Production of dispersions containing carbon nanotubes
View Patent ↗Process for the preparation of stable suspensions and dispersions of carbon nanotubes, and dispersions prepared by the process.
1. Process for the preparation of a dispersion containing carbon nanotubes, which comprises the following steps:
1. preparation of a mixture of dispersing agent, dispersing aid and, optionally, carbon nanotubes,
2. if carbon nanotubes have been added in step 1, optional pre-dispersion of the mixture from step 1,
3. dispersion of the mixture from step 1 or of the pre-dispersed mixture from step 2, wherein the dispersion is carried out using a high-pressure homogenizer, during which the viscosity of the dispersion increases to a maximum and then decreases and wherein all or part of the mixture is guided in a loop during the dispersion, wherein further CNT agglomerates are added continuously or discontinuously to the mixture during the dispersion, an initial dispersion being obtained,
4. further dispersion of the initial dispersion obtained in step 3 in the high-pressure homogeniser, optionally in loop mode, a final dispersion being obtained.
2. Process according to claim 1 , wherein the addition of the further CNT agglomerates in step 3) is carried out at a time at which the viscosity of the dispersion has passed the maximum.
3. Process according to claim 1 , wherein a final dispersion having a concentration up to 20 wt. % CNTs, based on the total mass of the dispersion, is obtained and the effective throughput is greater than 2 liters per hour.