Heat-shrinkable polyester film
Disclosed is a heat-shrinkable polyester film having a heat shrinkage initiation temperature of 60° C. or lower, a glass transition temperature (Tg) of 77° C. or lower and a heat shrinkage rate of 2% or more at 60° C. which has relatively low glass transition temperature and heat shrinkage initiation temperature, and thus can be useful as a label for a high-density polyethylene (HDPE) container and the like.
1. A heat-shrinkable polyester film having a heat shrinkage initiation temperature of 60° C. or lower, a glass transition temperature (Tg) of 77° C. or lower and a heat shrinkage rate of 2% or more at 60° C.,
wherein the film has a heat shrinkage rate of 15% or more at 65° C., 42% or more at 70° C., and 70% or more at 80° C.;
wherein the film is prepared by random-copolymerization of one kind of a dibasic acid component with three kinds of diol components;
wherein the dibasic acid component (A1) is one of terephthalic acid and dimethyl terephthalate; and
wherein the diol components are (B1) ethylene glycol, (B2) one of neopentyl glycol and cyclohexanedimethanol, and (B3) a linear diol component having three or more carbon atoms at a main chain thereof.
2. The heat-shrinkable polyester film of claim 1 , wherein the film has a heat shrinkage initiation temperature in a range of 55° C. to 60° C., a glass transition temperature in a range of 70° C. to 77° C., and a heat shrinkage rate of 2% to 10% at 60° C., 15% to 40% at 65° C., 42% to 60% at 70° C., and 70% to 75% at 80° C.
3. The heat-shrinkable polyester film of claim 1 , wherein the diol component (B3) is selected from the group consisting of diethylene glycol, 1,3-propanediol, 1,4-butanediol and 1,5-pentanediol.
4. The heat-shrinkable polyester film of claim 1 , wherein the amounts of (B1), (B2), and (B3) of the diol components are 60 to 90 mol %, 5 to 30 mol %, and 1 to 20 mol %, respectively, based on the total amount of (B1), (B2), and (B3).
5. The heat-shrinkable polyester film of claim 1 , wherein the amounts of (B1), (B2), and (B3) of the diol compounds are 60 to 85 mol %, 10 to 25 mol %, and 1 to 15 mol %, respectively, based on the total amount of (B1), (B2), and (B3).
6. The heat-shrinkable polyester film of claim 1 , wherein the heat-shrinkable polyester film is uniaxially stretched in the main contraction direction thereof.
7. A label for container comprising the heat-shrinkable polyester film of claim 1 .
8. The label of claim 7 , wherein the label for container is used as a label for a high-density polyethylene container.