Polypropylene with living hinge properties
View Patent ↗The present invention relates to a polypropylene which has—a melt flow rate MFR(230° C., 2.16 kg) of at least 13 g/10 min,—an amount of xylene solubles XS of 6.0 wt % or less, and—a crystalline fraction, wherein at least 10% of the crystalline fraction melts the temperature range of from 160 to 170° C., as determined by the stepwise isothermal segregation technique (SIST).
1. A polypropylene comprising:
a melt flow rate MFR(230° C., 2.16 kg) of at least 13 g/10 min,
an amount of xylene solubles XS of 6.0 wt % or less,
a crystalline fraction, wherein 10% to 40% of the crystalline fraction melts in the temperature range of from 160 to 170° C., as determined by the stepwise isothermal segregation technique (SIST), and
comonomer units derived from ethylene and/or a C 4-12 alpha-olefin in an amount of 1.5 wt % to 4.0 wt % of the polypropylene.
2. The polypropylene according to claim 1 , wherein the polypropylene has a melting temperature of from 146° C. to 164° C.
3. The polypropylene according to claim 1 , comprising a first propylene polymer fraction F 1 and one or more further propylene polymer fractions, wherein:
the first fraction F 1 contains comonomer units derived from ethylene and/or a C 4 -C 12 alpha-olefin,
the ratio of the amount of comonomer units of the first fraction F 1 to the amount of comonomer units of the polypropylene is less than 1.0, and
the ratio of the melt flow rate MFR(230° C., 2.16 kg) of the first fraction to the melt flow rate MFR(230° C., 2.16 kg) of the polypropylene is 3.0 or less.
4. The polypropylene according to claim 3 , wherein the first fraction has an amount of comonomer units within the range of 0.8 wt % to 3.0 wt %, and/or the first fraction has a melt flow rate MFR(230° C., 2.16 kg) within the range of 13 g/10 min to 35 g/10 min.
5. The polypropylene according to claim 3 , wherein the weight ratio of the first fraction F 1 to the one or more further propylene polymer fractions is within the range of from 30/70 to 70/30.
6. The polypropylene according to claim 1 , comprising a polymeric alpha-nucleating agent comprising monomer units derived from a vinyl compound of the following chemical formula:
wherein R1 and R2 independently from each other represent a substituted or unsubstituted alkyl, cycloalkyl or aryl, or R1 and R2 together form a saturated, unsaturated or aromatic ring system.
7. An article comprising a plastic hinge which comprises the polypropylene according to claim 1 .