formed from a thermoplastic polymer composition comprising, based on the total weight of the composition, 50 to 93 wt. % of a specific polycarbonate; 4 to 30 wt. % of a poly(carbonate-siloxane) comprising bisphenol A carbonate units, and siloxane units; 3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic polymer composition; wherein an article having a thickness of 0.5 to 10 mm molded from the composition has a Ds-4 smoke density≦300 measured according to ISO 5659-2, and a MAHRE≦90 kW/m 2 measured according to ISO 5660-1, a multiaxial impact energy ≧100 J, and a ductility in multiaxial impact of 80 to 100% at +23° C. according to ISO 6603.
1. A railway component,
wherein the component is a molded or extruded train seat component comprising a thermoplastic composition comprising, based on the total weight of the composition:
50 to 93 wt. % of a poly(bisphenol A carbonate)-co-(bisphenol phthalate ester);
4 to 30 wt. % of a poly(carbonate-siloxane) comprising
bisphenol A carbonate units, and
siloxane units of the formula
or a combination comprising at least one of the foregoing, wherein E has an average value of 2 to 200, wherein the poly(carbonate-siloxane) comprises 0.5 to 55 wt. % of siloxane units based on the total weight of the poly(carbonate-siloxane);
3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic composition; and
and optionally, up to 5 wt. % of an additive selected from a processing aid, a heat stabilizer, an ultra violet light absorber, a colorant, or a combination comprising at least one of the foregoing;
wherein the component has:
a smoke density after 4 minutes (Ds-4) of equal to or less than 300 measured according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m 2 ,
an integral of the smoke density as a function of time up to 4 minutes (VOF4) of equal to or less than 600 measured according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m 2 ,
a maximum average heat release (MAHRE) of equal to or less than 90 kW/m 2 measured according to ISO 5660-1 on a 3 mm thick plaque at 50 kW/m 2 , and
a ductility in multiaxial impact of 80 to 100%, measured at +23° C. at an impact speed of 4.4 m/second measured according to ISO 6603 on 3.2 mm thick discs, and
wherein the component is free of a polyetherimide.
2. The railway component of claim 1 , wherein the component is injection molded, and the thermoplastic composition has a melt volume flow rate of equal to or greater than 4 cc/10 min measured at 300° C. under 1.2 kg force measured according to ISO 1133.
3. The component of claim 1 , wherein the component is extruded, and formed, and the thermoplastic composition having a Vicat B120 of less than 140° C. measured according to ISO 306.
4. The railway component of claim 1 , wherein the thermoplastic composition comprises from 4 to 20 wt. % of the poly(carbonate-siloxane) comprising from 1 to 10 wt. % of siloxane units based on the total weight of the poly(carbonate-siloxane), and wherein a molded or formed sample of the thermoplastic polymer composition has a transmission of greater than 80% or a haze of 5 or less measured according to ASTM D1003 using the color space CIE1931 (Illuminant C and a 2° observer) at a thickness of 3 mm.
5. The railway component of claim 1 , wherein the poly(bisphenol-A carbonate)-co-poly(bisphenol phthalate ester) comprises 75 to 85 wt. % of ester units, wherein the ester units have a molar ratio of isophthalate to terephthalate in the ester units of 98:2 to 88:12.
6. The railway component of claim 1 , wherein the a poly(bisphenol-A carbonate)-co-poly(bisphenol phthalate ester) comprises 35 to 45 wt. % of carbonate units and 55 to 65 wt. % of ester units, wherein the ester units have a molar ratio of isophthalate to terephthalate of 45:55 to 55:45.
7. The railway component of claim 1 , wherein E has an average value of 2 to 60.
8. The railway component of claim 1 , wherein the organophosphorus compound is an aromatic organophosphorus compound having at least one organic aromatic group and at least one phosphorus-containing group, or an organic compound having at least one phosphorus-nitrogen bond.
9. The railway component of claim 8 , wherein the organophosphorus compound of the thermoplastic composition is bisphenol A bis(diphenyl phosphate), triphenyl phosphate, resorcinol bis(diphenyl phosphate), tricresyl phosphate, a phenol/bi-phenol polyphosphate, or a combination comprising at least one of the foregoing.
10. The railway component of claim 8 , wherein organophosphorus compound containing a nitrogen-phosphorus bond is a phosphazene, phosphorus ester amide, phosphoric acid amide, phosphonic acid amide, phosphinic acid amide, tris(aziridinyl) phosphine oxide, a combination comprising at least one of the foregoing.
11. The railway component of claim 1 , wherein the thermoplastic composition further comprises 0.1 to 12 wt. % of TiO 2 .
12. The railway component of claim 1 , wherein the thermoplastic composition further comprises 0.05 to 5.0 wt. % of a light diffuser additive comprising silicone, polymethylsilsesquioxane, crosslinked poly(methyl methacrylate), methyl methacrylate/ethylene glycol dimethacrylate copolymer, TiO 2 , or a combination comprising at least one of the foregoing.
13. The railway component of claim 1 , wherein the thermoplastic composition further comprises 0.00002 to 5.0 wt. % of a colorant based on the total weight of the polymers in the thermoplastic composition.
14. The railway component of claim 1 , wherein the thermoplastic composition further comprises 5 to 20 wt. % of a bisphenol A polycarbonate.
15. A railway component,
wherein the component is an extruded or molded interior train cladding comprising a thermoplastic composition comprising
50 to 93 wt. % of a poly(bisphenol A carbonate)-co-(bisphenol phthalate ester)
4 to 30 wt. % of a poly(carbonate-siloxane) comprising
bisphenol A carbonate units, and
siloxane units of the formula
or a combination comprising at least one of the foregoing, wherein E has an average value of 2 to 200, wherein the poly(carbonate-siloxane) comprises 0.5 to 55 wt. % of siloxane units based on the total weight of the poly(carbonate-siloxane);
3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic composition; and
and optionally, up to 5 wt. % of an additive selected from a processing aid, a heat stabilizer, an ultra violet light absorber, a colorant, or a combination comprising at least one of the foregoing;
wherein the component has:
a smoke density after 4 minutes (Ds-4) of equal to or less than 300 measured according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m 2 ,
an integral of the smoke density as a function of time up to 4 minutes (VOF4) of equal to or less than 600 measured according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m 2 ,
a maximum average heat release (MAHRE) of equal to or less than 90 kW/m 2 measured according to ISO 5660-1 on a 3 mm thick plaque at 50 kW/m 2 ,
a critical heat flux at extinguishment (CFE) of equal to or greater than 20 kW/m 2 measured according to ISO 5658-2 on a 3 mm thick plaque, and
a ductility in multiaxial impact of 80 to 100%, measured at +23° C. at an impact speed of 4.4m/second according to ISO 6603 on 3.2 mm thick discs, and
wherein the component is free of a polyetherimide.
16. The railway component of claim 15 , wherein the component is injected molded, and the thermoplastic composition has a melt volume flow rate of 4 cc/10 min or higher measured at 300° C. under 1.2 kg force measured according to ISO 1133.
17. The railway component of claim 15 , wherein the component is extruded, and the thermoplastic composition has a Vicat B120 of less than 140° C. measured according to ISO 306.
18. The railway component of claim 15 , wherein the thermoplastic composition comprises from 4 to 20 wt. % of the poly(carbonate-siloxane) comprising from 1to 10 wt. % of siloxane units based on the total weight of the poly(carbonate-siloxane), and wherein a molded or formed sample of the thermoplastic polymer composition has a transmission of greater than 80% or a haze of 5 or less measured according to ASTM D1003using the color space CIE1931 (Illuminant C and a 2° observer) at a thickness of 3 mm.
19. The railway component of claim 15 , wherein the poly(bisphenol-A carbonate)-co-poly(bisphenol phthalate ester) comprises 75 to 85 wt. % of ester units, wherein the ester units have a molar ratio of isophthalate to terephthalate in the ester units of 98:2 to 88:12.
20. The railway component of claim 15 , wherein the poly(bisphenol-A carbonate)-co-poly(bisphenol phthalate ester) comprises 35 to 45 wt. % of carbonate units and 55 to 65 wt. % of ester units, wherein the ester units have a molar ratio of isophthalate to terephthalate of 45:55 to 55:45.
21. The railway component of claim 15 , wherein E has an average value of 2to 60.
22. The railway component of claim 15 , wherein the organophosphorus compound is an aromatic organophosphorus compound having at least one organic aromatic group and at least one phosphorus-containing group, or an organic compound having at least one phosphorus-nitrogen bond.
23. The railway component of claim 22 , wherein the organophosphorus compound of the thermoplastic composition is bisphenol A bis(diphenyl phosphate), triphenyl phosphate, resorcinol bis(diphenyl phosphate), tricresyl phosphate, a phenol/bi-phenol polyphosphate, or a combination comprising at least one of the foregoing.
24. The railway component of claim 22 , wherein organophosphorus compound containing a nitrogen-phosphorus bond is a phosphazene, phosphorus ester amide, phosphoric acid amide, phosphonic acid amide, phosphinic acid amide, tris(aziridinyl) phosphine oxide, a combination comprising at least one of the foregoing.
25. The railway component of claim 15 , wherein the thermoplastic composition further comprises 0.05 to 5.0 wt. % of a light diffuser additive comprising silicone, polymethylsilsesquioxane, crosslinked poly(methyl methacrylate), methyl methacrylate/ethylene glycol dimethacrylate copolymer, TiO 2 , or a combination comprising at least one of the foregoing.
26. The railway component of claim 15 , wherein the thermoplastic composition further comprises 0.00002 to 5.0 wt. % of a colorant based on the total weight of the polymers in the thermoplastic composition.
27. The railway component of claim 15 , wherein the thermoplastic composition further comprises 0.1 to 12 wt. % of TiO 2 .
28. The railway component of claim 15 , wherein the thermoplastic composition further comprises 5 to 20 wt. % of a bisphenol polycarbonate.
29. The railway component of claim 15 , wherein the cladding is an interior vertical surface selected from room dividers, flaps, boxes, hoods and louvres; an interior door or lining for internal and external doors; a window insulation; a kitchen interior surface; an interior horizontal surface selected from ceiling paneling, flaps, boxes, hoods and louvres; a luggage storage area selected from overhead and vertical luggage racks, luggage containers and compartments; a driver's desk application selected from paneling and surfaces of driver's desk; an interior surface of gangways selected from interior sides of gangway membranes (bellows) and interior linings; a window frame ; an optionally folding table with downward facing surface; an interior or exterior surface of air ducts, or a device for passenger information.
30. The railway component of claim 29 , wherein the cladding is a side wall, a front wall, an end-wall, a partition, a room divider, an interior door, a window insulation, a lining, a kitchen interior surface, a ceiling panel, an overhead or vertical luggage rack, a luggage container, a luggage compartment, a window frame, an optionally folding table with downward facing surface, or an information display screen.
31. The railway component of claim 15 , wherein the component is a partition, a room divider, an interior door or lining for internal and external doors, a window insulation, an overhead and vertical luggage rack, a luggage container and compartment, a window frame; an optionally folding table with downward facing surface; or a device for passenger information; and wherein the component has a transmission of greater than 80% or a haze of 5 or less measured according to ASTM D1003 using the color space CIE1931(Illuminant C and a 2° observer) at a thickness of 3 mm.
32. The railway component of any one of claims 15 , wherein the component is a partition, a room divider, an interior door or lining for internal and external doors, a window insulation, an overhead and vertical luggage rack, a luggage container and compartment, a window frame, an optionally folding table with downward facing surface, or a device for passenger information; and wherein the thermoplastic composition further comprises a light diffuser additive.
33. The railway component of claim 1 , wherein the poly(carbonate-siloxane ) is present in an amount effective to provide 0.1 to 1.00 wt. % of silicon based on the total weight of the composition.
34. The railway component of claim 33 , wherein the poly(bisphenol-A carbonate)-co-poly(bisphenol phthalate ester) comprises 75 to 85 wt. % of ester units, wherein the ester units have a molar ratio of isophthalate to terephthalate in the ester units of 98:2 to 88:12 or the a poly(bisphenol-A carbonate)-co-poly(bisphenol phthalate ester) comprises 35 to 45 wt. % of carbonate units and 55 to 65 wt. % of ester units, wherein the ester units have a molar ratio of isophthalate to terephthalate of 45:55 to 55:45.