Porous polyolefin resin film
View Patent ↗The purpose is to provide a porous polyolefin resin film which has high gas permeability and a high porosity, and which can exhibit excellent properties including break down properties when used as a separator for a non-aqueous electrolyte secondary battery. The present invention relates to a porous polyolefin resin film which is produced from a resin composition (a) containing a polyolefin resin as the main component and additionally containing organic-inorganic hybrid particles (f).
1. A porous polyolefin resin film, comprising:
a first resin composition comprising a polyolefin resin as a main component; and
organic-inorganic hybrid particles,
wherein the organic-inorganic hybrid particles are organic silicon fine particles consisting of a polysiloxane crosslinked structure, and
the organic silicon fine particles are ring-shaped.
2. The porous polyolefin resin film according to claim 1 , wherein an amount of the organic-inorganic hybrid particles is not less than 1 part by mass and not more than 10 parts by mass, relative to 100 parts by mass of the polyolefin resin.
3. The porous polyolefin resin film according to claim 1 , wherein
the organic silicon fine particles have an average particle diameter of 0.01 to 10μm.
4. The porous polyolefin resin film according to claim 1 , wherein an air permeability of the resin film is not less than 10 seconds/100 ml and not more than 200 seconds/100 ml.
5. The porous polyolefin resin film according to claim 1 , wherein a porosity of the resin film is 55 to 90%.
6. The porous polyolefin resin film according to claim 1 , which is formed by laminating a layer consisting essentially of the first resin composition on a layer consisting of a second resin composition having a crystalline melting peak temperature lower than that of the first resin composition.
7. The porous polyolefin resin film according to claim 1 , wherein the polyolefin resin is a polypropylene resin having a β crystal activity.
8. A separator for a nonaqueous electrolytic solution secondary battery, comprising the porous polyolefin resin film according to claim 1 .
9. A nonaqueous electrolytic solution secondary battery, comprising the separator according to claim 8 .
10. The porous polyolefin resin film according to claim 2 , wherein
the organic silicon fine particles have an average particle diameter of 0.01 to 10μm.
11. The porous polyolefin resin film according to claim 2 , wherein an air permeability of the resin film is not less than 10 seconds/100 ml and not more than 200 seconds/100 ml.
12. The porous polyolefin resin film according to claim 2 , wherein a porosity of the resin film is 55 to 90%.
13. The porous polyolefin resin film according to claim 2 , which is formed by laminating a layer consisting essentially of the first resin composition on a layer consisting of a second resin composition having a crystalline melting peak temperature lower than that of the first resin composition.
14. The porous polyolefin resin film according to claim 2 , wherein the polyolefin resin is a polypropylene resin having a β crystal activity.
15. The porous polyolefin resin film according to claim 1 , wherein the polysiloxane crosslinked structure comprises a siloxane unit of formula 1, a siloxane unit of formula 2, a siloxane unit of formula 3, a siloxane unit of formula 4, a siloxane unit of formula 5, and a siloxane unit of formula 6,
SiO 4/2 (formula 1)
Si(OH)O 3/2 (formula 2)
R 1 (OH)O 3/2 (formula 3)
R 2 (OH)O 3/2 (formula 4)
R 3 Si(OH)O 2/2 (formula 5)
R 4 Si(OH)O 2/2 (formula 6),
wherein
each of R 1 and R 3 is an unreactive hydrocarbon group, and
each of R 2 and R 4 is an organic group having a reactive group selected form the group consisting of an acryloxy group, a methacryloxy group, a vinyl group, and a mercapto group.
16. The porous polyolefin resin film according to claim 15 ,
wherein
a molar ratio of an amount of the siloxane unit of formula 1 to a total amount of the siloxane unit of formula 2, the siloxane unit of formula 3, the siloxane unit of formula 4, the siloxane unit of formula 5, and the siloxane unit of formula 6 is from 20/80 to 50/50,
a molar ratio of a total amount of the siloxane unit of formula 2, the siloxane unit of formula 3, and the siloxane unit of formula 4 to a total amount of the siloxane unit of formula 5 and the siloxane unit of formula 6 is from 50/50 to 75/25, and
a molar ratio of a total amount of the siloxane unit of formula 3 and the siloxane unit of formula 5 to a total amount of the siloxane unit of formula 4 and the siloxane unit of formula 6 is from 20/80 to 60/40.
17. The porous polyolefin resin film according to claim 1 , further comprising the second resin composition.