IP Library Granted Patent US 10,449,525
Granted Patent B2
US 10,449,525 · App. 13/881,058 · Granted Oct 22, 2019

Hydrocarbon conversion catalyst composition

Inventors: Laszlo Domokos (Amsterdam, NL); Laurent Georges Huve (Amsterdam, NL); Hermanus Jongkind (Amsterdam, NL); Aan Hendrik Klazinga (Voorschoten, NL); Marcello Stefano Rigutto (Amsterdam, NL)
Assignee: SHELL OIL COMPANY
B01J29/7446B01J23/42B01J23/44B01J23/755B01J29/70B01J29/703B01J29/708B01J29/7049B01J29/7261B01J29/7461B01J29/7661B01J29/7861B01J29/80B01J37/0009B01J37/0201B01J37/30C10G35/065C10G45/64C10G49/08C10G50/00C10G65/12B01J2229/16B01J2229/186B01J2229/20B01J2229/37B01J2229/42
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Quick Facts
Patent No.
US 10,449,525
App. No.
13/881,058
Granted
Oct 22, 2019
Kind
B2
Abstract

A hydrocarbon conversion catalyst composition which comprises dealuminated ZSM-48 and/or EU-2 zeolite and a refractory oxide binder essentially free of alumina, processes for preparing such composition and processes for converting hydrocarbon feedstock with the help of such compositions.

Claims (19)

1. A dewaxing or alkylaromatics isomerization catalyst composition, which consists essentially of:

a dealuminated dried and calcined extrudate, obtained from a dried and calcined extrudate, wherein the extrudate, before drying and calcination, comprises a binder that is essentially free of alumina and which comprises both silica powder, wherein said silica powder comprises powder particles having a mean diameter between 10 μm and 200 μm, and a silica sol; EU-2 zeolite, wherein said EU-2 zeolite has a silica-to-alumina molar bulk ratio before the dealumination of said dried and calcined extrudate in the range of from 100 to 210; a plasticising agent; and water in an amount of at least 35% and not exceeding 60% by weight of the extrudate before drying and calcination; and

a catalytic metal selected from the group consisting of platinum, palladium and nickel;

wherein the dealumination of said dried and calcined extrudate is done by contacting said dried and calcined extrudate with an aqueous solution of fluorosilicate salt having a concentration of at least 0.005 mole of fluorosilicate salt/liter and at most 0.5 mole of fluorosilicate salt/liter and at a temperature in the range of from 10° C. to 120° C., and

wherein the amount of said EU-2 zeolite present in said hydroconversion catalyst composition is at least 15% wt of said hydrocarbon conversion catalyst composition; and

wherein the EU-2 zeolite is in the form of EU-2 zeolite particles, where the average aluminum concentration of the EU-2 zeolite particles is at least two times the aluminum concentration at the surface of the particles.

2. The catalyst composition according to claim 1 , wherein the zeolite content, on a dry basis, is of from 20 to 70 wt % as calculated on the total of said dewaxing or alkylaromatics isomerization catalyst composition.

3. The catalyst composition according to claim 1 , wherein said fluorosilicate salt of said fluorosilicate salt solution is represented by the formula:

(A) 2/b SiF 6

wherein ‘A’ is a metallic or non-metallic cation other than H+ having the valence ‘b’.

4. A process for converting a hydrocarbon feedstock which process comprises contacting the feedstock with a catalyst composition according to claim 1 at a temperature of from 100 to 600° C. and a pressure of from 1 to 100 bara.

5. A process according to claim 4 in which process the feedstock has a 10% distillation point greater than 343° C. measured by ASTM D-2887-93.

6. The catalyst composition according to claim 2 , wherein the plasticizing agent is selected from the group consisting of dextrose, gelatin, glucose, glues, gums, salts, waxes, starch and cellulose ethers.

7. The catalyst composition according to claim 6 , wherein said binder contains at most 2% wt alumina, based on dry weight of the binder per se.

8. The catalyst composition according to claim 7 , wherein said binder contains at most 1.1% wt alumina, based on dry weight of the binder per se.

9. The catalyst composition according to claim 8 , wherein said extrudate further comprises zeolite ZSM-12 that is present therein in an amount of at most 50% wt, based on the amount of EU-2 zeolite present.

10. The catalyst composition according to claim 9 , wherein the amount of EU-2 zeolite is at least 25% wt and at most 65% wt.

11. The catalyst composition according to claim 10 , wherein said plasticizing agent is methylcellulose or a methylcellulose derivative.

12. The catalyst composition according to claim 11 , wherein said binder contains at most 0.2% wt alumina, based on dry weight of the binder per se.

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 10, 2013
From: DOMOKOS, LASZLO; HUVE, LAURENT GEORGES; JONGKIND, HERMANUS; KLAZINGA, AAN HENDRIK; RIGUTTO, MARCELLO STEFANO
To: SHELL OIL COMPANY
Reel/Frame 030576/0668 →
Priority Claims (1)
EP 10306165 · Oct 25, 2010 · regional
Continuity (1)
Related Publication 20140209506A1 · Jul 31, 2014