Tubular threaded joint having improved low temperature performance
View Patent ↗In order to provide a tubular threaded joint constituted by a pin and a box each having threads and an unthreaded metal contact portion with excellent galling resistance and gas tightness even in extremely cold environments at −60° C. to −20° C. and rust preventing properties without using a compound grease, a thermoplastic solid lubricating coating containing low friction copolymer particles made from an acrylic-silicone copolymer and preferably further containing a solid lubricant (e.g., graphite) in a thermoplastic polymer matrix (e.g., selected from polyolefin resins and ethylene-vinyl acetate copolymer resins) is formed on the surface of the threads and unthreaded metal contact portion of a pin and/or a box.
1. A tubular threaded joint comprising a pin and a box each having contact surface including threads and an unthreaded metal contact portion, characterized in that the contact surface of at least one of the pin and the box has a thermoplastic solid lubricating coating formed as an uppermost surface treatment coating layer, said thermoplastic solid lubricating coating containing particles of a copolymer of a resin selected from a silicone resin and a fluorocarbon resin with a different thermoplastic resin in a thermoplastic polymer matrix.
2. A tubular threaded joint as set forth in claim 1 wherein the thermoplastic solid lubricating coating is formed on the contact surface of one of the pin and the box, and the contact surface of the other of the pin and the box has a solid corrosion-protecting coating based on an ultraviolet curing resin as an uppermost surface treatment coating layer.
3. A tubular threaded joint as set forth in claim 1 wherein the particles of a copolymer are acrylic-silicone copolymer particles.
4. A tubular threaded joint as set forth in claim 3 wherein the acrylic-silicone copolymer particles are spherical particles having an average particle diameter of 10-40 μm, and their content in the coating is 0.5-30 mass %.
5. A tubular threaded joint as set forth in claim 1 wherein the thermoplastic polymer matrix comprises one or more resins selected from a polyolefin resin and an ethylene-vinyl acetate copolymer resin.
6. A tubular threaded joint as set forth in claim 1 wherein the thermoplastic solid lubricating coating further contains a solid lubricant.
7. A threaded joint as set forth in claim 6 wherein the solid lubricant is graphite.
8. A tubular threaded joint as set forth in claim 1 wherein the thickness of the thermoplastic solid lubricating coating is 10-200 μm.
9. A tubular threaded joint as set forth in claim 2 wherein the thickness of the solid corrosion-protecting coating is 5-50 μm.
10. A connection for oil country tubular goods comprising a tubular threaded joint as set forth in claim 1 .
11. A composition for forming a thermoplastic solid lubricating coating on a tubular threaded joint characterized by comprising (1) a thermoplastic polymer matrix material, and (2) particles of a copolymer of a resin selected from a silicone resin and a fluorocarbon resin with a different thermoplastic resin.
12. A composition as set forth in claim 11 wherein the particles of a copolymer are acrylic-silicone copolymer particles.
13. A composition as set forth in claim 12 wherein the acrylic-silicone copolymer particles are spherical particles having an average particle diameter of 10-40 μm and their content is 0.5-30 mass % of the total solids content of the composition.
14. A composition as set forth in claim 11 wherein the thermoplastic polymer matrix material is one or more resins selected from a polyolefin resin and an ethylene-vinyl acetate copolymer resin.
15. A composition as set forth in claim 11 further containing a solid lubricant.
16. A composition as set forth in claim 15 wherein the solid lubricant is graphite.
17. A method of manufacturing a tubular threaded joint having a surface treatment coating layer, said tubular threaded joint comprising a pin and a box each having a contact surface including threads and an unthreaded metal contact portion, characterized by forming a solid lubricating coating as an uppermost surface treatment coating layer on the contact surface of at least one of the pin and box by application of a composition as set forth in claim 11 in which the thermoplastic polymer matrix material is in molten state followed by cooling.
18. A method as set forth in claim 17 wherein the solid lubricating coating is formed on the contact surface of one member of the pin and the box, and a solid corrosion-protecting coating is formed on the contact surface of the other member of the pin and the box as an uppermost surface treatment coating layer by application of a composition based on an ultraviolet curing resin followed by irradiation with ultraviolet light.